Cathodoluminescence Study of InP Photonic Structures Fabricated by Dry Etching

Ridge waveguides fabricated by inductively coupled plasma (ICP) etching using chlorine-based gases were studied by spectrum image cathodoluminescence (CL). Structures with different dimensions (height and width) were studied, evidencing the generation of defects during ICP processing. Using the CL spectrum images, the distribution of the stresses induced by the defects was mapped. The residual stresses depend on the dimensions of the waveguides. Using finite-element analysis the strain distribution was reproduced. The initial strain conditions provided a picture of the distribution of the defects generated by the etching process, showing differences between the etched floor, the side-walls of the waveguides, and the unetched top surface. The possible mechanisms for defect formation, as well as the possible identity of the defects, are discussed.

[1]  F. Pommereau,et al.  InP surface properties under ICP plasma etching using mixtures of chlorides and hydrides , 2006, 2006 International Conference on Indium Phosphide and Related Materials Conference Proceedings.

[2]  G. D. Pitt,et al.  The conduction band structure of InP from a high pressure experiment , 1970 .

[3]  F. Pommereau,et al.  Introduction of defects during the dry etching of InP photonic structures: a cathodo-luminescence study , 2008 .

[4]  H. Tan,et al.  Influence of cap layer on implantation induced interdiffusion in InP/InGaAs quantum wells , 2003 .

[5]  P. Daniel Dapkus,et al.  CH4-based dry etching of high Q InP microdisks , 2002 .

[6]  Diffusion and channeling of low‐energy ions: The mechanism of ion damage , 1995 .

[7]  Frederic Pommereau,et al.  Fabrication of low loss two-dimensional InP photonic crystals by inductively coupled plasma etching , 2004 .

[8]  N. Stoffel Molecular dynamics simulations of deep penetration by channeled ions during low‐energy ion bombardment of III–V semiconductors , 1992 .

[9]  P. Petroff,et al.  Photoluminescence studies on radiation enhanced diffusion of dry‐etch damage in GaAs and InP materials , 1996 .

[10]  T. Y. Liu,et al.  Investigation of reactive ion etching induced damage in GaAs–AlGaAs quantum well structures , 1988 .

[11]  R. H. Williams,et al.  Reactive ion etching induced damage in GaAs and Al0.3Ga0.7As using SiCl4 , 1992 .

[12]  F. Pommereau,et al.  Investigation of point defect generation in dry etched InP ridge waveguide structures , 2007 .

[13]  John D. O'Brien,et al.  Quality factors in single-defect photonic-crystal lasers with asymmetric cladding layers , 2002 .

[14]  Magnus Willander,et al.  Stresses and strains in epilayers, stripes and quantum structures of III - V compound semiconductors , 1996 .

[15]  T. E. Everhart,et al.  Determination of Kilovolt Electron Energy Dissipation vs Penetration Distance in Solid Materials , 1971 .

[16]  F. Pommereau,et al.  Cathodoluminescence study of inductively coupled plasma (ICP) etched InP waveguide structures: Influence of the ridge dimension and dielectric capping , 2008 .

[17]  Frederic Pommereau,et al.  Process induced mechanical stress in InP ridge waveguides fabricated by inductively coupled plasma etching , 2008 .

[18]  P D Gianino,et al.  Pressure and stress dependence of the refractive index of transparent crystals. , 1974, Applied optics.