Microwave‐Assisted Synthesis of (N‐Heterocyclic carbene)MCl Complexes of Group 11 Metals

The use of microwave heating for the synthesis of (N-heterocyclic carbene)-bearing complexes of Cu, Ag and Au allows for a drastic reduction of the reaction times required by conventional heating, while affording comparable or better yields of the desired complexes.

[1]  M. Ingleson,et al.  N-Heterocyclic carbene chemistry of iron: fundamentals and applications. , 2012, Chemical communications.

[2]  Ming‐Tsz Chen,et al.  Well-defined (N-heterocyclic carbene)-Ag(I) complexes as catalysts for A3 reactions. , 2012, Organic & biomolecular chemistry.

[3]  Huanfeng Jiang,et al.  A direct and practical approach for the synthesis of Au(I)-NHC complexes from commercially available imidazolium salts and Au(III) salts , 2012 .

[4]  Xiaofeng Chen,et al.  Well-defined N-heterocyclic carbene silver halides of 1-cyclohexyl-3-arylmethylimidazolylidenes: synthesis, structure and catalysis in A3-reaction of aldehydes, amines and alkynes. , 2011, Dalton transactions.

[5]  S. Nolan.  The development and catalytic uses of N-heterocyclic carbene gold complexes. , 2011, Accounts of chemical research.

[6]  O. Navarro,et al.  Recent advances of metal–nucleophilic carbene complexes in catalysis , 2011 .

[7]  L. Cavallo,et al.  N-heterocyclic carbene complexes of au, pd, and pt as effective catalysts in organic synthesis. , 2011, Topics in current chemistry.

[8]  F. Glorius,et al.  The measure of all rings--N-heterocyclic carbenes. , 2010, Angewandte Chemie.

[9]  C. Cazin,et al.  Copper N-heterocyclic carbene (NHC) complexes as carbene transfer reagents. , 2010, Chemical communications.

[10]  A. Slawin,et al.  Simple and versatile synthesis of copper and silver N-heterocyclic carbene complexes in water or organic solvents. , 2010, Dalton transactions.

[11]  O. Winkelmann,et al.  Microwave‐Assisted Synthesis of N‐Heterocyclic Carbene‐ Palladium(II) Complexes , 2010 .

[12]  C. Kappe,et al.  Microwave-assisted synthesis in water as solvent. , 2007, Chemical reviews.

[13]  J. Clyburne,et al.  Synthesis of Well-Defined N-Heterocyclic Carbene Silver(I) Complexes , 2005 .

[14]  J. Clark,et al.  Energy Efficiency in Chemical Reactions: A Comparative Study of Different Reaction Techniques , 2005 .

[15]  S. Nolan,et al.  Synthesis and Structural Characterization of N-Heterocyclic Carbene Gold(I) Complexes , 2005 .

[16]  I. McKenzie,et al.  A monomeric imidazol-2-ylidene-silver(I) chloride complex: synthesis, structure, and solid state 109Ag and 13C CP/MAS NMR characterization. , 2003, Inorganic chemistry.

[17]  W. Herrmann,et al.  Metallkomplexe heterocyclischer Carbene ‐ ein neues Katalysator‐Strukturprinzip in der homogenen Katalyse , 1995 .