New developments of advanced high-strength steels for automotive applications

Abstract Automotive industry asks for higher resistant steels to lighten parts and improve crash resistance. Keeping a good ductility while increasing tensile strength requires the development of new grades in which hardening mechanisms counteract the drop in elongation when enhancing mechanical resistance. This is mainly achieved with multiphase steels and completing dislocation hardening by twinning and martensite transformation during straining. This has led to high-strength steel families, some of them being already used in body in white (Dual Phase (DP) and TRIP steels). Others, still in development, will soon emerge on the market (Quenched and Partitioned (Q&P), medium-Mn steels or TWIP).

[1]  D. Raabe,et al.  Influence of Al content and precipitation state on the mechanical behavior of austenitic high-Mn low , 2013 .

[2]  Bing Chen,et al.  The effect of morphology on the stability of retained austenite in a quenched and partitioned steel , 2013 .

[3]  S. Wolf,et al.  Microstructure Defects Contributing to the Energy Absorption in CrMnNi TRIP Steels , 2013 .

[4]  Gregory B Olson,et al.  Kinetics of strain-induced martensitic nucleation , 1975 .

[5]  R. Miller Ultrafine-grained microstructures and mechanical properties of alloy steels , 1972 .

[6]  L. Rémy The interaction between slip and twinning systems and the influence of twinning on the mechanical behavior of fcc metals and alloys , 1981 .

[7]  S. Allain,et al.  Microstructure – Properties Relationships in Carbide-free Bainitic Steels , 2011 .

[8]  Tae-Ho Lee,et al.  Correlation between stacking fault energy and deformation microstructure in high-interstitial-alloyed austenitic steels , 2010 .

[9]  T. Shun,et al.  A study of work hardening in austenitic FeMnC and FeMnAlC alloys , 1992 .

[10]  Georg Frommeyer,et al.  Microstructures and Mechanical Properties of High‐Strength Fe‐Mn‐Al‐C Light‐Weight TRIPLEX Steels , 2006 .

[11]  Mats Oldenburg,et al.  Testing and evaluation of material data for analysis of forming and hardening of boron steel components , 2002 .

[12]  E. W. Hart Theory of the tensile test , 1967 .

[13]  A. Reinhardt,et al.  Development of Pre-Coated Boron Steel for Applications on PSA Peugeot Citroën and RENAULT Bodies in White , 2002 .

[14]  G. Thewlis,et al.  Classification and quantification of microstructures in steels , 2004 .

[15]  Y. Bréchet,et al.  Architectured materials: Expanding materials space , 2013 .

[16]  D. Matlock,et al.  Partitioning of carbon from supersaturated plates of ferrite, with application to steel processing and fundamentals of the bainite transformation , 2004 .

[17]  A. Pineau,et al.  Twinning and strain-induced F.C.C. → H.C.P. transformation in the FeMnCrC system , 1977 .

[18]  Patricia Verleysen,et al.  Advanced high strength steels for automotive industry , 2012 .

[19]  S. Allain,et al.  The development of a new Fe-Mn-C austenitic steel for automotive applications , 2006 .

[20]  Sunghak Lee,et al.  Exceptional combination of ultra-high strength and excellent ductility by inevitably generated Mn-segregation in austenitic steel , 2018, Materials Science and Engineering: A.

[21]  O. Bouaziz,et al.  High manganese austenitic twinning induced plasticity steels: A review of the microstructure properties relationships , 2011 .

[22]  U. F. Kocks,et al.  Kinetics of flow and strain-hardening☆ , 1981 .

[23]  Seok-Jae Lee,et al.  On the origin of dynamic strain aging in twinning-induced plasticity steels , 2011 .

[24]  O. Bouaziz,et al.  Modelling of TWIP effect on work-hardening , 2001 .

[25]  N. C. Goel,et al.  A theoretical model for the flow behavior of commercial dual-phase steels containing metastable retained austenite: Part I. derivation of flow curve equations , 1985 .

[26]  H. Abreu,et al.  Deformation induced martensitic transformation in a 201 modified austenitic stainless steel , 2009 .

[27]  O. Bouaziz,et al.  Evolution of microstructure and mechanical properties of medium Mn steels during double annealing , 2012 .

[28]  O. Bouaziz,et al.  Driving Force and Logic of Development of Advanced High Strength Steels for Automotive Applications , 2013 .

[29]  D. Matlock,et al.  Intercritically annealed and isothermally transformed 0.15 Pct C steels containing 1.2 Pct Si-1.5 Pct Mn and 4 Pct Ni: Part I. transformation, microstructure, and room-temperature mechanical properties , 1992 .

[30]  Gareth Thomas,et al.  On the law of mixtures in dual-phase steels , 1980 .

[31]  A. Gourgues-Lorenzon,et al.  Microstructure, plastic flow and fracture behavior of ferrite-austenite duplex low density medium Mn steel , 2017 .

[32]  G. B. Olson,et al.  A MECHANISM FOR THE STRAIN-INDUCED NUCLEATION OF MARTENSITIC TRANSFORMATIONS* , 1972 .

[33]  D. Schryvers,et al.  On the relationship between the twin internal structure and the work-hardening rate of TWIP steels , 2010 .

[34]  B. Blanpain,et al.  Material Evaluation to Prevent Nozzle Clogging during Continuous Casting of Al Killed Steels , 2002 .

[35]  D. Suh,et al.  Influence of Al on the Microstructural Evolution and Mechanical Behavior of Low-Carbon, Manganese Transformation-Induced-Plasticity Steel , 2010 .

[36]  F. Delannay,et al.  Enhancement of the mechanical properties of a low-carbon, low-silicon steel by formation of a multiphased microstructure containing retained Austenite , 1998 .

[37]  P. Hein,et al.  A Global Approach of the Finite Element Simulation of Hot Stamping , 2005 .

[38]  D. Matlock,et al.  Carbon partitioning into austenite after martensite transformation , 2003 .

[39]  D. Schryvers,et al.  On the mechanism of twin formation in Fe–Mn–C TWIP steels , 2010 .

[40]  H. Bhadeshia,et al.  The bainite transformation in a silicon steel , 1979 .

[41]  L. Rémy Kinetics of f.c.c. deformation twinning and its relationship to stress-strain behaviour , 1978 .

[42]  Manfred Geiger,et al.  Characterisation of the Flow Properties of the Quenchenable Ultra High Strength Steel 22MnB5 , 2006 .

[43]  N. C. Goel,et al.  A theoretical model for the flow behavior of commercial dual-phase steels containing metastable retained austenite: Part II. calculation of flow curves , 1985 .

[44]  S. Vandeputte,et al.  Static strain aging phenomena in cold-rolled dual-phase steels , 2003 .

[45]  S. Allain,et al.  In-situ investigation of quenching and partitioning by High Energy X-Ray Diffraction experiments , 2017 .

[46]  A. Deschamps,et al.  Hydrogen trapping by VC precipitates and structural defects in a high strength Fe–Mn–C steel studied by small-angle neutron scattering , 2012 .

[47]  S. V. van Bohemen Bainite and martensite start temperature calculated with exponential carbon dependence , 2012 .

[48]  Morris Azrin,et al.  Transformation behavior of TRIP steels , 1978 .

[49]  A. Gourgues-Lorenzon,et al.  Fracture behaviour of a Fe–22Mn–0.6C–0.2V austenitic TWIP steel , 2015 .

[50]  Han. Dong,et al.  Experimental and numerical analysis on formation of stable austenite during the intercritical annealing of 5Mn steel , 2011 .

[51]  D. Caillard,et al.  Development of 3rd generation Medium Mn duplex steels for automotive applications , 2018, Materials Science and Technology.

[52]  Dong-Woo Suh,et al.  Fe–Al–Mn–C lightweight structural alloys: a review on the microstructures and mechanical properties , 2013, Science and technology of advanced materials.

[53]  F. Pickering,et al.  Structure–property relationships in dual-phase steels , 1982 .

[54]  O. Bouaziz,et al.  A physical model of the twinning-induced plasticity effect in a high manganese austenitic steel , 2004 .

[55]  G. Krauss Martensite in steel: strength and structure , 1999 .

[56]  C. Scott,et al.  Role of copper and aluminum additions on the hydrogen embrittlement susceptibility of austenitic Fe–Mn–C TWIP steels , 2014 .

[57]  J. Molina-Aldareguia,et al.  Microstructural design in quenched and partitioned (Q&P) steels to improve their fracture properties , 2016 .

[58]  F. Hu,et al.  Nanostructured high-carbon dual-phase steels , 2011 .

[59]  B C De Cooman,et al.  State-of-the-knowledge on TWIP steel , 2012 .

[60]  D. Raabe,et al.  Dislocation and twin substructure evolution during strain hardening of an Fe-22 wt.% Mn-0.6 wt.% C TWIP steel observed by electron channeling contrast imaging , 2011 .

[61]  O. Bouaziz,et al.  Toward a new interpretation of the mechanical behaviour of As-quenched low alloyed martensitic steels , 2012 .

[62]  F. Hild,et al.  Coincidence of strain-induced TRIP and propagative PLC bands in Medium Mn steels , 2017 .

[63]  B. C. De Cooman,et al.  Selective Oxidation and Sub‐Surface Phase Transformation of TWIP Steel during Continuous Annealing , 2011 .

[64]  D. Matlock,et al.  Carbon partitioning to austenite from martensite or bainite during the quench and partition (Q&P) process: A critical assessment , 2008 .

[65]  S. Ghosh,et al.  Deformation and annealing behaviour of dual phase TWIP steel from the perspective of residual stress, faults, microstructures and mechanical properties , 2018, Materials Science and Engineering: A.

[66]  Mats Oldenburg,et al.  Dimensional Changes and Microstructural Evolution in a B-bearing Steel in the Simulated Forming and Quenching Process , 2001 .

[67]  Dieter. Fahr,et al.  ENHANCEMENT OF DUCTILITY IN HIGH STRENGTH STEELS , 1969 .

[68]  Yisheng Zhang,et al.  Enhancing ductility of the Al-Si coating on hot stamping steel by controlling the Fe-Al phase transformation during austenitization , 2014 .

[69]  P. Maugis,et al.  Austenite growth and stability in medium Mn, medium Al Fe-C-Mn-Al steels , 2016 .

[70]  O. Bouaziz,et al.  Towards the microstructure design of DP steels: A generic size-sensitive mean-field mechanical model , 2015 .

[71]  A. Tekkaya,et al.  A review on hot stamping , 2010 .