Reactive intermediates: a transient electrophilic phosphinidene caught in the act.

that have made a stunning impact on the preparative and in-dustrial scale syntheses of small molecules and polymericmaterials. It is tempting to extend the relationship for low-valent species that is based on the similar electronegativitiesof the element phosphorus and the diagonally relatedcarbon to these transition-metal complexes.

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