Synthesis of (±)-hirsutene by a catalytic allylpalladium-alkyne cyclization/carbonylation cascade

[1]  W. Oppolzer,et al.  Palladium-Catalyzed "Metallo-Ene"-Type Cyclization/Vinylstannane Coupling of 1-Acetoxy-octa-2,7-dienes and 1-Acetoxy-oct-2-en-7-ynes , 1993 .

[2]  W. Oppolzer,et al.  Formal Synthesis of (±)-Coriolin by Diastereocontrolled Nickel(0)-Catalyzed 'Metallo-ene-type' Cyclization/Methoxycarbonylation , 1992, CHIMIA.

[3]  K. McNamara,et al.  Use of dilithiomethane equivalent in a novel one-flask [2 + 1 + 2] cyclopentannulation reaction: a highly efficient total synthesis of (.+-.)-hirsutene. , 1992 .

[4]  R. Keese,et al.  Synthesis of [5.5.5.5]fenestranes by pd-catalyzed carbonylation-cyclisation , 1992 .

[5]  M. Franck-Neumann,et al.  Accès au squelette triquinanique linéaire par l'intermédiaire de dérivés bicyclo [2.1.0] pentaniques. Synthèse totale d'un triquinane, le (±) hirsutène , 1992 .

[6]  W. Oppolzer,et al.  Enantioselective synthesis of (+)-3-isorauniticine via a catalytic tandem palladium-ene/carbonylation reaction , 1991 .

[7]  R. DeVita,et al.  Direct syntheses of polyfused ring systems by intramolecular tandem palladium-ene/Heck insertion reactions , 1991 .

[8]  R. Grigg,et al.  Alkylpalladium(II) species. Reactive intermediates in a bis-cyclisation route to strained polyfused ring systems. , 1991 .

[9]  W. Oppolzer,et al.  Preparation of a Key Intermediate for the Synthesis of the (±)‐Pentalenolactone E Methyl Ester by Catalytic ‘Palladium‐Ene Cyclization’/Methoxycarbonylation , 1991 .

[10]  L. Paquette,et al.  Sequential Annulation in Molecular Construction. A Short, Stereocontrolled Synthesis of (±)‐Hirsutene , 1991 .

[11]  A. Greene,et al.  Asymmetric approach to Pauson-Khand bicyclization. Enantioselective formal synthesis of hirsutene , 1990 .

[12]  M. Abelman,et al.  Construction of quaternary carbon centers by palladium-catalyzed intramolecular alkene insertions. Total synthesis of the Amaryllidaceae alkaloids (.+-.)-tazettine and (.+-.)-6a-epipretazettine , 1990 .

[13]  Ayusman Sen,et al.  Insertion of olefins into palladium(II)-acyl bonds. Mechanistic and structural studies , 1990 .

[14]  D. Sternbach,et al.  Synthesis of polyquinanes. 3. The total synthesis of (.+-.)-hirsutene: the intramolecular Diels-Alder approach , 1990 .

[15]  W. Oppolzer Regio- and stereocontrolled catalytic palladium- and nickel 'ene-type' cyclizations , 1990 .

[16]  G. Bernardinelli,et al.  Palladium catalyzed cyclizations of enantiomerically pure acyclic 4-acetoxy-2,8-nonadienes: Efficient chirality transfer , 1990 .

[17]  S. Ghosh,et al.  Cyclopentanoid allylsilanes in synthesis : A stereoselective synthesis of (+)-hirsutene , 1990 .

[18]  J. Cossy,et al.  Synthese totale du (±) hirsutene , 1990 .

[19]  D. Clive,et al.  Formation of cis-fused cyclopentanoids by Michael addition and radical cyclization , 1989 .

[20]  W. Oppolzer Intramolekulare stöchiometrische (Li, Mg, Zn) und katalytische (Ni, Pd, Pt) Metallo-En-Reaktionen in der Organischen Synthese† , 1989 .

[21]  T. Keller,et al.  Diastereocontrolled nickel(0)- and palladium(0) catalyzed “metallo-ene-type” cyclizations/carbonylations , 1989 .

[22]  W. Oppolzer Intramolecular, Stoichiometric (Li, Mg, Zn) and Catalytic (Ni, Pd, Pt) Metallo‐Ene Reactions in Organic Synthesis [New Synthetic Methods (75)] , 1989 .

[23]  K. Sharpless,et al.  Vicinal diol cyclic sulfates. Like epoxides only more reactive , 1988 .

[24]  D. Sidler,et al.  A general method for the preparation of carbonyl compounds and butenolides from organomanganese pentacarbonyl complexes , 1988 .

[25]  D. Hua,et al.  Asymmetric synthesis of (+)-hirsutene , 1988 .

[26]  C. Switzer,et al.  Nickel-catalyzed intramolecular allylation of alkenes and alkynes coupled with β-elimination or carbonylation , 1988 .

[27]  B. Disanayaka,et al.  Application of the de Mayo reaction to the preparation of tricyclo[6.3.0.02,6]undecanes: a photochemical synthesis of (.+-.)-hirsutene , 1987 .

[28]  G. Mehta,et al.  A general approach to linearly fused triquinane natural products: total syntheses of (±)-hirsutene, (±)-coriolin, and (±)-capnellene , 1986 .

[29]  T. Livinghouse,et al.  Synthetic applications of the tandem aldol condensation-radical cyclization sequence. A new and highly convergent method for the annulation of carbocycles , 1985 .

[30]  D. Rakiewicz,et al.  Radical-initiated polyolefinic cyclizations in linear triquinane synthesis. model studies and total synthesis of (±)-hirsutene , 1985 .

[31]  R. L. Funk,et al.  Intramolecular cycloaddition reactions of exocyclic nitrones: Application in the total synthesis of terpenes , 1985 .

[32]  A. Ragauskas,et al.  A synthesis of hirsutene: a simple route via β-enolization , 1984 .

[33]  J. Norton,et al.  MECHANISM OF ACETYLENE AND OLEFIN INSERTION INTO PALLADIUM-CARBON Σ BONDS , 1984 .

[34]  R. Little,et al.  CONSEQUENCES OF INTRAMOLECULAR DIYL TRAPPING REACTIONS USING UNACTIVATED DIYLOPHILES. A SHORT, CONVERGENT SYNTHESIS OF HIRSUTENE , 1983 .

[35]  J. Howbert,et al.  Synthetic studies on arene-olefin cycloadditions -III- total synthesis of (±)-hirsutene☆ , 1982 .

[36]  R. Little,et al.  Intramolecular diyl trapping. Total synthesis of dl-hirsutene , 1981 .

[37]  T. Hudlický,et al.  Total synthesis of (.+-.)-hirsutene , 1980 .

[38]  R. M. Scarborough,et al.  A stereospecific total synthesis of (.+-.)-methylenomycin A and its epimer, (.+-.)-epimethylenomycin A , 1980 .

[39]  A. Greene Iterative three-carbon annelations. Synthesis of (±)-hirsutene , 1980 .

[40]  K. Akimoto,et al.  A new, stereocontrolled synthesis of cis,anti,cis-tricyclo[6.3.0.02,6]undecanes. Total synthesis of (.+-.)-hirsutene , 1979 .

[41]  R. Hoffmann,et al.  The olefin insertion reaction , 1978 .

[42]  M. Nishizawa,et al.  Organoselenium chemistry. A facile one-step synthesis of alkyl aryl selenides from alcohols , 1976 .

[43]  K. Sharpless,et al.  Olefin synthesis. Rate enhancement of the elimination of alkyl aryl selenoxides by electron-withdrawing substituents , 1975 .