Reaction de la bromo-3 pyridine avec le diisopropylamidure de lithium. Mecanismes de metallation et de migration d'halogene. Regioselectivite de l'addition polaire sur la pyridyne-3,4

[1]  T. Kress Direct metalation of pyrimidine. Synthesis of some 4-substituted pyrimidines , 1979 .

[2]  M. Mallet,et al.  Nouvelles réactions d'halogenopyridines avec le n-butyllithium. proposition d'un mécanisme par métallation et migration du brome , 1979 .

[3]  J. Bartmess,et al.  Equilibrium acidities of carbon acids. VI. Establishment of an absolute scale of acidities in dimethyl sulfoxide solution , 1975 .

[4]  J. Bunnett,et al.  Relative reactivities of ammonia and amide ion in addition to 4-chlorobenzyne , 1973 .

[5]  J. Bunnett Base-catalyzed halogen dance, and other reactions of aryl halides , 1972 .

[6]  Ralph G. Pearson,et al.  Symmetry rules for chemical reactions , 1971 .

[7]  Kenichi Fukui,et al.  Recognition of stereochemical paths by orbital interaction , 1971 .

[8]  J. Bunnett,et al.  Evidence for a radical mechanism of aromatic "nucleophilic" substitution , 1970 .

[9]  Craig L. Smith,et al.  Unusual influence of nitrogen on rates of anion formation. Hydrogen-deuterium exchange of pyridine and the diazines , 1969 .

[10]  E. Biehl,et al.  Orientation and reactivity in nucleophilic addition to arynes possessing charged substituents. I. Orientation and reactivity in nucleophilic addition to benzyne-3- and -4-carboxylate , 1969 .

[11]  C. Pyun,et al.  Orientation, Reactivity, and Mechanism in the Addition of Methanol to 4-Chlorobenzyne1 , 1966 .

[12]  T. Kauffmann,et al.  Hetarine II. Nucleophile Substitutionsreaktionen an Halogen‐Pyridinen , 1962 .

[13]  R. Huisgen,et al.  Nucleophile aromatische Substitutionen, XIII. Der Nachweis löslicher Komplexe aus Lithiumpiperidid und Lithiumhalogeniden , 1960 .

[14]  John D. Roberts,et al.  Orientation in Aminations of Substituted Halobenzenes , 1956 .

[15]  H. French,et al.  Some Reactions of 3-Pyridyllithium1 , 1951 .

[16]  W. Langham,et al.  The Application of the Halogen—Metal Interconversion Reaction to Syntheses with Isotopic Carbon1 , 1948 .

[17]  H. Gilman,et al.  Organolithium Compounds of Pyridine and Quinoline , 1940 .