Observation of blue phases in chiral networks

Abstract We report the first observation of cholesteric blue phases in chiral anisotropic polymer networks. In two-component mixtures of a chiral and a non-chiral diacrylate, we observed typical textures of BPI, BPII and BPIII phases. By photopolymerization of these materials at constant temperature we obtained blue phase networks. After polymerization, the blue phases were stored, which enabled us to further study them without any temperature control.

[1]  R. Hikmet,et al.  Electrically induced light scattering from anisotropic gels , 1990 .

[2]  D. Broer,et al.  INSITU PHOTOPOLYMERIZATION OF ORIENTED LIQUID-CRYSTALLINE ACRYLATES .4. INFLUENCE OF A LATERAL METHYL SUBSTITUENT ON MONOMER AND ORIENTED POLYMER NETWORK PROPERTIES OF A MESOGENIC DIACRYLATE , 1989 .

[3]  Heinz-S. Kitzerow,et al.  The effect of electric fields on blue phases , 1991 .

[4]  C. Papenfuss,et al.  Blue phase mixtures exhibiting low fractions of a chiral compound experimental observation of some unusual properties , 1990 .

[5]  Growth of cubic liquid single crystals in cholesteric blue phases , 1983 .

[6]  P. Crooker Plenary Lecture. The blue phases. A review of experiments , 1989 .

[7]  J. Gilli,et al.  Phases bleues "figées" dans un polysiloxane mésomorphe , 1989 .

[8]  R. Hikmet Anisotropic gels and plasticized networks formed by liquid crystal molecules , 1991 .

[9]  J. Gilli,et al.  Quenched Blue Phase, Below the Glass Transition of a Side Chain Polysiloxane: Electron Microscope Studies , 1991 .

[10]  R. Hikmet,et al.  Cholesteric Networks Containing Free Molecules , 1991 .

[11]  P. Cladis,et al.  ‘Thermodynamic, structural and morphological studies on liquid-crystalline blue phases’ by H. Stegemeyer, Th. Blümel, K. Hiltrop, H. Onusseit and F. Porsch , 1988 .

[12]  R. Hikmet From Liquid Crystalline Molecules to Anisotropic Gels , 1991 .

[13]  D. Broer,et al.  INSITU PHOTOPOLYMERIZATION OF ORIENTED LIQUID-CRYSTALLINE ACRYLATES .3. ORIENTED POLYMER NETWORKS FROM A MESOGENIC DIACRYLATE , 1989 .