Design of Packed Catalytic Reactors

Publisher Summary This chapter discusses the presently known methods for predicting the performance of nonisothermal continuous catalytic reactors and points out some of the problems that remain to be solved before a complete description of such reactors can be worked out. It focuses on packed catalytic reactors of the heat-exchanger type, in which a major requirement is that enough heat be transferred to control the temperature within permissible limits. To provide a logical framework for the discussion, an example is worked out to illustrate the methods used. There is no question of providing a recipe for designing nonisothermal reactors; methods of working that are useful are presented, and their application to a more or less typical problem is described. This chapter discusses a few reactors one of which is Adiabatic Reactor. Such a reactor with a regular flow pattern is much simpler to work with than one with exchange of heat. Except for resistance to ex- change of material and heat between fluid and catalyst, the space velocity is the only significant space variable. Conditions within a reactor are described with the help of numerical solutions of equations. The concept of a scale model of a reactor is useful because in some situations of practical importance it permits one to predict rather accurately the effects of changing certain design parameters of a reactor even though the kinetics of the reactions are not known, provided other parameters are changed in a corresponding way.

[1]  Harold S. Mickley,et al.  Applied mathematics in chemical engineering , 1939 .

[2]  F. B. Hildebrand,et al.  Methods of Applied Mathematics , 1966 .

[3]  D. Kunii,et al.  Studies on heat transfer near wall surface in packed beds , 1960 .

[4]  R. Sehr The thermal conductivity of catalyst particles , 1958 .

[5]  Thomas J. Hanrattry Nature of wall heat transfer coefficient in packed beds , 1954 .

[6]  George G. O'Brien,et al.  A Study of the Numerical Solution of Partial Differential Equations , 1950 .

[7]  J. M. Smith,et al.  Mass transfer in packed beds , 1955 .

[8]  D. Thoenes,et al.  Mass transfer from spheres in various regular packings to a flowing fluid , 1958 .

[9]  Olaf A. Hougen,et al.  Chemical process principles , 1947 .

[10]  J. M. Smith,et al.  Flow Distribution in Packed Beds , 1953 .

[11]  S. S. Kwong,et al.  Radial Heat Transfer in Packed Beds , 1957 .

[12]  Leon Lapidus,et al.  A computational model for predicting and correlating the behavior of fixed‐bed reactors: I. Derivation of model for nonreactive systems , 1960 .

[13]  Neal R. Amundson,et al.  Applications of Matrix Mathematics to Chemical Engineering Problems , 1955 .

[14]  H. Kramers,et al.  Frequency response analysis of continuous flow systems , 1953 .

[15]  Robert R. White,et al.  Mixing of fluids flowing through beds of packed solids , 1958 .

[16]  Elton J. Cairns,et al.  Longitudinal mixing in packed beds , 1960 .

[17]  Neal R. Amundson,et al.  Chemical reactor stability and sensitivity: II. Effect of parameters on sensitivity of empty tubular reactors , 1956 .

[18]  Y. Chu,et al.  Heat transfer to air flowing through packed tubes , 1952 .

[19]  V. P. Dorweiler,et al.  MASS TRANSFER AT LOW FLOW RATES IN A PACKED COLUMN , 1959 .

[20]  J. Kjær Measurement and calculation of temperature and conversion in fixed-bed catalytic reactors , 1958 .

[21]  S. Walas Reaction kinetics for chemical engineers , 1959 .

[22]  Rutherford Aris,et al.  Some remarks on longitudinal mixing or diffusion in fixed beds , 1957 .

[23]  A. O. Converse The effect of velocity profile on axial dispersion in packed beds , 1960 .

[24]  I. Amdur,et al.  Transport Processes in Applied Chemistry , 1957 .

[25]  Sakae Yagi,et al.  Heat and mass transfer from wall to fluid in packed beds , 1959 .

[26]  J. M. Smith,et al.  Effective Thermal Conductivities in Gas-Solid Systems , 1949 .

[27]  M. W. Thring,et al.  Book Reviews: Pilot Plants, Models, and Scale-Up Methods in Chemical Engineering , 1957 .

[28]  C. Geankoplis,et al.  Longitudinal Diffusivity of Liquids in Packed Beds , 1958 .

[29]  J. M. Smith,et al.  Velocities and Effective Thermal Conductivities in Packed Beds , 1951 .