Coalescence of a Ferrofluid Drop at Its Bulk Surface with or without a Magnetic Field.

The coalescence of a ferrofluid drop at its bulk surface, with or without a magnetic field, was investigated experimentally by a high-speed camera. Shape deformations of both the pendant ferrofluid drop and the bulk surface in the axial direction were observed during the approaching process even in the absence of a magnetic field. The angle of the upper pendant peak at the first contact decreases with the magnetic flux density, while the lower ferrofluid peak displays an opposite trend. The coalescing width of the ferrofluid drop follows a power-law relationship. The exponent of 0.64 under medium and high magnetic fields as well as the case without magnetic field confirms the inertial regime of drop coalescence. Under the low magnetic field, the significant exponent increasing from 0.59 to 3.02 at about 4 ms is in coincidence with the sudden change to a smooth coalescing section according to the visualized images. A high-speed microparticle image velocimetry (micro-PIV) technique was employed with a transparent model fluid to reveal the flow fields during the drop coalescence instead of opaque ferrofluids.

[1]  S. Hardt,et al.  Manipulation and control of droplets on surfaces in a homogeneous electric field , 2022 .

[2]  Siddhartha Das,et al.  Coalescence of Microscopic Polymeric Drops: Effect of Drop Impact Velocities. , 2021, Langmuir : the ACS journal of surfaces and colloids.

[3]  J. Zhang,et al.  Digital Microfluidics: Magnetic Transportation and Coalescence of Sessile Droplets on Hydrophobic Surfaces. , 2021, Langmuir : the ACS journal of surfaces and colloids.

[4]  M. A. Bijarchi,et al.  Experimental investigation of on-demand ferrofluid droplet generation in microfluidics using a Pulse-Width Modulation magnetic field with proposed correlation , 2021 .

[5]  Hongbin Yang,et al.  Coalescence behavior of aqueous drops in water-in-oil emulsions under high-frequency pulsed AC fields , 2021 .

[6]  L. Yeo,et al.  Coalescence of Droplets in a Microwell Driven by Surface Acoustic Waves. , 2021, Langmuir : the ACS journal of surfaces and colloids.

[7]  M. A. Bijarchi,et al.  Experimental investigation on the dynamics of on-demand ferrofluid drop formation under a pulse-width-modulated non-uniform magnetic field. , 2020, Langmuir : the ACS journal of surfaces and colloids.

[8]  J. Bacri,et al.  Magnetic field driven deformation, attraction and coalescence of non-magnetic aqueous droplets in an oil based ferrofluid. , 2020, Langmuir : the ACS journal of surfaces and colloids.

[9]  Huaizhi Li,et al.  Self-sustained coalescence-breakup cycles of ferrodrops under a magnetic field. , 2019, Langmuir : the ACS journal of surfaces and colloids.

[10]  M. I. Menéndez,et al.  Surfactant-Mediated Solubilization of Magnetically Separable Nanocatalysts for the Oxidation of Alcohols , 2019, ACS omega.

[11]  E. Sergeeva,et al.  Inkjet Printing in Liquid Media: Intra-Volumetric Drop Coalescence in Polymers , 2019, Coatings.

[12]  A. Dalal,et al.  Coalescence dynamics of unequal sized drops , 2019, Physics of Fluids.

[13]  B. Fleck,et al.  Effects of magnetic field on the spreading dynamics of an impinging ferrofluid droplet. , 2018, Journal of colloid and interface science.

[14]  G. Mistura,et al.  Division of Ferrofluid Drops Induced by a Magnetic Field. , 2018, Langmuir : the ACS journal of surfaces and colloids.

[15]  D. Langevin,et al.  Instability of Emulsions Made with Surfactant-Oil-Water Systems at Optimum Formulation with Ultralow Interfacial Tension. , 2018, Langmuir : the ACS journal of surfaces and colloids.

[16]  Q. Liao,et al.  Dynamic behaviors of the coalescence between two droplets with different temperatures simulated by the VOF method , 2018 .

[17]  J. M. Bush,et al.  Thermal delay of drop coalescence , 2017, Journal of Fluid Mechanics.

[18]  M. Kraume,et al.  Drop coalescence in technical liquid/liquid applications: a review on experimental techniques and modeling approaches , 2017 .

[19]  Huaizhi Li,et al.  Formation and breakup dynamics of ferrofluid drops , 2016 .

[20]  Dominique M. Roberge,et al.  Liquid–liquid flow regimes and mass transfer in various micro-reactors , 2016 .

[21]  G. Żyła,et al.  Paramagnetic ionic liquids for advanced applications: A review , 2016 .

[22]  Y. Shikhmurzaev,et al.  Coalescence of liquid drops: Different models versus experiment , 2012, 1211.7212.

[23]  Michael T Harris,et al.  The inexorable resistance of inertia determines the initial regime of drop coalescence , 2012, Proceedings of the National Academy of Sciences.

[24]  J. M. Bush,et al.  The influence of surface tension gradients on drop coalescence , 2009 .

[25]  Kohsei Takehara,et al.  The initial coalescence of miscible drops , 2007 .

[26]  F. Blanchette,et al.  Partial coalescence of drops at liquid interfaces , 2006 .

[27]  J. Weis,et al.  The structure of ferrofluids: A status report , 2005 .

[28]  Chih-Ming Ho,et al.  Scaling law in liquid drop coalescence driven by surface tension , 2004 .

[29]  An-Bang Wang,et al.  On some common features of drop impact on liquid surfaces , 2004 .

[30]  T. A. Hatton,et al.  (2015). Magnetic surfactants. Current Opinion in Colloid and Interface Science , 20 (3), 140-150. , 2016 .