Potential utilization of FGD gypsum and fly ash from a Chinese power plant for manufacturing fire-resistant panels

Abstract The present study investigates the geochemical characteristics of the flue gas desulfurization gypsum (FGD Gp) generated from a pulverized-coal combustion (PCC) power plant in Xinjiang, Northwest China, with special emphasis on manufacturing fire-resistant panels using this FGD Gp as well as the fly ash collected from the same power plant. The physical, mechanical and insulating properties of the manufactured panels are also determined. The FGD Gp is characterized by low trace element concentration and low leachable potential for environment-concerned trace elements, indicating it can be reused with low environmental implication. Fire-resistant panels were successfully made from pure FGD Gp, pure commercial gypsum (CGp) and different FGD Gp/fly ash and CGp/fly ash mixtures. With the same gypsum/fly ash proportion, the FGD Gp/fly ash panels present relatively lower density, lower water absorption and lower mechanical strength, but higher moisture contents and better insulating capacities than the CGp/fly ash panels. The pure FGD Gp panel presents the best insulating capacity (52 min), much higher than that of the pure CGp panel (42.8 min). The mechanical and insulating properties of the panels are reduced with the increasing of fly ash proportion in the mixtures, but even prepared with 80% fly ash, the manufactured panels can still be used as benign fire-resistant panels with no significantly physico-chemical, and mechanical limitations. Therefore, manufacture of fire-resistant panels from FGD-Gp and fly ash is a very promising application for these coal combustion by-products which are substantially being generated in large amounts from Xinjiang power plants. The manufactured fire-resistant panels can be used in large amount as insulating construction and building materials with low environmental implication and high economic value.

[1]  Luis F. Vilches,et al.  Effect of carbonaceous matter contents on the fire resistance and mechanical properties of coal fly ash enriched mortars , 2008 .

[2]  James C. Hower,et al.  Geochemical and mineralogical evidence for a coal-hosted uranium deposit in the Yili Basin, Xinjiang, northwestern China , 2015 .

[3]  Luis F. Vilches,et al.  Development of new fire-proof products made from coal fly ash: the CEFYR project† , 2002 .

[4]  Xavier Querol,et al.  Environmental geochemistry of the feed coals and their combustion by-products from two coal-fired power plants in Xinjiang Province, Northwest China , 2012 .

[5]  J. C. Ballesteros,et al.  Use of FGD gypsum in fire resistant panels. , 2010, Waste management.

[6]  Yutaka Asako,et al.  Fire resistance test for fire protection materials with high water content , 2000 .

[7]  Xavier Querol,et al.  Partitioning of trace inorganic elements in a coal-fired power plant equipped with a wet Flue Gas Desulphurisation system , 2012 .

[8]  Robert Černý,et al.  Flue gas desulfurization gypsum: Study of basic mechanical, hydric and thermal properties , 2007 .

[9]  Luis F. Vilches,et al.  Influence of the type of ash on the fire resistance characteristics of ash-enriched mortars , 2005 .

[10]  Jing Li,et al.  Synthesis of merlinoite from Chinese coal fly ashes and its potential utilization as slow release K-fertilizer. , 2014, Journal of hazardous materials.

[11]  Xavier Querol,et al.  The retention capacity for trace elements by the flue gas desulphurisation system under operational conditions of a co-combustion power plant , 2012 .

[12]  William E. Thacker,et al.  Beneficial use of industrial by-products , 2001 .

[13]  Luis F. Vilches,et al.  Fire Resistance Characteristics of Plates Containing a High Biomass-Ash Proportion , 2007 .

[14]  Prinya Chindaprasirt,et al.  Plaster materials from waste calcium sulfate containing chemicals, organic fibers and inorganic additives , 2011 .

[15]  Takeshi Otaka,et al.  FIRE RESISTANCE CHARACTERISTICS OF MATERIALS WITH POLYMER GELS WHICH ABSORB AQUEOUS SOLUTION OF CALCIUM CHLORIDE , 2004 .

[16]  Luis F. Vilches,et al.  Coal fly ash-containing sprayed mortar for passive fire protection of steel sections , 2005 .

[17]  J. C. Ballesteros,et al.  Influence of a modification of the petcoke/coal ratio on the leachability of fly ash and slag produced from a large PCC power plant. , 2007, Environmental science & technology.

[18]  Luis F. Vilches,et al.  Insulating capacity of fly ash pastes used for passive protection against fire , 2005 .

[19]  Luis F. Vilches,et al.  Recycling potential of coal fly ash and titanium waste as new fireproof products , 2003 .

[20]  P. Sarker,et al.  A comprehensive review on the applications of coal fly ash , 2015 .

[21]  Judith Gurney BP Statistical Review of World Energy , 1985 .

[22]  J. A. Carter,et al.  Pathways of thirty-seven trace elements through coal-fired power plant , 1975 .

[23]  X. Querol,et al.  Trace element mobility in soils seven years after the Aznalcóllar mine spill. , 2008, Chemosphere.

[24]  M. Ahmaruzzaman,et al.  A review on the utilization of fly ash , 2010 .

[25]  Jan-Dirk Herbell,et al.  Utilization of fly ash from coal-fired power plants in China , 2008 .

[26]  Xavier Querol,et al.  High quality of Jurassic Coals in the Southern and Eastern Junggar Coalfields, Xinjiang, NW China: Geochemical and mineralogical characteristics , 2012 .

[27]  Xavier Querol,et al.  Geological controls on the mineralogy and geochemistry of the Beypazari lignite, central Anatolia, Turkey , 1997 .

[28]  Jaime Solís-Guzmán,et al.  High fire resistance in blocks containing coal combustion fly ashes and bottom ash. , 2011, Waste management.