Recent Progress in Active Mechanical Metamaterials and Construction Principles

Active mechanical metamaterials (AMMs) (or smart mechanical metamaterials) that combine the configurations of mechanical metamaterials and the active control of stimuli‐responsive materials have been widely investigated in recent decades. The elaborate artificial microstructures of mechanical metamaterials and the stimulus response characteristics of smart materials both contribute to AMMs, making them achieve excellent properties beyond the conventional metamaterials. The micro and macro structures of the AMMs are designed based on structural construction principles such as, phase transition, strain mismatch, and mechanical instability. Considering the controllability and efficiency of the stimuli‐responsive materials, physical fields such as, the temperature, chemicals, light, electric current, magnetic field, and pressure have been adopted as the external stimuli in practice. In this paper, the frontier works and the latest progress in AMMs from the aspects of the mechanics and materials are reviewed. The functions and engineering applications of the AMMs are also discussed. Finally, existing issues and future perspectives in this field are briefly described. This review is expected to provide the basis and inspiration for the follow‐up research on AMMs.

[1]  Ying Li,et al.  Hydrogel-driven origami metamaterials for tunable swelling behavior , 2021 .

[2]  Yunteng Cao,et al.  Bistable Structures for Advanced Functional Systems , 2021, Advanced Functional Materials.

[3]  J. Andrade,et al.  Structured fabrics with tunable mechanical properties , 2021, Nature.

[4]  Yanbin Li,et al.  3D Transformable Modular Kirigami Based Programmable Metamaterials , 2021, Advanced Functional Materials.

[5]  D. Fang,et al.  Micro-CT based trans-scale damage analysis of 3D braided composites with pore defects , 2021, Composites Science and Technology.

[6]  Xiaogang Guo,et al.  Metamaterials with remarkable thermal–mechanical stability and high specific modulus: Mechanical designs, theoretical predictions and experimental demonstrations , 2021 .

[7]  J. Pikul,et al.  Materials with Electroprogrammable Stiffness , 2021, Advanced materials.

[8]  Xiang Zhang,et al.  Self-adaptive acoustic cloak enabled by soft mechanical metamaterials , 2021, Extreme Mechanics Letters.

[9]  Lucia M. Korpas,et al.  Temperature-Responsive Multistable Metamaterials. , 2021, ACS applied materials & interfaces.

[10]  Sahab Babaee,et al.  Kirigami-inspired stents for sustained local delivery of therapeutics , 2021, Nature Materials.

[11]  G. Hu,et al.  Tailored Mechanical Metamaterials with Programmable Quasi‐Zero‐Stiffness Features for Full‐Band Vibration Isolation , 2021, Advanced Functional Materials.

[12]  Jaehyung Ju,et al.  Thermomechanically Triggered Reversible Multi‐Transformability of a Single Material System by Energy Swapping and Shape Memory Effects , 2021, Advanced Functional Materials.

[13]  Yuli Chen,et al.  A Stair‐Building Strategy for Tailoring Mechanical Behavior of Re‐Customizable Metamaterials , 2021, Advanced Functional Materials.

[14]  M. Sitti,et al.  Liquid-Crystal-Elastomer-Actuated Reconfigurable Microscale Kirigami Metastructures , 2021, Advanced materials.

[15]  Yi Yang,et al.  Grasping with kirigami shells , 2021, Science Robotics.

[16]  Fujun Peng,et al.  Soft Origami Gripper with Variable Effective Length , 2021, Adv. Intell. Syst..

[17]  Xiaogang Guo,et al.  Metamaterials with a controllable thermal-mechanical stability: Mechanical designs, theoretical predictions and experimental demonstrations , 2021 .

[18]  Jianxun Cui,et al.  Morphing pasta and beyond , 2021, Science Advances.

[19]  Kyu-Jin Cho,et al.  Underwater maneuvering of robotic sheets through buoyancy-mediated active flutter , 2021, Science Robotics.

[20]  Jun Zou,et al.  Customizing a self-healing soft pump for robot , 2021, Nature Communications.

[21]  Yang Wang,et al.  Self-powered locomotion of a hydrogel water strider , 2021, Science Robotics.

[22]  S. Rudykh,et al.  Elastic instabilities, microstructure transformations, and pattern formations in soft materials , 2021, Current Opinion in Solid State and Materials Science.

[23]  R. Tao,et al.  SMP-based chiral auxetic mechanical metamaterial with tunable bandgap function , 2021 .

[24]  J. Aizenberg,et al.  Liquid-induced topological transformations of cellular microstructures , 2021, Nature.

[25]  Yuesheng Wang,et al.  Customized broadband pentamode metamaterials by topology optimization , 2021, Journal of the Mechanics and Physics of Solids.

[26]  Paul L. McEuen,et al.  Micrometer-sized electrically programmable shape-memory actuators for low-power microrobotics , 2021, Science Robotics.

[27]  D. Fang,et al.  Two-scale damage failure analysis of 3D braided composites considering pore defects , 2021 .

[28]  R. Harne,et al.  Digital logic gates in soft, conductive mechanical metamaterials , 2021, Nature Communications.

[29]  Zunfeng Liu,et al.  Tuning the reversibility of hair artificial muscles by disulfide cross-linking for sensors, switches, and soft robotics. , 2021, Materials horizons.

[30]  K. Sanderson Electronic skin: from flexibility to a sense of touch , 2021, Nature.

[31]  Shiqiang Zhu,et al.  Self-powered soft robot in the Mariana Trench , 2021, Nature.

[32]  R. Rawat,et al.  Volatile Ultrafast Switching at Multilevel Nonvolatile States of Phase Change Material for Active Flexible Terahertz Metadevices , 2021, Advanced Functional Materials.

[33]  L. Valdevit,et al.  Tensegrity Metamaterials: Toward Failure‐Resistant Engineering Systems through Delocalized Deformation , 2021, Advanced materials.

[34]  Ran Tao,et al.  Recent progress in the design and fabrication of multifunctional structures based on metamaterials , 2021 .

[35]  J. Leroux,et al.  Digital light 3D printing of customized bioresorbable airway stents with elastomeric properties , 2021, Science Advances.

[36]  Jianzhong Fu,et al.  A flexible porous chiral auxetic tracheal stent with ciliated epithelium. , 2021, Acta biomaterialia.

[37]  Xiaodong Chen,et al.  An on-demand plant-based actuator created using conformable electrodes , 2021, Nature Electronics.

[38]  Y. Mei,et al.  Gaussian-preserved, non-volatile shape morphing in three-dimensional microstructures for dual-functional electronic devices , 2021, Nature Communications.

[39]  Z. Zhuang,et al.  The role of material and geometric nonlinearities and damping effects in designing mechanically tunable acoustic metamaterials , 2021 .

[40]  W. Gilewski,et al.  Towards Recognition of Scale Effects in a Solid Model of Lattices with Tensegrity-Inspired Microstructure , 2021, Solids.

[41]  Sungjoon Lim,et al.  Review on recent origami inspired antennas from microwave to terahertz regime , 2021 .

[42]  S. Fang,et al.  Humidity- and Water-Responsive Torsional and Contractile Lotus Fiber Yarn Artificial Muscles. , 2021, ACS applied materials & interfaces.

[43]  S. Qu,et al.  3D printing of highly stretchable hydrogel with diverse UV curable polymers , 2021, Science Advances.

[44]  M. Pauly,et al.  A reprogrammable mechanical metamaterial with stable memory , 2021, Nature.

[45]  Yonggang Huang,et al.  Designing Mechanical Metamaterials with Kirigami‐Inspired, Hierarchical Constructions for Giant Positive and Negative Thermal Expansion , 2020, Advanced materials.

[46]  M. Sitti,et al.  Multifunctional magnetic soft composites: a review , 2020, Multifunctional materials.

[47]  Yanju Liu,et al.  Porous bone tissue scaffold concept based on shape memory PLA/Fe3O4 , 2020 .

[48]  R. Tao,et al.  4D printed origami metamaterials with tunable compression twist behavior and stress-strain curves , 2020 .

[49]  R. Tao,et al.  4D printed multi-stable metamaterials with mechanically tunable performance , 2020 .

[50]  Qing Gao,et al.  Fabrication of Multi-Scale and Tunable Auxetic Scaffolds for Tissue Engineering , 2020 .

[51]  Xiangyang Zhu,et al.  Programmable soft bending actuators with auxetic metamaterials , 2020, Science China Technological Sciences.

[52]  Constantinos Soutis,et al.  Lightweight Self‐Forming Super‐Elastic Mechanical Metamaterials with Adaptive Stiffness , 2020, Advanced Functional Materials.

[53]  Metin Sitti,et al.  Bioinspired cilia arrays with programmable nonreciprocal motion and metachronal coordination , 2020, Science Advances.

[54]  Yong Wang,et al.  In situ stiffness manipulation using elegant curved origami , 2020, Science Advances.

[55]  Neil Gershenfeld,et al.  Discretely assembled mechanical metamaterials , 2020, Science Advances.

[56]  Jie Tang,et al.  Real-time tunable negative stiffness mechanical metamaterial , 2020 .

[57]  R. Tao,et al.  Design and analysis of 2D/3D negative hydration expansion Metamaterial driven by hydrogel , 2020 .

[58]  Han Zhou,et al.  A review of topology optimization for additive manufacturing: Status and challenges , 2020 .

[59]  Jakob A Faber,et al.  Dome‐Patterned Metamaterial Sheets , 2020, Advanced science.

[60]  R. Harne,et al.  Liquid metal microchannels as digital sensors in mechanical metamaterials , 2020, Extreme Mechanics Letters.

[61]  S. Forest,et al.  Propagating material instabilities in planar architectured materials , 2020 .

[62]  H. Qi,et al.  Recent advances in additive manufacturing of active mechanical metamaterials , 2020, Current Opinion in Solid State and Materials Science.

[63]  N. Yang,et al.  3D kirigami metamaterials with coded thermal expansion properties , 2020, Extreme Mechanics Letters.

[64]  Rebecca Kramer-Bottiglio,et al.  Roboticizing fabric by integrating functional fibers , 2020, Proceedings of the National Academy of Sciences.

[65]  Qiji Ze,et al.  Untethered control of functional origami microrobots with distributed actuation , 2020, Proceedings of the National Academy of Sciences.

[66]  Yanju Liu,et al.  4D Printing Auxetic Metamaterials with Tunable, Programmable, and Reconfigurable Mechanical Properties , 2020, Advanced Functional Materials.

[67]  H. Qi,et al.  Magnetic Multimaterial Printing for Multimodal Shape Transformation with Tunable Properties and Shiftable Mechanical Behaviors. , 2020, ACS applied materials & interfaces.

[68]  K. Bertoldi,et al.  Programming nonreciprocity and reversibility in multistable mechanical metamaterials , 2020, Nature Communications.

[69]  Wenwang Wu,et al.  Chiral constrained stent: Effect of structural design on the mechanical and intravascular stent deployment performances , 2020 .

[70]  A. Ngan,et al.  Chemo-mechanical instability of light-induced humidity responsive bilayered actuators , 2020 .

[71]  Metin Sitti,et al.  Reprogrammable shape morphing of magnetic soft machines , 2020, Science Advances.

[72]  S. Cai,et al.  Three-dimensional printing of functionally graded liquid crystal elastomer , 2020, Science Advances.

[73]  Hajun Lee,et al.  3D-printed programmable tensegrity for soft robotics , 2020, Science Robotics.

[74]  M. Tolley,et al.  Reversible actuation for self-folding modular machines using liquid crystal elastomer , 2020, Smart Materials and Structures.

[75]  C. M. Portela,et al.  Pushing and Pulling on Ropes: Hierarchical Woven Materials , 2020, Advanced science.

[76]  E. Filipov,et al.  Elastically and Plastically Foldable Electrothermal Micro‐Origami for Controllable and Rapid Shape Morphing , 2020, Advanced Functional Materials.

[77]  F. Daining,et al.  Multi-scale elastic property prediction of 3D five-directional braided composites considering pore defects , 2020 .

[78]  Marina Pilz da Cunha,et al.  An artificial aquatic polyp that wirelessly attracts, grasps, and releases objects , 2020, Proceedings of the National Academy of Sciences.

[79]  I. Burgert,et al.  Mechanical Properties Tailoring of 3D Printed Photoresponsive Nanocellulose Composites , 2020, Advanced Functional Materials.

[80]  Xiang Luo,et al.  Geometrically reconfigurable 3D mesostructures and electromagnetic devices through a rational bottom-up design strategy , 2020, Science Advances.

[81]  Jinsong Leng,et al.  Direct Ink Writing Based 4D Printing of Materials and Their Applications , 2020, Advanced science.

[82]  Zhenan Bao,et al.  Enabling Deformable and Stretchable Batteries , 2020, Advanced Energy Materials.

[83]  H. Qi,et al.  Magneto‐Mechanical Metamaterials with Widely Tunable Mechanical Properties and Acoustic Bandgaps , 2020, Advanced Functional Materials.

[84]  A. A. Zadpoor,et al.  Strain rate-dependent mechanical metamaterials. , 2020, Science Advances.

[85]  Guoyong Mao,et al.  Soft electromagnetic actuators , 2020, Science Advances.

[86]  Yonggang Huang,et al.  Assembly of Foldable 3D Microstructures Using Graphene Hinges , 2020, Advanced materials.

[87]  B. Nelson,et al.  Magnetic cilia carpets with programmable metachronal waves , 2020, Nature Communications.

[88]  Chuanzeng Zhang,et al.  3D acoustic metamaterial-based mechanical metalattice structures for low-frequency and broadband vibration attenuation , 2020 .

[89]  Qian Zhao,et al.  Modular 4D Printing via Interfacial Welding of Digital Light-Controllable Dynamic Covalent Polymer Networks , 2020 .

[90]  D. Kochmann,et al.  Phase transformations in substrate-free dissipative multistable metamaterials , 2020 .

[91]  Xiangyang Zhu,et al.  Design of 3D printed programmable horseshoe lattice structures based on a phase-evolution model. , 2020, ACS applied materials & interfaces.

[92]  W. Hong,et al.  Kirigami‐Design‐Enabled Hydrogel Multimorphs with Application as a Multistate Switch , 2020, Advanced materials.

[93]  Sojung Yim,et al.  Ladybird beetle–inspired compliant origami , 2020, Science Robotics.

[94]  J. S. Ho,et al.  Somatosensory, Light‐Driven, Thin‐Film Robots Capable of Integrated Perception and Motility , 2020, Advanced materials.

[95]  M. Wegener,et al.  Mapping acoustical activity in 3D chiral mechanical metamaterials onto micropolar continuum elasticity , 2020 .

[96]  Yihui Zhang,et al.  Recent progress of morphable 3D mesostructures in advanced materials , 2020, Journal of Semiconductors.

[97]  D. Fang,et al.  Rapid volatilization induced mechanically robust shape-morphing structures toward 4D printing. , 2020, ACS applied materials & interfaces.

[98]  Yihui Zhang,et al.  Laser‐Induced Graphene for Electrothermally Controlled, Mechanically Guided, 3D Assembly and Human–Soft Actuators Interaction , 2020, Advanced materials.

[99]  Li Ma,et al.  1D to 3D multi-stable architected materials with zero Poisson's ratio and controllable thermal expansion , 2020 .

[100]  Daining Fang,et al.  Frequency-selective-surface based sandwich structure for both effective loadbearing and customizable microwave absorption , 2020 .

[101]  Yonggang Huang,et al.  Inverse Design Strategies for 3D Surfaces Formed by Mechanically Guided Assembly , 2020, Advanced materials.

[102]  Qiji Ze,et al.  Evolutionary Algorithm‐Guided Voxel‐Encoding Printing of Functional Hard‐Magnetic Soft Active Materials , 2020, Adv. Intell. Syst..

[103]  Thomas J. Wallin,et al.  Autonomic perspiration in 3D-printed hydrogel actuators , 2020, Science Robotics.

[104]  Christopher T. Nguyen,et al.  An organosynthetic dynamic heart model with enhanced biomimicry guided by cardiac diffusion tensor imaging , 2020, Science Robotics.

[105]  Yazheng Yang,et al.  Active Reconfigurable Tristable Square‐Twist Origami , 2020, Advanced Functional Materials.

[106]  K. Bertoldi,et al.  Guided transition waves in multistable mechanical metamaterials , 2020, Proceedings of the National Academy of Sciences.

[107]  J. Runt,et al.  A highly scalable dielectric metamaterial with superior capacitor performance over a broad temperature , 2020, Science Advances.

[108]  N. Vasilyev,et al.  Magnetically Active Cardiac Patches as an Untethered, Non‐Blood Contacting Ventricular Assist Device , 2020, Advanced science.

[109]  D. Fang,et al.  Customized Kirigami Electrodes for Flexible and Deformable Lithium-Ion Batteries. , 2019, ACS applied materials & interfaces.

[110]  A. Priimagi,et al.  Kirigami‐Based Light‐Induced Shape‐Morphing and Locomotion , 2019, Advanced materials.

[111]  Lin-zhi Wu,et al.  Novel multidirectional negative stiffness mechanical metamaterials , 2019, Smart Materials and Structures.

[112]  Xiaobo Tan,et al.  Soft Crawling Robots: Design, Actuation, and Locomotion , 2019, Advanced Materials Technologies.

[113]  John A. Rogers,et al.  Resettable skin interfaced microfluidic sweat collection devices with chemesthetic hydration feedback , 2019, Nature Communications.

[114]  August G. Domel,et al.  Programmable Hierarchical Kirigami , 2019, Advanced Functional Materials.

[115]  Kyu-Jin Cho,et al.  Bioinspired dual-morphing stretchable origami , 2019, Science Robotics.

[116]  Jinsong Leng,et al.  Personalized 4D printing of bioinspired tracheal scaffold concept based on magnetic stimulated shape memory composites , 2019, Composites Science and Technology.

[117]  Bradley J. Nelson,et al.  Nanomagnetic encoding of shape-morphing micromachines , 2019, Nature.

[118]  Bradley J. Nelson,et al.  Magnetic quadrupole assemblies with arbitrary shapes and magnetizations , 2019, Science Robotics.

[119]  D. Fang,et al.  A nonlinear mechanics model of soft network metamaterials with unusual swelling behavior and tunable phononic band gaps , 2019, Composites Science and Technology.

[120]  G. Qian,et al.  Mechanical design and multifunctional applications of chiral mechanical metamaterials: A review , 2019, Materials & Design.

[121]  Ha Uk Chung,et al.  Mechanoacoustic sensing of physiological processes and body motions via a soft wireless device placed at the suprasternal notch , 2019, Nature Biomedical Engineering.

[122]  G. Hu,et al.  Influences of imperfectness and inner constraints on an acoustic cloak with unideal pentamode materials , 2019, Journal of Sound and Vibration.

[123]  Yonggang Huang,et al.  2D Mechanical Metamaterials with Widely Tunable Unusual Modes of Thermal Expansion , 2019, Advanced materials.

[124]  Sungjoon Lim,et al.  Bioinspired DNA Origami Quasi-Yagi Helical Antenna with Beam Direction and Beamwidth Switching Capability , 2019, Scientific Reports.

[125]  Wim M van Rees,et al.  Shape-shifting structured lattices via multimaterial 4D printing , 2019, Proceedings of the National Academy of Sciences.

[126]  Lu Zhang,et al.  Stiff reconfigurable polygons for smart connecters and deployable structures , 2019, International Journal of Mechanical Sciences.

[127]  Qiji Ze,et al.  Magnetic Shape Memory Polymers with Integrated Multifunctional Shape Manipulation , 2019, Advanced materials.

[128]  Heng Yang,et al.  Electrochemically reconfigurable architected materials , 2019, Nature.

[129]  Shuai Wu,et al.  Symmetry-breaking Actuation Mechanism for Soft Robotics and Active Metamaterials. , 2019, ACS applied materials & interfaces.

[130]  Fei Xiao,et al.  Multi-stimuli-responsive programmable biomimetic actuator , 2019, Nature Communications.

[131]  H. Rodrigue,et al.  Long Shape Memory Alloy Tendon-based Soft Robotic Actuators and Implementation as a Soft Gripper , 2019, Scientific Reports.

[132]  Z. Eckel,et al.  Elastomeric Microlattice Impact Attenuators , 2019, Matter.

[133]  Yue Zhao,et al.  Biomimetic Locomotion of Electrically Powered “Janus” Soft Robots Using a Liquid Crystal Polymer , 2019, Advanced materials.

[134]  Howon Lee,et al.  4D printing reconfigurable, deployable and mechanically tunable metamaterials , 2019, Materials Horizons.

[135]  Yihui Zhang,et al.  Micro/Nanoscale 3D Assembly by Rolling, Folding, Curving, and Buckling Approaches , 2019, Advanced materials.

[136]  M. Sitti,et al.  Multi-functional soft-bodied jellyfish-like swimming , 2019, Nature Communications.

[137]  C. Park,et al.  Suit-type Wearable Robot Powered by Shape-memory-alloy-based Fabric Muscle , 2019, Scientific Reports.

[138]  Jinsong Leng,et al.  Mechanical Models, Structures, and Applications of Shape-Memory Polymers and Their Composites , 2019, Acta Mechanica Solida Sinica.

[139]  Guozheng Kang,et al.  Dynamic Photomask‐Assisted Direct Ink Writing Multimaterial for Multilevel Triboelectric Nanogenerator , 2019, Advanced Functional Materials.

[140]  Craig M. Hamel,et al.  3D Printing of Auxetic Metamaterials with Digitally Reprogrammable Shape. , 2019, ACS applied materials & interfaces.

[141]  Wei-li Song,et al.  Integrated design of component and configuration for a flexible and ultrabroadband radar absorbing composite , 2019, Composites Science and Technology.

[142]  Lihua Jin,et al.  Programmable Granular Metamaterials for Reusable Energy Absorption , 2019, Advanced Functional Materials.

[143]  Yuli Chen,et al.  Infrared Skin‐Like Active Stretchable Electronics Based on Organic–Inorganic Composite Structures for Promotion of Cutaneous Wound Healing , 2019, Advanced Materials Technologies.

[144]  Jonghwa Park,et al.  A Hierarchical Nanoparticle‐in‐Micropore Architecture for Enhanced Mechanosensitivity and Stretchability in Mechanochromic Electronic Skins , 2019, Advanced materials.

[145]  Yuli Chen,et al.  3D Pixel Mechanical Metamaterials , 2019, Advanced materials.

[146]  Martin L. Dunn,et al.  Machine-learning based design of active composite structures for 4D printing , 2019, Smart Materials and Structures.

[147]  Amir Hosein Sakhaei,et al.  Multimaterial 3D Printed Soft Actuators Powered by Shape Memory Alloy Wires , 2019, Sensors and Actuators A: Physical.

[148]  Kurt Maute,et al.  Combined Level-Set-XFEM-Density Topology Optimization of Four-Dimensional Printed Structures Undergoing Large Deformation , 2019, Journal of Mechanical Design.

[149]  Robert J. Wood,et al.  A Vacuum-driven Origami “Magic-ball” Soft Gripper , 2019, 2019 International Conference on Robotics and Automation (ICRA).

[150]  Tianqi Xu,et al.  Millimeter-scale flexible robots with programmable three-dimensional magnetization and motions , 2019, Science Robotics.

[151]  D. Fang,et al.  Three-Dimensionally Printed Mechanical Metamaterials With Thermally Tunable Auxetic Behavior , 2019, Physical Review Applied.

[152]  K. Bertoldi,et al.  Propagation of pop ups in kirigami shells , 2019, Proceedings of the National Academy of Sciences.

[153]  L. Ionov,et al.  Light‐Responsive Shape‐Changing Polymers , 2019, Advanced Optical Materials.

[154]  Timothy Bretl,et al.  Large-area MRI-compatible epidermal electronic interfaces for prosthetic control and cognitive monitoring , 2019, Nature Biomedical Engineering.

[155]  P. Chakravarthy,et al.  High glass-transition polyurethane-carbon black electro-active shape memory nanocomposite for aerospace systems , 2019, Materials Science and Technology.

[156]  J. L. Curiel-Sosa,et al.  Meso-Scale Finite Element Analysis of Mechanical Behavior of 3D Braided Composites Subjected to Biaxial Tension Loadings , 2019, Applied Composite Materials.

[157]  Shashank Priya,et al.  Three-dimensional printing of piezoelectric materials with designed anisotropy and directional response , 2019, Nature Materials.

[158]  O. Velev,et al.  3D‐Printed Silicone Soft Architectures with Programmed Magneto‐Capillary Reconfiguration , 2019, Advanced Materials Technologies.

[159]  D. Fang,et al.  Twistable Origami and Kirigami: from Structure-Guided Smartness to Mechanical Energy Storage. , 2019, ACS applied materials & interfaces.

[160]  Haiwen Luan,et al.  A Generic Soft Encapsulation Strategy for Stretchable Electronics , 2019, Advanced Functional Materials.

[161]  C. Majidi,et al.  Highly Dynamic Shape Memory Alloy Actuator for Fast Moving Soft Robots , 2019, Advanced Materials Technologies.

[162]  John A. Rogers,et al.  Waterproof, electronics-enabled, epidermal microfluidic devices for sweat collection, biomarker analysis, and thermography in aquatic settings , 2019, Science Advances.

[163]  Wojciech Gilewski,et al.  Soft and Stiff Simplex Tensegrity Lattices as Extreme Smart Metamaterials , 2019, Materials.

[164]  S. Cai,et al.  A Light‐Powered Ultralight Tensegrity Robot with High Deformability and Load Capacity , 2018, Advanced materials.

[165]  Kon-Well Wang,et al.  Architected Origami Materials: How Folding Creates Sophisticated Mechanical Properties , 2018, Advanced materials.

[166]  Kenneth J. Loh,et al.  Field responsive mechanical metamaterials , 2018, Science Advances.

[167]  K. J. Hsia,et al.  Differential growth and shape formation in plant organs , 2018, Proceedings of the National Academy of Sciences.

[168]  Z. Lou,et al.  Device Configurations and Future Prospects of Flexible/Stretchable Lithium‐Ion Batteries , 2018, Advanced Functional Materials.

[169]  Qiang Huang,et al.  A bioinspired multilegged soft millirobot that functions in both dry and wet conditions , 2018, Nature Communications.

[170]  M. Sitti,et al.  Light-Triggered Drug Release from 3D-Printed Magnetic Chitosan Microswimmers. , 2018, ACS nano.

[171]  Lihua Jin,et al.  Geometric role in designing pneumatically actuated pattern-transforming metamaterials , 2018, Extreme Mechanics Letters.

[172]  Mingji Chen,et al.  Effects of stitch on mechanical and microwave absorption properties of radar absorbing structure , 2018, Composite Structures.

[173]  Shu-ying Gu,et al.  3D printed self-expandable vascular stents from biodegradable shape memory polymer , 2018, Advances in Polymer Technology.

[174]  Shawn A. Chester,et al.  Printing ferromagnetic domains for untethered fast-transforming soft materials , 2018, Nature.

[175]  D. Fang,et al.  Soft mechanical metamaterials with unusual swelling behavior and tunable stress-strain curves , 2018, Science Advances.

[176]  Wen-Di Li,et al.  Light-stimulated actuators based on nickel hydroxide-oxyhydroxide , 2018, Science Robotics.

[177]  Katia Bertoldi,et al.  Stimuli-induced bi-directional hydrogel unimorph actuators , 2018 .

[178]  N. Fang,et al.  Magnetoactive Acoustic Metamaterials , 2018, Advanced materials.

[179]  Conner K. Dunn,et al.  Thermomechanically Triggered Two‐Stage Pattern Switching of 2D Lattices for Adaptive Structures , 2018 .

[180]  Yashraj S. Narang,et al.  Mechanically Versatile Soft Machines through Laminar Jamming , 2018 .

[181]  Jakob A Faber,et al.  Bioinspired spring origami , 2018, Science.

[182]  Rongrong Zhang,et al.  4D Printing of Robust Hydrogels Consisted of Agarose Nanofibers and Polyacrylamide. , 2018, ACS macro letters.

[183]  Weiqiu Chen,et al.  Soft Ultrathin Electronics Innervated Adaptive Fully Soft Robots , 2018, Advanced materials.

[184]  Qifa Zhou,et al.  3D‐Printed Biomimetic Super‐Hydrophobic Structure for Microdroplet Manipulation and Oil/Water Separation , 2018, Advanced materials.

[185]  Xiaodong Chen,et al.  Auxetic Mechanical Metamaterials to Enhance Sensitivity of Stretchable Strain Sensors , 2018, Advanced materials.

[186]  Tianzhen Li,et al.  Mechanochemical Regulated Origami with Tough Hydrogels by Ion Transfer Printing. , 2018, ACS applied materials & interfaces.

[187]  Katia Bertoldi,et al.  Kirigami skins make a simple soft actuator crawl , 2018, Science Robotics.

[188]  Weihua Li,et al.  Versatile Microfluidic Platforms Enabled by Novel Magnetorheological Elastomer Microactuators , 2018 .

[189]  Jung Woo Lee,et al.  Morphable 3D Mesostructures and Microelectronic Devices by Multistable Buckling Mechanics , 2018, Nature Materials.

[190]  Metin Sitti,et al.  Small-scale soft-bodied robot with multimodal locomotion , 2018, Nature.

[191]  A. Schenning,et al.  Photoresponsive Passive Micromixers Based on Spiropyran Size-Tunable Hydrogels. , 2018, Macromolecular rapid communications.

[192]  Martin L. Dunn,et al.  4D rods: 3D structures via programmable 1D composite rods , 2018 .

[193]  Jizhou Song,et al.  Programming a crystalline shape memory polymer network with thermo- and photo-reversible bonds toward a single-component soft robot , 2018, Science Advances.

[194]  Robert J. Wood,et al.  Fluid-driven origami-inspired artificial muscles , 2017, Proceedings of the National Academy of Sciences.

[195]  Hod Lipson,et al.  Soft material for soft actuators , 2017, Nature Communications.

[196]  W. Hong,et al.  Cooperative deformations of periodically patterned hydrogels , 2017, Science Advances.

[197]  K. Bertoldi,et al.  Exploiting Microstructural Instabilities in Solids and Structures: From Metamaterials to Structural Transitions , 2017 .

[198]  Yunchao Xie,et al.  Bioinspired Programmable Polymer Gel Controlled by Swellable Guest Medium. , 2017, ACS applied materials & interfaces.

[199]  Conner K. Dunn,et al.  3D printed reversible shape changing soft actuators assisted by liquid crystal elastomers. , 2017, Soft matter.

[200]  Deyong Zhu,et al.  "Freezing", morphing, and folding of stretchy tough hydrogels. , 2017, Journal of materials chemistry. B.

[201]  Tianqi Liu,et al.  Surface Patterning of Hydrogels for Programmable and Complex Shape Deformations by Ion Inkjet Printing , 2017 .

[202]  Quankang Wang,et al.  A multifunctional skin-like sensor based on a 3D printed thermo-responsive hydrogel , 2017 .

[203]  K. Bertoldi,et al.  Origami Metamaterials for Tunable Thermal Expansion , 2017, Advanced materials.

[204]  P. Reis,et al.  Reversible patterning of spherical shells through constrained buckling , 2017 .

[205]  Glaucio H. Paulino,et al.  Programmable Deployment of Tensegrity Structures by Stimulus-Responsive Polymers , 2017, Scientific Reports.

[206]  Yong Wang,et al.  Electrically/infrared actuated shape memory composites based on a bio-based polyester blend and graphene nanoplatelets and their excellent self-driven ability , 2017 .

[207]  Jun Liu,et al.  Spatial Control of Functional Response in 4D-Printed Active Metallic Structures , 2017, Scientific Reports.

[208]  Chao Yuan,et al.  Direct 4D printing via active composite materials , 2017, Science Advances.

[209]  D. Fang,et al.  Origami by frontal photopolymerization , 2017, Science Advances.

[210]  Jizhou Song,et al.  Ultrafast Digital Printing toward 4D Shape Changing Materials , 2017, Advanced materials.

[211]  Yichao Tang,et al.  Origami and kirigami inspired self-folding for programming three-dimensional shape shifting of polymer sheets with light , 2017 .

[212]  Nong Zhang,et al.  Level-set topology optimization for multimaterial and multifunctional mechanical metamaterials , 2017 .

[213]  M. Buehler,et al.  The mechanics and design of a lightweight three-dimensional graphene assembly , 2017, Science Advances.

[214]  Damiano Pasini,et al.  Bistable Auxetic Mechanical Metamaterials Inspired by Ancient Geometric Motifs , 2016, 1612.05988.

[215]  Vincent Tournat,et al.  Reconfigurable origami-inspired acoustic waveguides , 2016, Science Advances.

[216]  R. Xiao Modeling Mismatch Strain Induced Self-Folding of Bilayer Gel Structures , 2016 .

[217]  Derek E. Moulton,et al.  Critical slowing down in purely elastic ‘snap-through’ instabilities , 2016, Nature Physics.

[218]  Jeonghyun Kim,et al.  Mechanical assembly of complex, 3D mesostructures from releasable multilayers of advanced materials , 2016, Science Advances.

[219]  Katia Bertoldi,et al.  Harnessing Buckling to Design Architected Materials that Exhibit Effective Negative Swelling , 2016, Advanced materials.

[220]  Xin Peng,et al.  Tough Hydrogels with Programmable and Complex Shape Deformations by Ion Dip‐Dyeing and Transfer Printing , 2016 .

[221]  Randall M. Erb,et al.  Actuating Soft Matter with Magnetic Torque , 2016 .

[222]  Chao Yuan,et al.  3D Printed Reversible Shape Changing Components with Stimuli Responsive Materials , 2016, Scientific Reports.

[223]  Yonggang Huang,et al.  Controlled Mechanical Buckling for Origami‐Inspired Construction of 3D Microstructures in Advanced Materials , 2016, Advanced functional materials.

[224]  Zhuo Xu,et al.  Pentamodal property and acoustic band gaps of pentamode metamaterials with different cross-section shapes , 2016 .

[225]  M. Dickey,et al.  Selective and directional actuation of elastomer films using chained magnetic nanoparticles. , 2016, Nanoscale.

[226]  Jakob S. Jensen,et al.  Topology Optimized Architectures with Programmable Poisson's Ratio over Large Deformations , 2015, Advanced materials.

[227]  Bo Li,et al.  Isotropic Negative Thermal Expansion Metamaterials. , 2015, ACS applied materials & interfaces.

[228]  Kon-Well Wang,et al.  Fluidic origami: a plant-inspired adaptive structure with shape morphing and stiffness tuning , 2015 .

[229]  F. Qiu,et al.  Controlled In Vivo Swimming of a Swarm of Bacteria‐Like Microrobotic Flagella , 2015, Advanced materials.

[230]  Nathaniel S. Hwang,et al.  Hydrogel-laden paper scaffold system for origami-based tissue engineering , 2015, Proceedings of the National Academy of Sciences.

[231]  Katia Bertoldi,et al.  Discontinuous Buckling of Wide Beams and Metabeams. , 2014, Physical review letters.

[232]  L. Mahadevan,et al.  Scaling macroscopic aquatic locomotion , 2014, Nature Physics.

[233]  Elizabeth R. Chen,et al.  Harnessing Multiple Folding Mechanisms in Soft Periodic Structures for Tunable Control of Elastic Waves , 2014 .

[234]  M. van Hecke,et al.  Programmable mechanical metamaterials. , 2014, Physical review letters.

[235]  M. Wegener,et al.  An elasto-mechanical unfeelability cloak made of pentamode metamaterials , 2014, Nature Communications.

[236]  Yanju Liu,et al.  Sodium dodecyl sulfate/epoxy composite: water-induced shape memory effect and its mechanism , 2014 .

[237]  Kyu-Jin Cho,et al.  Flytrap-inspired robot using structurally integrated actuation based on bistability and a developable surface , 2014, Bioinspiration & biomimetics.

[238]  O. Sigmund,et al.  Topology optimization approaches , 2013, Structural and Multidisciplinary Optimization.

[239]  Katia Bertoldi,et al.  Harnessing instabilities for design of soft reconfigurable auxetic/chiral materials , 2013 .

[240]  E. Palleau,et al.  Reversible patterning and actuation of hydrogels by electrically assisted ionoprinting , 2013, Nature Communications.

[241]  Marc Behl,et al.  Temperature-memory polymer actuators , 2013, Proceedings of the National Academy of Sciences.

[242]  Leonid Ionov,et al.  Hierarchical Multi‐Step Folding of Polymer Bilayers , 2013 .

[243]  J. Greener,et al.  Three-dimensional shape transformations of hydrogel sheets induced by small-scale modulation of internal stresses , 2013, Nature Communications.

[244]  Martin Wegener,et al.  Phonon band structures of three-dimensional pentamode metamaterials , 2012, 1207.5976.

[245]  M. Wegener,et al.  On the feasibility of pentamode mechanical metamaterials , 2012, 1203.1481.

[246]  Hwan Chul Jeon,et al.  Controlled origami folding of hydrogel bilayers with sustained reversibility for robust microcarriers. , 2012, Angewandte Chemie.

[247]  Filip Ilievski,et al.  Multigait soft robot , 2011, Proceedings of the National Academy of Sciences.

[248]  Howon Lee,et al.  Programming magnetic anisotropy in polymeric microactuators. , 2011, Nature materials.

[249]  Yanju Liu,et al.  Shape-memory polymers and their composites: Stimulus methods and applications , 2011 .

[250]  G. Cheng,et al.  Optimal structure design with low thermal directional expansion and high stiffness , 2011 .

[251]  Haiyi Liang,et al.  Growth, geometry, and mechanics of a blooming lily , 2011, Proceedings of the National Academy of Sciences.

[252]  Chul-Hee Lee,et al.  Virtual Surface Characteristics of a Tactile Display Using Magneto-Rheological Fluids , 2011, Sensors.

[253]  D. Gracias,et al.  Photolithographically patterned smart hydrogel based bilayer actuators , 2010 .

[254]  Ruben Gatt,et al.  Elastic constants of 3-, 4- and 6-connected chiral and anti-chiral honeycombs subject to uniaxial in-plane loading , 2010 .

[255]  Dominiek Reynaerts,et al.  Pneumatic and hydraulic microactuators: a review , 2010 .

[256]  M. Ruzzene,et al.  Composite chiral structures for morphing airfoils: Numerical analyses and development of a manufacturing process , 2010 .

[257]  K. Bertoldi,et al.  Negative Poisson's Ratio Behavior Induced by an Elastic Instability , 2010, Advanced materials.

[258]  Jin-Chul Kim,et al.  Alginate beads containing pH-sensitive liposomes and glucose oxidase: glucose-sensitive release , 2009 .

[259]  Triplicane A. Parthasarathy,et al.  Tailorable thermal expansion hybrid structures , 2009 .

[260]  A. Norris Acoustic cloaking theory , 2008, Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences.

[261]  Thao D. Nguyen,et al.  Finite deformation thermo-mechanical behavior of thermally induced shape memory polymers , 2008 .

[262]  J. Ou,et al.  Magnetostrictive effect of magnetorheological elastomer , 2008 .

[263]  M. Ben Amar,et al.  Morphogenesis of growing soft tissues. , 2007, Physical review letters.

[264]  G. Yin,et al.  A Smart Supramolecular Hydrogel Exhibiting pH‐Modulated Viscoelastic Properties , 2007 .

[265]  C. Radcliffe,et al.  Internal organizational measurement for control of magnetorheological fluid properties , 2007 .

[266]  Sang-Hyun Kim,et al.  Mechanical behavior of mismatch strain-driven microcantilever , 2007, Microelectron. J..

[267]  A. Lendlein,et al.  Polymers Move in Response to Light , 2006 .

[268]  Nicolas Triantafyllidis,et al.  Failure Surfaces for Finitely Strained Two-Phase Periodic Solids Under General In-Plane Loading , 2006 .

[269]  Yiping Liu,et al.  Thermomechanics of shape memory polymers: Uniaxial experiments and constitutive modeling , 2006 .

[270]  B. Feringa,et al.  University of Groningen Design and Application of Self-Assembled Low Molecular Weight Hydrogels , 2005 .

[271]  Zhengguo Zhu,et al.  Sensitivity gains in chemosensing by lasing action in organic polymers , 2005, Nature.

[272]  S. Torquato,et al.  Composites with extremal thermal expansion coefficients , 1996 .

[273]  S. Timoshenko,et al.  Analysis of Bi-Metal Thermostats , 1925 .

[274]  R. Tao,et al.  SMP-based multi-stable mechanical metamaterials: From bandgap tuning to wave logic gates , 2021 .

[275]  A. Lendlein,et al.  Final Draft of the original manuscript , 2021 .

[276]  Owies M. Wani,et al.  Light-Driven, Caterpillar-Inspired Miniature Inching Robot. , 2018, Macromolecular rapid communications.

[277]  G. Spinks,et al.  4D Printing of Reversible Shape Morphing Hydrogel Structures , 2017 .

[278]  H. Petryk,et al.  Material instabilities in elastic and plastic solids , 2000 .