Treatment of paper mill effluents in a batch-stirred electrochemical tank reactor

Abstract Electrochemical treatment of organic pollutants is a promising treatment technique for substances which are resistant to biodegradation. In this study an electrochemical treatment based on the principle of anodic oxidation was used to treat paper mill effluent from Rakta's Pulp and Paper Company where rice straw is used to produce paper pulp. Experiments were carried out in a cylindrical agitated vessel lined with lead sheet as anode while a concentric cylindrical stainless steel sheet screen was placed as a cathode. The effect of current density, pH, NaCl concentration, impeller rotational speed and temperature on the rate of color and COD removal was studied. The results showed that the use of electrochemical technique reduces the COD from an average value of 5500 to 160. The percentage color removal ranged from 53% to 100% depending on the operating conditions. Energy consumption calculation shows that energy consumption ranges from 4 to 29 kWh/m3 of effluent depending on the operating conditions. The experimental results proved that the electrochemical oxidation is a powerful tool for treating paper mill effluents where rice straw is used as a raw material.

[1]  G Thompson,et al.  The treatment of pulp and paper mill effluent: a review. , 2001, Bioresource technology.

[2]  W. Wirojanagud,et al.  Removal of color, COD and lignin of pulp and paper wastewater using wood ash , 2004 .

[3]  M. M. Zaki,et al.  Mass transfer characteristics of reciprocating screen stack electrochemical reactor in relation to heavy metal removal from dilute solutions , 2007 .

[4]  I. Thakur Screening and identification of microbial strains for removal of colour and adsorbable organic halogens in pulp and paper mill effluent , 2004 .

[5]  Guohua Chen Electrochemical technologies in wastewater treatment , 2004 .

[6]  Ralph E. White,et al.  Comprehensive Treatise of Electrochemistry , 1981 .

[7]  F. Kargı,et al.  Color, TOC and AOX removals from pulp mill effluent by advanced oxidation processes: a comparative study. , 2007, Journal of hazardous materials.

[8]  J. Kallas,et al.  Wet oxidation of concentrated wastewaters of paper mills for water cycle closing , 2000 .

[9]  C. Ackel Controlling wastewater color via coagulation and flotation separation , 1988 .

[10]  D. Rajkumar,et al.  Electrochemical degradation of Reactive Blue 19 in chloride medium for the treatment of textile dyeing wastewater with identification of intermediate compounds , 2007 .

[11]  T. Viraraghavan,et al.  Treatment of pulp and paper mill wastewater--a review. , 2004, The Science of the total environment.

[12]  F. Kobayashi,et al.  Microbial treatment of kraft pulp wastewater pretreated with ozone , 1997 .

[13]  N. Azbar,et al.  Feasibility of physico-chemical treatment and Advanced Oxidation Processes (AOPs) as a means of pretreatment of olive mill effluent (OME) , 2005 .

[14]  Linyang Gu,et al.  Electrochemical oxidation of pulp and paper making wastewater assisted by transition metal modified kaolin. , 2007, Journal of hazardous materials.

[15]  N. Durán,et al.  Photoassisted electrochemical degradation of organic pollutants on a DSA type oxide electrode: process test for a phenol synthetic solution and its application for the E1 bleach Kraft mill effluent. , 2001, Environmental science & technology.

[16]  I. D. Mall,et al.  Treatment of pulp and paper mill wastewaters with poly aluminium chloride and bagasse fly ash , 2005 .

[17]  D. W. Smith,et al.  Color and chlorinated organics removal from pulp mills wastewater using activated petroleum coke. , 2001, Water research.

[18]  B. Han,et al.  Application of electron beam to treatment of wastewater from papermill , 2002 .

[19]  R. Bertazzoli,et al.  Electrodegradation of landfill leachate in a flow electrochemical reactor. , 2005, Chemosphere.

[20]  A. Majcherczyk,et al.  Removal of Chlorophenols and Chlorolignins from Bleaching Effluent by Combined Chemical and Biological Treatment , 1988 .

[21]  Nicolas Kalogerakis,et al.  Electrochemical oxidation of olive oil mill wastewaters. , 2005, Water research.

[22]  Hanqing Yu,et al.  Degradation of lignin in pulp mill wastewaters by white-rot fungi on biofilm. , 2005, Bioresource technology.

[23]  N. Durán,et al.  Photoelectrochemical degradation of lignin , 2000 .

[24]  S. M. Ghoreishi,et al.  Chromophores removal in pulp and paper mill effluent via hydrogenation-biological batch reactors , 2007 .

[25]  I. Thakur,et al.  Removal of colour and detoxification of pulp and paper mill effluent by microorganisms in two step bioreactor , 2004 .

[26]  A. E. Greenberg,et al.  Standard methods for the examination of water and wastewater : supplement to the sixteenth edition , 1988 .

[27]  S. Duff,et al.  Coagulation and precipitation of a mechanical pulping effluent—I. Removal of carbon, colour and turbidity , 1996 .