Detection of a Noble Gas Molecular Ion, 36ArH+, in the Crab Nebula

We Are Stardust Most of the universe's chemical elements were produced in stars, with the heaviest elements being produced when stars explode. Barlow et al. (p. 1343) used the Herschel Space Observatory to obtain submillimeter spectra of the Crab Nebula, the remains of a stellar explosion that was witnessed on Earth in 1054 AD, and detected the first evidence of a noble gas-containing molecular ion in space—36ArH+. Koo et al. (p. 1346) obtained near-infrared spectroscopic observations of the remains of another stellar explosion, Cassiopeia A, with the Palomar 5-m Hale telescope, and found evidence that a substantial amount of phosphorus was formed in the explosion. Among the six elements essential for life (hydrogen, carbon, nitrogen, oxygen, phosphorus, and sulfur), only the origin of phosphorus remained to be confirmed by observation. Spectroscopic observations of the remains of stellar explosions confirm that argon-36 and phosphorus are produced in such energetic events. Noble gas molecules have not hitherto been detected in space. From spectra obtained with the Herschel Space Observatory, we report the detection of emission in the 617.5- and 1234.6-gigahertz J = 1-0 and 2-1 rotational lines of 36ArH+ at several positions in the Crab Nebula, a supernova remnant known to contain both molecular hydrogen and regions of enhanced ionized argon emission. Argon-36 is believed to have originated from explosive nucleosynthesis in massive stars during core-collapse supernova events. Its detection in the Crab Nebula, the product of such a supernova event, confirms this expectation. The likely excitation mechanism for the observed 36ArH+ emission lines is electron collisions in partially ionized regions with electron densities of a few hundred per centimeter cubed.

[1]  O. Krause,et al.  A COOL DUST FACTORY IN THE CRAB NEBULA: A HERSCHEL STUDY OF THE FILAMENTS , 2012, 1209.5677.

[2]  Christine D. Wilson,et al.  SUBMILLIMETER LINE SPECTRUM OF THE SEYFERT GALAXY NGC 1068 FROM THE HERSCHEL-SPIRE FOURIER TRANSFORM SPECTROMETER , 2012, 1208.6132.

[3]  J. Cernicharo Laboratory astrophysics and astrochemistry in the Herschel/ALMA era , 2012 .

[4]  Z. K. Curtis,et al.  H2 temperatures in the Crab Nebula , 2011, 1112.1568.

[5]  T. Roellig,et al.  PROPERTIES AND SPATIAL DISTRIBUTION OF DUST EMISSION IN THE CRAB NEBULA , 2011, 1205.2062.

[6]  Z. K. Curtis,et al.  A SURVEY OF MOLECULAR HYDROGEN IN THE CRAB NEBULA , 2011, 1103.6043.

[7]  O. Krause,et al.  MESS (Mass-loss of Evolved StarS), a Herschel key program , 2010, 1012.2701.

[8]  S. Ott,et al.  Herschel Space Observatory - An ESA facility for far-infrared and submillimetre astronomy , 2010, 1005.5331.

[9]  S. J. Liu,et al.  Herschel : the first science highlights Special feature L etter to the E ditor The Herschel-SPIRE instrument and its in-flight performance , 2010 .

[10]  H. Roussel,et al.  In-flight calibration of the Herschel-SPIRE instrument , 2010, 1005.5073.

[11]  G. Savini,et al.  Black hole accretion and star formation as drivers of gas excitation and chemistry in Markarian 231 , 2010, 1005.2877.

[12]  N. Jaidane,et al.  Collision-induced rotational excitation of SiH+ by He atom at low temperatures , 2009 .

[13]  J. J. Hester,et al.  The Crab Nebula: An Astrophysical Chimera , 2008 .

[14]  R. Wiens,et al.  Constraints on Neon and Argon Isotopic Fractionation in Solar Wind , 2007, Science.

[15]  J. Severinghaus,et al.  A redetermination of the isotopic abundances of atmospheric Ar , 2006 .

[16]  L. H. Andersen,et al.  Dissociative recombination of rare gas hydride ions: II. ArH+ , 2005 .

[17]  Holger S. P. Müller,et al.  The Cologne Database for Molecular Spectroscopy, CDMS: a useful tool for astronomers and spectroscopists , 2005 .

[18]  R. Fesen,et al.  The Nature of [Ar III]-Bright Knots in the Crab Nebula , 2001, astro-ph/0108219.

[19]  J. Tennyson,et al.  Electron-impact rotational excitation of CH+ , 1999 .

[20]  E. P. Hunter,et al.  Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update , 1998 .

[21]  P. Cox,et al.  An ISO Long Wavelength Spectrometer detection of CH in NGC 7027 and an HeH + upper limit , 1997 .

[22]  D. Arnett,et al.  Supernovae and Nucleosynthesis , 1996 .

[23]  A. Uomoto,et al.  Extraordinary Line-emitting Knots in the Crab Nebula , 1994 .

[24]  J. Graham,et al.  Infrared spectroscopy and imaging of the Crab Nebula , 1990 .

[25]  R. P. Lowe,et al.  Search for HeH+ in NGC 7027 , 1988 .

[26]  R. Fesen,et al.  Recent Developments Concerning the Crab Nebula , 1985 .

[27]  Joel F. Liebman,et al.  Evaluated Gas Phase Basicities and Proton Affinities of Molecules; Heats of Formation of Protonated Molecules , 1984 .

[28]  S. C. Snyder,et al.  Chemical accelerator studies of reaction dynamics: Ar^+ + CH4 → ArH^+ + CH3 , 1975 .

[29]  A. C. Roach,et al.  The potential curve of ArH+ and the heats of the reactions Ar++ H2→ ArH++ H and Ar + H2+→ ArH++ H , 1970 .