Salt Effects in Liquid-Liquid Equilibria

The effect of lithium chloride, sodium chloride and potassium chloride on the distribution of acetic acid, propionic acid and butyric acid between benzene and water at 25° C has been studied. The method of Hand' which has previously been used to correlate tie line data in salt-free ter.nar.y systems, has now been successfully employed to correlate distribution data for quaternary systems containing salt. The slope and intercept of the Hand equations have been expressed as linear functions of the salt concentration in each system studied. Equations for slope and intercept possessing high statistical significance have been formulated using a linear regression in two variables. The order of decreasing salting out on a weight basis is