Pressure Oscillations During Extrusion of Polyethylene. Part I

Abstract One of the basic technical and economic problems in the manufacture of plas- tics is improving the rate of production without adversely affecting the surface of the product. When the rate of extrusion is gradually increased above the critical value of rate of shear, γ ≥ γc (or the corresponding critical shear stress σ12 ≥ σ12, c), the extrudate becomes rough, distorted, and fractured.), The phenomenon, known as “melt fracture”, hasbeen investigated by many authors during the last 30 years, e.g., see Refs. 14, and reviewed by others [5–9]. Melt fracture is observed for all polymers and plastics. However, several types of distortion with such colorful names as sharkskin and orange peel have been observed for one but not for another extruded material. In this article we re-restrict ourselves to the types of distortions observed for linear, high-density polyethylene (HDPE).

[1]  B. Stalínski Structural Features of Rare Earth Hydrides* , 1985 .

[2]  L. Utracki,et al.  Pressure Oscillation During Extrusion of Polyethylenes. II , 1984 .

[3]  A. Weill Capillary flow of linear polyethylene melt: sudden increase of flow rate , 1980 .

[4]  R. Chǔjǒ,et al.  Application of Catastrophe Theory to Draw Resonance , 1979 .

[5]  J. Cuculo,et al.  Polymer Flow Instability: A Review and Analysis , 1976 .

[6]  L. Utracki,et al.  A method for the measurement of the true die swell of polymer melts , 1975 .

[7]  A. Murthy Flow Instabilities in a Capillary Rheometer for an Elastic Polymer Solution , 1974 .

[8]  G. V. Vinogradov,et al.  Viscoelastic properties and flow of narrow distribution polybutadienes and polyisoprenes , 1972 .

[9]  T. Takata,et al.  Vinyl polymerization by metal complexes. III. Vinyl polymerization initiated by oligoamide and cupric ion system , 1972 .

[10]  J. Holomek,et al.  Unstable flow of amorphous polymers through capillaries I. Velocity profiles of polymer having discontinuous flow curve , 1971 .

[11]  James L White,et al.  Polymer Melt Flow Instabilities in Extrusion: Investigation of the Mechanism and Material and Geometric Variables , 1971 .

[12]  Jacqueline I. Kroschwitz,et al.  Encyclopedia of Polymer Science and Technology , 1970 .

[13]  H. Schreiber Molecular dependence of flow instability in polyethylene , 1969 .

[14]  J. Lupton,et al.  Melt flow of polyethylene at high rates , 1965 .

[15]  J. Tordella Unstable flow of molten polymers: A second site of melt fracture , 1963 .

[16]  E. B. Bagley,et al.  Filament distortion and die entry angle effects in polyethylene extrusion , 1960 .

[17]  H. Schott,et al.  Flow Irregularities in the Extrusion of Polyethylene Melts , 1959 .

[18]  E. B. Bagley End Corrections in the Capillary Flow of Polyethylene , 1957 .

[19]  J. Tordella Fracture in the Extrusion of Amorphous Polymers through Capillaries , 1956 .

[20]  Frederick R. Eirich,et al.  Rheology : theory and applications , 1956 .

[21]  S. H. Maron,et al.  Direct Determination of the Flow Curves of Non‐Newtonian Fluids , 1952 .

[22]  R. S. Spencer,et al.  The viscous flow of molten polystyrene. , 1948, Journal of colloid science.