Ferroelectric thin films for micro-sensors and actuators: a review

This paper reviews deposition, integration, and device fabrication of ferroelectric PbZrxTi1-xO3 (PZT) films for applications in microelectromechanical systems. As examples, a piezoelectric ultrasonic micromotor and pyroelectric infrared detector array are presented. A summary of the published data on the piezoelectric properties of PZT thin films is given. The figures of merit for various applications are discussed. Some considerations and results on operation, reliability, and depolarization of PZT thin films are presented.

[1]  R. Castellano,et al.  Ion‐beam deposition of thin films of ferroelectric lead zirconate titanate (PZT) , 1979 .

[2]  S. Mochizuki,et al.  Preparation of PbTiO3 Thin Films by Sputter Assisted Plasma Chemical Vapor Deposition Method , 1989 .

[3]  G. Dormans,et al.  Measurement of piezoelectric coefficients of ferroelectric thin films , 1994 .

[4]  Y. Nemirovsky,et al.  A thin film pyroelectric detector , 1995 .

[5]  N. Setter,et al.  Gas spectrometry based on pyroelectric thin-film arrays integrated on silicon , 1998 .

[6]  S. B. Krupanidhi,et al.  Excimer laser ablated lead zirconate titanate thin films , 1991 .

[7]  Y. Sakashita,et al.  Metalorganic Chemical Vapor Deposition of c-Axis Oriented PZT Thin Films , 1990 .

[8]  A. Erbil,et al.  Metalorganic chemical vapor deposition of PbTiO3 thin films , 1988 .

[9]  R. Bruchhaus,et al.  Deposition of ferroelectric PZT thin films by planar multi-target sputtering , 1992 .

[10]  Jian Li,et al.  Pzt Interaction with Metal and Oxides Studied by Rutherford Backscattering Spectrometry , 1991 .

[11]  A. Kingon,et al.  Electrodes for ferroelectric thin films , 1993 .

[12]  S. D. Collins,et al.  Microfabricated Lamb wave device based on PZT sol-gel thin film for mechanical transport of solid particles and liquids , 1997 .

[13]  M. J. E. Ulenaers,et al.  Preparation and ferroelectric properties of PbZr0.53Ti0.47O3 thin films by spin coating and metalorganic decomposition , 1991 .

[14]  M. Sayer,et al.  rf planar magnetron sputtering and characterization of ferroelectric Pb(Zr,Ti)O3 films , 1983 .

[15]  M. Okuyama,et al.  Chemical Vapor Deposition of PbTiO3 Thin Film , 1983 .

[16]  Hermann Sandmaier,et al.  Absorbing layers for thermal infrared detectors , 1992 .

[17]  G. Arlt Microstructure and domain effects in ferroelectric ceramics , 1989 .

[18]  Toru Fujii,et al.  Application of lead zirconate titanate thin film displacement sensors for the atomic force microscope , 1995 .

[19]  Fabrication and characterization of PZT thin films for micromotors , 1995 .

[20]  Paul Muralt,et al.  Stabilized Platinum Electrodes for Ferroelectric Film Deposition using Ti, Ta and Zr Adhesion Layers , 1998 .

[21]  R. Reuben,et al.  Torque evaluation of a LIGA fabricated electrostatic micromotor , 1999 .

[22]  C. L. Hernandez,et al.  Microstructural evolution of Pb(Zr, Ti)O_3 thin films prepared by hybrid metallo-organic decomposition , 1992 .

[23]  Paul Muralt,et al.  Piezoelectric actuation of PZT thin-film diaphragms at static and resonant conditions , 1996 .

[24]  A. Morimoto,et al.  Preparation of Pb(Zn_ Ti_ )O_3 Films by Laser Ablation , 1990 .

[25]  N. Setter,et al.  Relaxor behavior and electromechanical properties of Pb(Mg1/3Nb2/3)O3 thin films , 1998 .

[26]  K.K. Li,et al.  Micromachined high frequency ferroelectric sonar transducers , 1997, IEEE Transactions on Ultrasonics, Ferroelectrics and Frequency Control.

[27]  Nicolas Ledermann,et al.  Effective transverse piezoelectric coefficient e31,f of (100)/(001) textured PZT thin films , 1999 .

[28]  Peter Ryser,et al.  Pyroelectric thin-film sensor array , 1997 .

[29]  T. Maeder,et al.  Interferometric study of piezoelectric degradation in ferroelectric thin films , 1995 .

[30]  Katsuhiro Aoki,et al.  Effects of Titanium Buffer Layer on Lead-Zirconate-Titanate Crystallization Processes in Sol-Gel Deposition Technique , 1995 .

[31]  Paul Muralt,et al.  Pb(Zr,Ti)O3 thin films on zirconium membranes for micromechanical applications , 1996 .

[32]  S. Kawai,et al.  Preparation of PbTiO3 thin films at low temperature by an excimer laser ablation technique , 1991 .

[33]  Paul Muralt,et al.  Piezoelectric thin films for MEMS , 1997, Applied Physics Letters.

[34]  Paul Muralt,et al.  Fabrication and characterization of PZT thin-film vibrators for micromotors , 1995 .

[35]  James S. Speck,et al.  DOMAIN CONFIGURATIONS DUE TO MULTIPLE MISFIT RELAXATION MECHANISMS IN EPITAXIAL FERROELECTRIC THIN FILMS. I: THEORY , 1994 .

[36]  K. Tominaga,et al.  Preparation and properties of (Pb,La)(Zr,Ti)O3 thin films by metalorganic chemical vapor deposition , 1992 .

[37]  P. Muralt,et al.  In-plane piezoelectric coefficient of PZT thin films as a function of composition , 1999 .

[38]  Nava Setter,et al.  Photoinduced poling of lead titanate zirconate thin films , 1997 .

[39]  L. E. Cross,et al.  Piezoelectric micromotors for microrobots , 1992 .

[40]  Paul Muralt,et al.  Properties of aluminum nitride thin films for piezoelectric transducers and microwave filter applications , 1999 .

[41]  D. A. Berlincourt,et al.  Piezoelectric Properties of Polycrystalline Lead Titanate Zirconate Compositions , 1960, Proceedings of the IRE.

[42]  Paul Muralt,et al.  Flexural-standing-wave elastic force motor using ZnO and PZT thin film on micromachined silicon membranes for wristwatch applications , 1998 .

[43]  D. Roy,et al.  Excimer laser ablation of ferroelectric Pb(Zr,Ti)O3 thin films with low pressure direct‐current glow discharge , 1992 .

[44]  M.-A. Dubois,et al.  PZT thin film actuated elastic fin micromotor , 1998, IEEE Transactions on Ultrasonics, Ferroelectrics and Frequency Control.

[45]  K. Tominaga,et al.  Preparation of c-Axis-Oriented PbTiO3 Thin Films by MOCVD under Reduced Pressure , 1989 .

[46]  Michael Sayer,et al.  Sol-gel processing of PLZT thin films , 1995 .

[47]  N. Setter,et al.  Microstructural evolution of dense and porous pyroelectric Pb_1−xCa_xTiO_3 thin films , 1999 .

[48]  D. Vijay,et al.  Electrodes for PbZr x Ti1 − x O 3 Ferroelectric Thin Films , 1993 .

[49]  D. Wouters,et al.  Nucleation and orientation of sol-gel pzt-films on pt electrodes , 1997 .

[50]  T. Sands,et al.  Ferroelectric La‐Sr‐Co‐O/Pb‐Zr‐Ti‐O/La‐Sr‐Co‐O heterostructures on silicon via template growth , 1993 .

[51]  A. Tagantsev,et al.  Effect of mechanical boundary conditions on phase diagrams of epitaxial ferroelectric thin films , 1998 .

[52]  Paul Muralt,et al.  Which PZT thin films for piezoelectric microactuator applications , 1998 .

[53]  S. B. Krupanidhi,et al.  Property modification of ferroelectric Pb(Zr,Ti)O3 thin films by low‐energy oxygen ion bombardment during film growth , 1992 .

[54]  Relva C. Buchanan,et al.  Ceramic materials for electronics: Processing, properties, and applications , 1986 .

[55]  K. Budd,et al.  Thin-film ferroelectrics of PZT of sol-gel processing , 1988, IEEE Transactions on Ultrasonics, Ferroelectrics and Frequency Control.

[56]  Tatsuo Shimizu,et al.  Preparation of Pb(Zn0.52Ti0.48)O3 Films by Laser Ablation , 1990 .

[57]  Robert Elliman,et al.  Investigation of Pt/Ti bilayer metallization on silicon for ferroelectric thin film integration , 1994 .

[58]  Paul Muralt,et al.  Texture control of PbTiO3 and Pb(Zr,Ti)O3 thin films with TiO2 seeding , 1998 .

[59]  S. Hayashi,et al.  Preparation and Characterization of Pb-Based Ferroelectric Thin Films , 1991 .

[60]  G. Arlt,et al.  Dielectric properties of fine‐grained barium titanate ceramics , 1985 .

[61]  T. Maeder,et al.  In-Situ Thin Film Growth of PbTiO3 By Multi Target Sputtering , 1994 .

[62]  S. Sinharoy,et al.  PULSED LASER DEPOSITION AND FERROELECTRIC CHARACTERIZATION OF BISMUTH TITANATE FILMS , 1991 .

[63]  S. Desu,et al.  Formation kinetics of PbZr_xTi_1−xO_3 thin films , 1994 .

[64]  Seshu B. Desu,et al.  Low temperature perovskite formation of lead zirconate titanate thin films by a seeding process , 1993 .

[65]  T. Itoh,et al.  Self-excited piezoelectric PZT microcantilevers for dynamic SFM—with inherent sensing and actuating capabilities , 1999 .

[66]  R. Gardiner,et al.  Reduced Pressure MOCVD of C-Axis Oriented BiSrCaCuO Thin Films , 1990 .

[67]  Paul Muralt,et al.  Pb(Zr,Ti)O3 thin films by in-situ reactive sputtering on micromachined membranes for micromechanical applications , 1995 .

[68]  A. Grill,et al.  Layered TaSiN as an oxidation resistant electrically conductive barrier , 1999 .

[69]  G. Dormans,et al.  Modelling of organometallic chemical vapour deposition of lead titanate , 1995 .

[70]  Stefano Carabelli,et al.  Lead zirconate titanate cantilever for noncontact atomic force microscopy , 1999 .

[71]  Xingjiao Li,et al.  Low‐temperature in situ preparation of ferroelectric Pb(Zr0.55Ti0.45)O3 thin films by reactive sputtering , 1993 .

[72]  P. Muralt,et al.  Poling of pyroelectric thin films , 1998 .

[73]  T. Shrout,et al.  Characterization of MOCVD PbTiO3 thin films , 1989 .

[74]  T. Hara,et al.  Barrier Properties for Oxygen Diffusion in a TaSiN Layer , 1997 .

[75]  R. Whatmore,et al.  The growth of ferroelectric oxides by MOCVD , 1989 .

[76]  P. Renaud,et al.  Piezoelectric Cantilever Beams Actuated By PZT Sol-gel Thin Film , 1995, Proceedings of the International Solid-State Sensors and Actuators Conference - TRANSDUCERS '95.

[77]  M. Sayer,et al.  Properties of d.c magnetron-sputtered lead zirconate titanate thin films , 1989 .

[78]  Paul Muralt,et al.  Thin film pyroelectric array as a detector for an infrared gas spectrometer , 1998 .

[79]  K. H. Hardtl,et al.  PbO vapour pressure in the Pb(Ti1−x)O3 system , 1969 .

[80]  M. Kosec,et al.  Effect of Nb Doping on the Microstructure of Sol-Gel-Derived Pzt Thin-Films , 1995 .

[81]  J. Mackenzie,et al.  Crystallization Kinetics Of Metallo-Organics Derived Pzt Thin Film , 1990 .

[82]  T. Maeder,et al.  Conducting Barriers for Direct Contact of PZT Thin Films on Reactive Substrates , 1999 .

[83]  G. Dormans,et al.  Composition-controlled growth of PbTiO3 on SrTiO3 by organometallic chemical vapour deposition , 1992 .

[84]  N. F. de Rooij,et al.  Piezoelectric cantilever beams actuated by PZT sol-gel thin film , 1996 .

[85]  N. Setter,et al.  Gas spectrometry based on a pyroelectric thin film array , 1999 .

[86]  Michael Sayer,et al.  Lead zirconate titanate films by rapid thermal processing , 1991 .

[87]  T. Mihara,et al.  Relationship between Crystal Structure and Chemical Composition of PbTiO3 Thin Films Prepared by Sputter-Assisted Plasma CVD , 1992 .

[88]  Nabeel A. Riza,et al.  High resolution 50 nm linear displacement macroscale meander-line PZT actuator , 1993 .