REVIEW: A review on biomass torrefaction process and product properties for energy applications

Abstract Torrefaction of biomass can be described as a mild form of pyrolysis at temperatures typically ranging between 200 and 300°C in an inert and reduced environment. Common biomass reactions during torrefaction include devolatilization, depolymerization, and carbonization of hemicellulose, lignin, and cellulose. The torrefaction process produces a brown to black uniform solid product, as well as condensable (water, organics, and lipids) and Noncondensable gases (CO2, CO, and CH4). Typically during torrefaction, 70% of the mass is retained as a solid product, containing 90% of the initial energy content, while 30% of the lost mass is converted into condensable and noncondensable products. The system’s energy efficiency can be improved by reintroducing the material lost during torrefaction as a source of heat. Torrefaction of biomass improves its physical properties like grindability; particle shape, size, and distribution; pelletability; and proximate and ultimate composition like moisture, carbon and...

[1]  T. Reed,et al.  Densified biomass: a new form of solid fuel , 1978 .

[2]  Emmanuel G. Koukios,et al.  Progress in Thermochemical, Solid-State Refining of Biofuels — From Research to Commercialization , 1993 .

[3]  W. Kauman CONTRIBUTION TO THE THEORY OF CELL COLLAPSE IN WOOD: INVESTIGATIONS WITH EUCALYPTUS REGNANS , 1960 .

[4]  T. O. Rodrigues,et al.  EFFECTS OF TORREFACTION ON ENERGY PROPERTIES OF Eucalyptus grandis WOOD , 2009 .

[5]  S. Sadaka,et al.  Improvements of biomass physical and thermochemical characteristics via torrefaction process , 2009 .

[6]  E. Anklam,et al.  Impact of the roasting degree of coffee on the in vitro radical scavenging capacity and content of acrylamide , 2007 .

[7]  Mark T. Holtzapple,et al.  Producing fuels and chemicals from lignocellulosic biomass , 2008 .

[8]  J. R. Hess,et al.  Formulation, Pretreatment, and Densification Options to Improve Biomass Specifications for Co-Firing High Percentages with Coal , 2012 .

[9]  L. S. Esteban,et al.  Evaluation of different strategies for pulverization of forest biomasses , 2006 .

[10]  Jenny M. Jones,et al.  Torrefaction of reed canary grass, wheat straw and willow to enhance solid fuel qualities and combustion properties , 2008 .

[11]  C. Aring,et al.  A CRITICAL REVIEW , 1939, Journal of neurology and psychiatry.

[12]  Buchala,et al.  Glycerol is a suberin monomer. New experimental evidence for an old hypothesis , 1999, Plant physiology.

[13]  Kj Krzysztof Ptasinski,et al.  Torrefaction of wood: Part 2. Analysis of products , 2006 .

[14]  P. Bergman The TOP process , 2022 .

[15]  P. Kärenlampi,et al.  Effect of relative humidity on thermal degradation of Norway spruce (Picea abies) wood , 2008, Journal of Wood Science.

[16]  P. Kärenlampi,et al.  Cell Wall Porosity in Norway Spruce Wood as Affected by High-Temperature Drying , 2011 .

[17]  H. Jameel,et al.  Changes in pore size distribution during the drying of cellulose fibers as measured by differential scanning calorimetry , 2006 .

[18]  C. Sterling EFFECT OF MOISTURE AND HIGH TEMPERATURE ON CELL WALLS IN PLANT TISSUES , 1955 .

[19]  P. Lehtikangas Quality properties of fuel pellets from forest biomass , 1999 .

[20]  Mj Mark Prins,et al.  Thermodynamic analysis of biomass gasification and torrefaction , 2005 .

[21]  J. P. Bourgeois,et al.  Torrefied wood from temperate and tropical species. Advantages and prospects , 1984 .

[22]  D. Mohan,et al.  Pyrolysis of Wood/Biomass for Bio-oil: A Critical Review , 2006 .

[23]  Gui-jun Wang,et al.  Pretreatment of biomass by torrefaction , 2011 .

[24]  P.C.A. Bergman,et al.  Torrefaction for biomass co-firing in existing coal-fired power stations BIOCOAL , 2005 .

[25]  J. Boon,et al.  Preservation of d-glucose-oligosaccharides in cellulose chars , 1993 .

[26]  X. Bi,et al.  Rate and peak concentrations of off-gas emissions in stored wood pellets--sensitivities to temperature, relative humidity, and headspace volume. , 2009, The Annals of occupational hygiene.

[27]  S. Mani,et al.  Impact of torrefaction on the grindability and fuel characteristics of forest biomass. , 2011, Bioresource technology.

[28]  L. Berglund,et al.  Modeling of cell wall drying stresses in wood , 2002, Wood Science and Technology.

[29]  P. Kärenlampi,et al.  Phase transformations of wood cell wall water , 2005, Journal of Wood Science.

[30]  Thomas A. Milne,et al.  Direct mass-spectrometric studies of the pyrolysis of carbonaceous fuels: III. Primary pyrolysis of lignin , 1986 .

[31]  André Faaij,et al.  Pre-treatment technologies, and their effect on international bioenergy supply chain logistics. Techno-economic evaluation of torrefaction, fast pyrolysis and pelletisation , 2008 .

[32]  Kozo Kanayama,et al.  Destabilization of wood microstructure caused by drying , 2011 .

[33]  Alfred J. Stamm,et al.  Thermal Degradation of Wood and Cellulose , 1956 .

[34]  H. Lindberg,et al.  The effect of drying on wood fracture surfaces from specimens loaded in wet condition , 1998, Wood Science and Technology.

[35]  K.H.J. Buschow,et al.  Encyclopedia of Materials: Science and Technology , 2004 .

[36]  H. Pereira,et al.  Influence of steam heating on the properties of pine (Pinus pinaster) and eucalypt (Eucalyptus globulus) wood , 2007, Wood Science and Technology.

[37]  Paul T. Williams,et al.  The influence of temperature and heating rate on the slow pyrolysis of biomass , 1996 .

[38]  René Guyonnet,et al.  Energy requirement for fine grinding of torrefied wood , 2010 .

[39]  S. Sokhansanj,et al.  Development of laboratory studies on the off-gassing of wood pellets , 2010 .

[40]  Fred Shafizadeh,et al.  Chemical composition and thermal analysis of cottonwood , 1971 .

[41]  R. Guyonnet,et al.  Thermal treatment of wood: analysis of the obtained product , 1989, Wood Science and Technology.

[42]  Unfccc Kyoto Protocol to the United Nations Framework Convention on Climate Change , 1997 .

[43]  J. Bourgois,et al.  Characterization and analysis of torrefied wood , 1988, Wood Science and Technology.

[44]  Kj Krzysztof Ptasinski,et al.  Torrefaction of wood: Part 1. Weight loss kinetics , 2006 .

[45]  S. Pipatmanomai,et al.  Overview and Experiences of Biomass Fluidized Bed Gasification in Thailand , 2011 .

[46]  J. J. Pis,et al.  Influence of torrefaction on the grindability and reactivity of woody biomass , 2008 .

[47]  William J. Norton Part III , 1916, Transactions of the American Institute of Electrical Engineers.

[48]  J. Kiel,et al.  Torrefaction for biomass upgrading , 2005 .

[49]  A. Demirbaş Pyrolysis Mechanisms of Biomass Materials , 2009 .

[50]  P. Kärenlampi,et al.  Three mechanisms affecting the mechanical properties of spruce wood dried at high temperatures , 2010, Journal of Wood Science.

[51]  S. Sokhansanj,et al.  Grinding performance and physical properties of wheat and barley straws, corn stover and switchgrass , 2004 .

[52]  F. Shafizadeh Pyrolytic Reactions and Products of Biomass , 1985 .

[53]  M. Dietenberger,et al.  Wood Products: Thermal Degradation and Fire , 2001 .

[54]  Jian Deng,et al.  Pretreatment of agricultural residues for co-gasification via torrefaction , 2009 .

[55]  L. Berglund,et al.  Effects of an impregnation procedure for prevention of wood cell wall damage due to drying , 2001, Wood Science and Technology.

[56]  H. Paulapuro,et al.  Quantification of water in different states of interaction with wood pulp fibres , 1996 .

[57]  Barry Turner,et al.  United Nations (UN) , 2009 .