Investigation of Si/SiGe/Si heterostructure implanted by H ion and annealed in vacuum and dry O2 ambient

The 20-nm-thick Si cap layer/74-nm-thick Si"0"."7"2Ge"0"."2"8 epilayer/Si heterostructures implanted by 25keV H^+ ion to a dose of 1x10^1^6cm^-^2 were annealed in ultra-high vacuum ambient and dry O"2 ambient at the temperature of 800^oC for 30min, respectively. Rutherford backscattering/ion channeling (RBS/C), Raman spectra, high-resolution X-ray diffraction (HRXRD) and atomic force microscopy (AFM) were used to characterize the structural characteristics of the Si"0"."7"2Ge"0"."2"8 layer. Investigations by RBS/C demonstrated that the crystal quality of the Si/Si"0"."7"2Ge"0"."2"8/Si heterostructure sample implanted by 25keV H^+ in conjunction with subsequent annealing in dry O"2 ambient is superior to that of identical sample annealing in ultra-high vacuum ambient. The less strain relaxation of SiGe layer of the Si/Si"0"."7"2Ge"0"."2"8/Si heterostructures implanted by H ion and annealed in dry O"2 ambient at the temperature of 800^oC for 30min could be doublechecked by Raman spectra as well as HRXRD, which was compared with that in an identical sample annealed in ultra-high vacuum ambient for identical thermal budget. In addition, the SiGe layer of the H-implanted Si/SiGe/Si heterostructural sample annealed in dry O"2 ambient accompanied by better crystal quality and less strain relaxation made its surface morphology superior to that of the sample annealed in ultra-high vacuum ambient at the temperature of 800^oC for 30min, which was also verified by AFM images.

[1]  G. G. Stokes "J." , 1890, The New Yale Book of Quotations.

[2]  Don Monroe,et al.  Extremely high electron mobility in Si/GexSi1−x structures grown by molecular beam epitaxy , 1991 .

[3]  J. Michler,et al.  Elastic and plastic relaxation in slightly undulated misfitting epitaxial layers ‐ A quantitative approach by three‐dimensional finite element calculations , 1996 .

[4]  Shi-Li Zhang,et al.  Retardation of strain relaxation in Si/SiGe/Si heterostructures during high temperature oxidation , 2002 .

[5]  P ? ? ? ? ? ? ? % ? ? ? ? , 1991 .

[6]  M. Oehme,et al.  New virtual substrate concept for vertical MOS transistors , 1998 .

[7]  C. Peng,et al.  RELAXED SI0.7GE0.3 LAYERS GROWN ON LOW-TEMPERATURE SI BUFFERS WITH LOW THREADING DISLOCATION DENSITY , 1997 .

[8]  Cowern,et al.  Diffusion in strained Si(Ge). , 1994, Physical review letters.

[9]  Theory of electron-mobility degradation caused by roughness with long correlation length in strained-silicon devices , 2003 .

[10]  S. Iyer,et al.  Thermal relaxation of pseudomorphic Si-Ge superlattices by enhanced diffusion and dislocation multiplication , 1989 .

[11]  Huajian Gao,et al.  Strain relaxation and defect formation in heteroepitaxial Si1−xGex films via surface roughening induced by controlled annealing experiments , 1997 .

[12]  Andrew G. Glen,et al.  APPL , 2001 .

[13]  J. W. Matthews,et al.  Defects in epitaxial multilayers: I. Misfit dislocations* , 1974 .

[14]  Bernard S. Meyerson,et al.  High electron mobility in modulation‐doped Si/SiGe , 1991 .

[15]  E. Bugiel,et al.  Relaxed Si1−xGex/Si1−x−yGexCy buffer structures with low threading dislocation density , 1997 .

[16]  Reinhard Carius,et al.  Tensely strained silicon on SiGe produced by strain transfer , 2004 .

[17]  B. Holländer,et al.  Strained silicon FETs on thin SiGe virtual substrates produced by He implantation: effect of reduced self-heating on DC and RF performance , 2004 .

[18]  B. Holländer,et al.  Enhanced strain relaxation of epitaxial SiGe layers on Si(100) after H+ ion implantation , 1999 .

[19]  Thomas A. Langdo,et al.  Controlling threading dislocation densities in Ge on Si using graded SiGe layers and chemical-mechanical polishing , 1998 .

[20]  B. Holländer,et al.  Strain relaxation of pseudomorphic heterostructures after hydrogen or helium ion implantation for virtual substrate fabrication , 2001 .

[21]  S. M. Hu,et al.  Formation of stacking faults and enhanced diffusion in the oxidation of silicon , 1974 .

[22]  W. Dou,et al.  Composition determination of Si/Si1−xGex/Si by photoreflectance spectroscopy , 2004 .

[23]  Lockwood,et al.  Strain-shift coefficients for phonons in Si1-xGex epilayers on silicon. , 1992, Physical review. B, Condensed matter.

[24]  F. Namavar,et al.  Raman scattering studies of Si1-xGex epitaxial layers grown by atmospheric pressure chemical vapor deposition , 1993 .