2 – Sodium and Potassium

[1]  A. Degl'innocenti,et al.  Heteroatom-Assisted Isomerization of Oxiranes to Allylic Alcohols Promoted by Bases , 1994 .

[2]  M. Schlosser,et al.  Site selective hydrogen/metal exchange: Competition and cooperation between superbases and neighboring groups , 1994 .

[3]  S. Pecchi,et al.  The synthesis of 4′-thia-α-santalene and 4′-thia-α-santalol through an organometallic approach , 1994 .

[4]  C. Floris,et al.  Metallation reactions. XXI. Metallation of alkyl (alkylthio) benzenes by superbases versus organolithium compounds , 1994 .

[5]  M. Schlosser,et al.  Polar allyl type organometallics as key intermediates in regio- and stereocontrolled reactions: conformational mobilities and preferences , 1994 .

[6]  M. Schlosser,et al.  4′-Oxa-α-santalene and 4′-oxa-α-santalol : An olfactory comparison with the analogous natural sesquiterpenes , 1993 .

[7]  Yoshinori Yamamoto,et al.  SELECTIVE REACTIONS USING ALLYLIC METALS , 1993 .

[8]  P. Caubére Unimetal super bases , 1993 .

[9]  P. Beak,et al.  An α-metalloamine synthetic equivalent from N-Boc-allylamine , 1993 .

[10]  A. Mann,et al.  Allylsilanes derived from aminoacids in the synthesis of piperidine and pyrrolidins derivatives , 1993 .

[11]  M. Schlosser,et al.  N-phenylpyrrole: A kinetic, though not thermodynamic preference for dilithiation , 1993 .

[12]  M. Schlosser,et al.  A shortcut to α-Santalol , 1993 .

[13]  G. Gelli,et al.  Metallation reactions: XVIII. Regioselective metallation of (alkylthio)benzenes by superbases , 1992 .

[14]  W. Bauer,et al.  Structure of a super base in tetrahydrofuran solution studied by 6Li, 1H HOESY, 133Cs, 1H HOESY, and MNDO. Evidence for discrete species rather than a mixed aggregate , 1992 .

[15]  L. Brandsma,et al.  An Efficient Synthesis of Triphenylene , 1992 .

[16]  M. Taddei,et al.  Chiral Allylsilanes Derived from Naturally Occurring α-Amino Acids , 1992 .

[17]  M. Schlosser,et al.  Fluorine and trifluoromethyl substituted anilines: site selective metalation and electrophilic substitution , 1992 .

[18]  N. Mills,et al.  Delocalized Carbanions in Synthesis , 1992 .

[19]  M. Schlosser,et al.  A one-pot synthesis of coumaryl, coniferyl, and sinapyl alcohol , 1991 .

[20]  Y. Guggisberg,et al.  Optional ortho or alpha hydroxymethylation of alkylarenes , 1991 .

[21]  M. Schlosser,et al.  The “two-fold reaction” benchmark applied to the copper catalyzed assembling of 1ω-difunctional hydrocarbon chains , 1991 .

[22]  M. Schlosser,et al.  A one-pot synthesis of ibuprofene involving three consecutive steps of superbase metalation , 1991 .

[23]  R. K. Boeckman,et al.  The chemistry of cyclic vinyl ethers. 6. Total synthesis of polyether ionophore antibiotics of the calcimycin (A-23187) class , 1991 .

[24]  T. Chan,et al.  Regioselective alkylation of 1-silyl-2-methylallyl carbanions , 1991 .

[25]  M. Schlosser,et al.  1,(ω-1)-Dienes : solvent controlled unilateral or bilateral metalation , 1991 .

[26]  M. Zaidlewicz Synthesis with organoboranes. V, Hydroxymethylation and formylation of cycloalkenes via allylic organopotassium and organoboron compounds , 1991 .

[27]  G. Simig,et al.  8-Methoxyisoquinoline derivatives through ortho-selective metalation of 2-(3-methoxyphenyl)ethylamine , 1991 .

[28]  J. Petránek,et al.  More efficient metallation of alkylbenzenes by modified superbases from butyllithium and potassium alkoxides. Effect of alkoxide structure and concentration , 1991 .

[29]  L. Brandsma,et al.  On the direct metalation of isoprene , 1991 .

[30]  M. Taddei,et al.  Carbon-centered optically active organosilanes. A rational approach to an efficient silylated chiral auxiliary , 1991 .

[31]  R. Bates,et al.  Methoxymetacyclophanes from 2,6-dimethylanisole , 1991 .

[32]  A. Degl'innocenti,et al.  Allylsilanes by the Regio- and Stereocontrolled Substitution of Metalated Homoallylsilanes , 1991 .

[33]  A. Mordini,et al.  A New Approach to the Synthesis of 2-Aza-1,3-Dienes through a Novel 1,4-Rearrangement of a Trimethylsilyl Group from Nitrogen to Carbon , 1991 .

[34]  M. Schlosser,et al.  Fluorine- and Trifluoromethyl-Substituted Toluenes: Site Selective Metalation of Aromatic or Benzylic Positions , 1991 .

[35]  M. Schlosser,et al.  The metalation of fluoroanisoles: optional regioselectivity due to metal mediated control , 1991 .

[36]  L. Brandsma,et al.  Interaction of alkoxides XVIII. Utilitization of the complex base from alkyllithium and potassium alkoxides in the dimetallation of phenol, thiophenol, o-, m- and p-cresol , 1990 .

[37]  Victor Snieckus,et al.  Directed ortho metalation. Tertiary amide and O-carbamate directors in synthetic strategies for polysubstituted aromatics , 1990 .

[38]  M. Schlosser,et al.  The enigmatic 1J(CH) coupling constants of allyl-type organometallic compounds , 1990 .

[39]  L. Brandsma,et al.  Generation of Ortho-Potassiofluorobenzene and its Functionalization , 1990 .

[40]  P. Schleyer,et al.  Experimental and theoretical study of the dimetalation of phenylacetylene and (1-naphthyl)acetylene , 1990 .

[41]  T. Siahaan,et al.  A new rearrangement of alkoxybenzyl anions , 1990 .

[42]  T. Kramer,et al.  Metallated 2-alkenyl carbamates: chiral homoenolate reagents for asymmetric synthesis , 1990 .

[43]  M. Schlosser,et al.  Superbase Reactions: The Expedient and Selective Metalation of Fluorine- or Trifluoromethyl-Substituted Benzenes , 1990 .

[44]  H. Brown,et al.  Chiral synthesis VIA organoboranes. 26. An efficient synthesis of isoprenyl derivatives of borane - valuable reagents for the isoprenylboration of aldehydes. A convenient route to both enantiomers of ipsenol and ipsdienol in high optical purity , 1990 .

[45]  B. Lipshutz,et al.  Quantitative metalations of 2-substituted 1,3-dithianes at -78°C using n-BuLi/Na-O-t-Bu , 1990 .

[46]  C. Margot,et al.  1,2-elimination of alcohol from homoallyl ethers under the influence of mixed metal bases , 1990 .

[47]  A. Maercker,et al.  Versuche zur Umlagerung von Cyclobutyl‐ in 3‐Butenyl‐Anionen: Endocyclische Ringöffnung bei der Reaktion von (3,3‐Diphenyl‐1‐vinylcyclobutyl)methylether mit Alkalimetallen – anionisch oder radikalisch? , 1990 .

[48]  M. Schlosser,et al.  Selective mono- or dimetalation of arenes by means of superbasic reagents , 1990 .

[49]  M. Jarman,et al.  Metallation of N-(pivaloyl)- and N-(tert-butoxycarbonyl)difluoroanilines: regiocontrol by fluorine in the synthesis of 4-methoxycarbonyl derivatives , 1990 .

[50]  C. Margot,et al.  Facile isomerization of oxiranes to allyl alcohols by mixed metal bases , 1990 .

[51]  C. Djerassi,et al.  Scope and regiochemical control of the allylpotassium reaction in the synthesis of sterols with unsaturated side chains , 1989 .

[52]  H. Brown,et al.  Hydroboration of terpenes. 10. An improved procedure for the conversion of .alpha.-pinene into .beta.-pinene in high chemical and optical yield using a combination of the Schlosser allylic metalation of .alpha.-pinene and allylborane chemistry , 1989 .

[53]  C. M. Lindsay,et al.  Directed lithiation of arenethiols , 1989 .

[54]  J. C. Martin,et al.  Directed ortho-lithiation of lithium thiophenolate. New methodology for the preparation of ortho-substituted thiophenols and related compounds , 1989 .

[55]  J. Zubieta,et al.  o-lithiothiophenol equivalents: Generation, reactions, and applications in synthesis of hindered thiolate ligands , 1989 .

[56]  R. Bates,et al.  Preparations and reactions of symmetrical dimethylenebiphenyl dianions; conformations of [O.n]-o-cyclophanes. A simple NMR method for determining twist angles in biphenyls , 1989 .

[57]  D. Kempf Remote lithiation of N-methallyl amides , 1989 .

[58]  M. Schlosser,et al.  The wittig rearrangement as a practical method for aldehyde synthesis , 1989 .

[59]  N. Hertkorn,et al.  Selektive Metallierung von Bicyclo[3.2.1]octa-2,6-dien: I. Monostannylierte Derivate☆ , 1988 .

[60]  B. Feringa,et al.  Dimetalation of Furans and Thiophenes. One-Pot Procedures for Furan-2,5- and Thiophene-2,5-dicarboxaldehyde , 1988 .

[61]  M. Schlosser Superbases for organic synthesis , 1988 .

[62]  M. Taddei,et al.  A simple regio- and stereocontrolled synthesis of α-branched allylsilanes. , 1988 .

[63]  M. Zaidlewicz Synthesis with Organoboranes; 4.1 Transformation of Olefins into Homoallylic Alcohols, β,γ- and α,β-Unsaturated Ketones via Allylic Diethylboranes , 1988 .

[64]  M. Schlosser,et al.  1-(Triphenylmethyl)allyl potassium :conformational preference and [1,2]-rearrangement , 1988 .

[65]  L. Brandsma,et al.  Regiospecific functionalization of dimetalated isopropenylacetylene, a synthetic equivalent of the isoprene anion. An efficient synthesis of the bark beetle pheromones (±)-ipsenol and (±)-ipsdienol , 1987 .

[66]  K. Tamao,et al.  Silafunctional Compounds in Organic Synthesis. XXXVII. Metalated (Allyl) Aminosilanes: Regioselective Coupling with Alkyl Halides to (E)-1-Alkenylsilanes with a Functional Group on Silicon , 1987 .

[67]  S. Masamune,et al.  Asymmetric addition of (E)- and (Z)-crotyl-trans-2,5-dimethylborolanes to aldehydes , 1987 .

[68]  T. Siahaan,et al.  Preparation and Reactions of Trianions from the Dimethylphenols , 1987 .

[69]  P. Schleyer,et al.  Convenient procedures for the α-metallation of vinylic ethers and thioethers , 1987 .

[70]  K. Tamao,et al.  Silafunctional compounds in organic synthesis. 35. Silafunctional .alpha.,.beta.-epoxy silanes. Transformation into erythro- and threo-1,2-diol skeletons and its application to the synthesis of (.+-.)-exo-brevicomin , 1987 .

[71]  N. S. Narasimhan,et al.  Heteroatom directed aromatic lithiation reactions for the synthesis of condensed heterocyclic compounds , 1987 .

[72]  L. Lochmann,et al.  Lithium-potassium exchange in alkyllithium/potassium t-pentoxide systems: XIV. Interactions of alkoxides , 1987 .

[73]  E. Weiss,et al.  Über metallalkyl- und aryl-verbindungen ☆: XXXV. Zur struktur von allyllithium. Darstellung und kristallstruktur einer monomeren allyllithium-verbindung, allyl(pentamethyldiethylentriamin)lithium, LiC3H5(Me2NC2H4N(Me)C2H4NMe2) , 1987 .

[74]  C. S. Panda,et al.  Synthesis with Organoboranes;3.1 Allylic Monodeuteration of Olefins , 1987 .

[75]  R. Schmidt,et al.  C-1 lithiation of c-2 activated glucals☆ , 1987 .

[76]  L. Lochmann Metallation of benzene with the system organolithium compound-potassium tert-pentoxide , 1987 .

[77]  W. Roush,et al.  Diisopropyl tartrate modified (E)-crotylboronates: highly enantioselective propionate (E)-enolate equivalents , 2002 .

[78]  A. Meyers,et al.  Stereo- and regiocontrol by complex induced proximity effects: reactions of organolithium compounds , 1986 .

[79]  S. Higuchi,et al.  Synthesis and antiinflammatory activity of alkenylphenylpropionic acids. , 1986, Chemical & pharmaceutical bulletin.

[80]  W. Bauer,et al.  n-Butylpotassium: preparation, synthetic use and NMR properties in hexane and tetrahydrofuran solution , 1986 .

[81]  T. Siahaan,et al.  Preparation and reactions of dianions from cresols , 1986 .

[82]  B. Gordon,et al.  Delocalized carbanions: 3,3',5,5'-tetramethylenebiphenyl tetraanion, a new tetraanion , 1986 .

[83]  H. Brown,et al.  Enantiomeric Z- and E-crotyldiisopinocampheylboranes. Synthesis in high optical purity of all four possible stereoisomers of .beta.-methylhomoallyl alcohols , 1986 .

[84]  S. Hanessian,et al.  Formation of C-glycosides by polarity inversion at the anomeric centre , 1986 .

[85]  P. Schleyer,et al.  The first successful direct metallation of ethene , 1986 .

[86]  M. Zaidlewicz Synthesis with organoboranes. 21. Synthesis of α- and gd-bamascone , 1986 .

[87]  R. D. Bach,et al.  Model studies aimed at the synthesis of Fredericamycin A. A simple o-quinodimethane route to the spiro naphthalene portion , 1986 .

[88]  L. Brandsma,et al.  Preparative metallation of norbornene and norbornadiene , 1986 .

[89]  P. Schleyer,et al.  n-Butylsodium: The preparation, properties and NMR spectra of a hydrocarbon- and tetrahydrofuran-soluble reagent , 1985 .

[90]  M. Zaidlewicz Synthesis with organoboranes , 1985 .

[91]  C. Margot,et al.  A new stereoselective synthesis of (Z)-9-tricosene, the sex attractant of the common housefly , 1985 .

[92]  Ann E. Mera,et al.  Delocalized carbanions: the facile-synthesis of disubstituted butadienes and diols , 1985 .

[93]  C. Ogle,et al.  High-field proton NMR study of the aggregation and complexation of n-butyllithium in tetrahydrofuran , 1985 .

[94]  H. Loosli,et al.  A rapid-injection (RI) NMR study of the reactivity of butyllithium aggregates in tetrahydrofuran , 1985 .

[95]  G. Posner,et al.  Phenoxide-directed ortho lithiation , 1985 .

[96]  C. Margot,et al.  A regio- and stereocontrolled access to 2,4-dienols by amide/alcoholate-promoted ring-opening of dihydro-pyrans , 1985 .

[97]  L. Brandsma,et al.  Direct metallation of isoprene , 1985 .

[98]  L. Brandsma,et al.  Dimetallation of phenylacetylene. Synthesis of ortho‐substituted derivatives of phenylacetylene, benzo[b]selenophene and benzo[b]tellurophene , 1985 .

[99]  M. Schlosser,et al.  A diastereoselective synthesis of both quercus lactone isomers employing allyl-type organometallics as key intermediates , 1985 .

[100]  D. Hoppe Die Homoaldol-Reaktion oder wie man Probleme der Regio- und Stereoselektivität in den Griff bekommt†‡ , 1984 .

[101]  D. Hoppe The Homoaldol Reaction, or How to Overcome Problems of Regio‐ and Stereo‐selectivity , 1984 .

[102]  L. Brandsma,et al.  Kinetic and thermodynamic control in the metalation of pyridine. A direct synthesis of 2-and 4-substituted pyridines , 1984 .

[103]  M. Schlosser,et al.  Facile hydrogen/metal exchange between butylpotassium and saturated ethers , 1984 .

[104]  M. Schlosser,et al.  The Halide-promoted fragmentation of 1-chloro-1-fluoro-2-(a-silylakyl))cyclopropanes: A new entry to fluorodienes† , 1984 .

[105]  L. Brandsma,et al.  Functionalization of pyridine via direct metallation , 1984 .

[106]  M. Schlosser,et al.  Facile and selective metalation of 7-dehydro-cholesterol (pro-vitamin D3) , 1984 .

[107]  M. Schlosser,et al.  The “super-basic” butyllithium/potassium tert-butoxide mixture and other lickor-reagents , 1984 .

[108]  K. Koumaglo,et al.  Regioselection in the alkylation of trimethylsilylallyl anion-stereoselective synthesis of disubstituted alkenes , 1984 .

[109]  H. Ahlbrecht,et al.  α-Metallierte amine durch deprotonierung aliphatischer N-methylamine , 1984 .

[110]  L. Brandsma,et al.  Synthesis of condensed bicyclic thiophene derivatives from diyne systems , 1983 .

[111]  J. Fehrentz,et al.  An Efficient Synthesis of Optically Active α-(t-Butoxycarbonylamino)-aldehydes from α-Amino Acids , 1983 .

[112]  N. S. Narasimhan,et al.  Syntheses of Heterocyclic Compounds Involving Aromatic Lithiation Reactions in the Key Step , 1983 .

[113]  H. Simon,et al.  3-Metallierte Enamine; VIII1. Alkylierung von deprotoniertem 2-(N-Methylanilino)-2-butensäure-methylester; eine einfache Methode zur Homologisierung von 2-Oxobutansäure-estern , 1983 .

[114]  L. Brandsma,et al.  Dimetalation of isopropenylacetylene. Application in the synthesis of 3-methylselenophen, 3-methylene-2,3-dihydroselenophen and the tellurium analogues , 1983 .

[115]  G. Boche,et al.  The reaction of n-butyllithium/sodium(potassium) tert.-butoxide (Lochmann-Schlosser base) with a ch-acid leads to organo-sodium(potassium) compounds. An NMR spectroscopical study of several organo-lithium, -sodium and -potassium compounds in tetrahydrofuran-D8 , 1983 .

[116]  H. Simon,et al.  3-Metallierte Enamine; IX1. 4-(1-Hydroxyalkylierung) von deprotoniertem 2-(N-Methylanilino)-2-butensäure-methylester, eine einfache Methode zur Herstellung von Derivaten der 5-Hydroxy-2-oxoalkansäure-ester , 1983 .

[117]  N. Mills,et al.  Dianions of 2,5-dimethyl-2,4-hexadiene. Evidence for the stability of an 8-.pi.-electron cross-conjugated system , 1982 .

[118]  L. Brandsma,et al.  Synthesis of 2,3-disubstituted thiophens via metalated acetylenes and allenes , 1982 .

[119]  C. Ogle,et al.  Arenes disubstituted with primary alkyl groups from xylylene dianions , 1982 .

[120]  Katsuramaru Fujitta,et al.  A convenient and diastereoselective route to homoallyl alcohols: Addition of (z)‐ or (e)‐alkenyl‐dimethoxyboranes to aldehydes , 1982 .

[121]  M. Schlosser,et al.  Eine stereokontrollierte Synthese des Pheromons 4‐Methyl‐3‐heptanol: neue und selektive CC‐verknüpfende Aufbaureaktionen , 1982 .

[122]  M. Schlosser,et al.  A Stereocontrolled Synthesis of the Pheromone 4-Methyl-3-heptanol : Novel and Selective CC-Linking Reactions , 1982 .

[123]  H. Ahlbrecht,et al.  3-Metallated Enamines; VII1. 3-Oxosilanes via Silylation of 3-Metallated Enamines , 1982 .

[124]  M. Schlosser,et al.  Neue 13C-spektroskopische Untersuchungen zur Struktur von Allylmetall-Verbindungen , 1981 .

[125]  L. Brandsma,et al.  Dimetallation of phenylacetylene. Selective ortho-substitution , 1981 .

[126]  L. J. Schaad,et al.  Delocalized dicarbanions and higher delocalized carbanions , 1981 .

[127]  A. Nakamura,et al.  Chemistry of Dienyl Anions. IV. Geometry of Pentadienyl Anions in Solution and in the Solid State Determined by Regioselective Trimethylsilylation and NMR , 1981 .

[128]  L. Brandsma,et al.  Synthesis of o-halogenophenylacetylenes via the dianion of phenylacetylene (1) , 1981 .

[129]  H. Bosshardt,et al.  Die Strukturdynamik von Pentadienylmetall-Verbindungen mit endständiger Alkyl-Gruppe : zugleich "stereoselektive" und "stereodefensive" Synthese eines natürlichen Riechstoffes , 1980 .

[130]  M. Schlosser,et al.  Regioselektive Metallierung des Phenylcyclopropans sowie leichte Anlagerung des 1‐Phenylcyclopropyl‐kaliums an Äthylen , 1980 .

[131]  D. Worsfold,et al.  Allyl alkali metal compounds , 1980 .

[132]  M. Schlosser,et al.  Allylic Compounds of Magnesium, Lithium, and Potassium: σ- or π-Structures?†‡ , 1980 .

[133]  M. Schlosser,et al.  Magnesium‐, Lithium‐ und Kalium‐Verbindungen vom Allyl‐Typ: σ‐ oder π‐Strukturen? , 1980 .

[134]  H. Bosshardt,et al.  Einfacher Weg zu einem empfindlichen Terpenalkohol‐regio‐unselektive (!) Metallierung des α‐Terpinens als Schlüsselschritt , 1980 .

[135]  A. Nakamura,et al.  Chemistry of dienyl anions. I. Crystalline dienyl anions by direct reaction of conjugated and non-conjugated dienes with alkali metals in the presence of Et3N. , 1979 .

[136]  R. Bates,et al.  2,3-Dimethylenebutadiene dianion; convenient procedure for allylic metalation of conjugated dienes , 1979 .

[137]  M. Schlosser,et al.  Metalation of Pyrans and Dihydropyridines: When is an 8 π-System Cost Effective?† , 1979 .

[138]  M. Schlosser,et al.  Metallierung von Pyranen und Dihydropyridinen: Wann ist ein 8π-System erschwinglich?† , 1979 .

[139]  T. Crimmins,et al.  Metalation of ethylbenzene with n-pentylsodium in the presence of N,N,N',N'-tetramethylethylenediamine , 1978 .

[140]  M. Schlosser,et al.  2-Methylpentadienyl- and 2,4-dimethylpentadienylpotassium: first examples of U-shaped, though open-chain, organometallics , 1978 .

[141]  M. Schlosser,et al.  Capricious Stereoselectivities of Alkenylpotassium Formation under Kinetic and Thermodynamic Control Oxygen-Triggered Configurational Equilibration of an Allyl Type Organometallic Compound† , 1977 .

[142]  D. Chadwick,et al.  High-yield syntheses of dilithio-derivatives of furan, thiophen, N-methylpyrrole, 3-methylfuran, and 3-methylthiophen. Application of the method to 2-methylfuran, 2-methylthiophen, 2,5-dimethylfuran, 2,5-dimethylthiophen, benzo[b]furan, benzo[b]thiophen, pyrrole, and indole , 1977 .

[143]  K. Mori Absolute configuration of (−)-4-methylheptan-3-ol, a pheromone of the smaller european elm bark beetle, as determined by the synthesis of its (3R,4R)-(+)- and (3S,4R)-(+)-isomers , 1977 .

[144]  M. Schlosser,et al.  2-Alkenyl anions and their surprising endo preference. Facile and extreme stereocontrol over carbon-carbon linking reactions with organometallics of the allyl type , 1976 .

[145]  T. Crimmins,et al.  Metalation of cumene with n-pentylsodium in the presence of N,N,N',N'-tetramethylethylenediamine. Preparation of .alpha.-cumylsodium , 1976 .

[146]  E. Demole,et al.  A Chemical Investigation of the Volatile Constituents of East Indian Sandalwood Oil (SantalumalbumL.) , 1976 .

[147]  M. Schlosser,et al.  Ene-sulfides as Reaction Partners of Organometallic Compounds , 1976 .

[148]  M. Schlosser,et al.  Selektive Synthesen mit Organometallen V: Trimethylsilylmethyl‐kalium und andere Spitzenkönner unter den Metallierungsmitteln , 1976 .

[149]  C. Eaborn Cleavages of aryl-silicon and related bonds by electrophiles , 1975 .

[150]  M. Schlosser,et al.  Metallierung allylständiger Methylen- und Methin-Gruppen , 1975 .

[151]  R. Corriu,et al.  Syntheses a partir de carbanions allyliques silicies , 1975 .

[152]  M. Schlosser,et al.  Selektive Synthesen mit Organometallen IV: Gezielte Hydroxylierung von Allylstellungen† , 1975 .

[153]  W. S. Matthews,et al.  Acidities of carbon acids. IV. Kinetic vs. equilibrium acidities as measures of carbanion stabilities. Relative effects of phenylthio, diphenylphosphino, and phenyl groups , 1975 .

[154]  F. Matsumura,et al.  Identification of the sex pheromone of the furniture carpet beetle, anthrenus flavipes leconte , 1975 .

[155]  M. Schlosser,et al.  Selektive Synthesen mit Organometallen II: Metallierung und Abwandlung funktionell substituierter Alkene , 1974 .

[156]  P. Caubére Applications of sodamide-containing complex bases in organic synthesis , 1974 .

[157]  C. R. Gentry,et al.  Sex Pheromones and Reproductive Isolation of the Lesser Peachtree Borer and the Peachtree Borer , 1974, Science.

[158]  W. Ford,et al.  Direct observation of acyclic pentadienyllithium conformational isomers by carbon-13 magnetic resonance spectroscopy , 1974 .

[159]  W. Houlihan,et al.  The Metalation of 1,3-Bis(trifluoromethyl)benzene by nbutyllithium , 1974 .

[160]  M. Schlosser,et al.  Bessere CC‐Verknüpfungen durch kontrollierte Kupfer‐Katalyse , 1974 .

[161]  H. Ahlbrecht,et al.  3-Metallierte Enamine, III1. Metallierung von 3- und 1-(N-Methylanilino)-propen , 1974 .

[162]  M. Schlosser,et al.  Improved Carbon‐Carbon Linking by Controlled Copper Catalysis , 1974 .

[163]  M. Schlosser,et al.  alpha-Metallierte Enäther als "Masken" für Acyl-Anionen , 1974 .

[164]  O. Meth–Cohn,et al.  Novel aspects of the metalation of heterocycles. Side-chain metalation of thiophen and ring metalation of six-membered nitrogen heterocycles , 1974 .

[165]  M. Schlosser,et al.  Selektive Synthesen mit Organometallen I. Konfigurativ einheitliche Folgeprodukte aus Alkenylkalium‐Zwischenstufen , 1974 .

[166]  K. Bartle,et al.  An NMR study of some substituted 1,3‐ and 1,4‐bistrifluoromethylbenzenes , 1973 .

[167]  R. Corriu,et al.  Organométalliques allyliques siliciés: obtention et comportement , 1973 .

[168]  M. Schlosser,et al.  Ummetallierung und doppelter Metall-Austausch: ein bequemer Zugang zu Organolithium-Verbindungen vom Benzyl- und Allyl-Typ , 1973 .

[169]  K. Oshima,et al.  New synthesis of ketones using 1-(alkylthio)vinyllithium , 1973 .

[170]  U. Schöllkopf,et al.  1‐Äthoxyvinyllithium als Reagens zur nucleophilen Acetylierung , 1972 .

[171]  B. Burger,et al.  Sex-pheromones. cis-Dec-5-en-1-yl 3-methylbutanoate as the pheromone from the pine emperor moth (Nudaurelia cytherea cytherea Fabr.) , 1972 .

[172]  E. F. Taschenberg,et al.  Sex pheromone of the grape berry moth: identification by classical and electroantennogram methods, and field tests. , 1971, Journal of insect physiology.

[173]  J. Hepworth,et al.  Metallation of 1,3-bistrifluoromethylbenzene and NN-dimethyl-3,5-bistrifluoromethylaniline , 1971 .

[174]  U. Schöllkopf Recent Results in Carbanion Chemistry , 1970 .

[175]  U. Schöllkopf Neuere Ergebnisse der Carbanionchemie , 1970 .

[176]  C. D. Broaddus Homogeneous metalation of alkylbenzenes , 1970 .

[177]  John D. Roberts,et al.  Nuclear magnetic resonance spectroscopy. Low temperature studies of diallylmagnesium , 1969 .

[178]  T. Crimmins,et al.  Factors governing orientation in metalation reactions. IV. The role of alkoxide in metalation reactions involving organosodium compounds , 1968 .

[179]  S. Mckinley,et al.  Ionic character of allyllithium , 1968 .

[180]  D. A. Shirley,et al.  Product distribution in the metalation of some aromatic substrates with n-butyllithium , 1968 .

[181]  A. J. Chalk,et al.  Ring metalation of toluene by butyllithium in the presence of N,N,N′,N′-tetramethylethylenediamine☆ , 1968 .

[182]  M. Schlosser Zur aktivierung lithiumorganischer reagenzien , 1967 .

[183]  R. Bates,et al.  Diene studies. V. Structures of and rotation barriers in pentadienyllithiums , 1967 .

[184]  J. Uhr,et al.  Immunologic Maturation in utero: Kinetics of the Primary Antibody Response in the Fetal Lamb , 1966, Science.

[185]  C. D. Broaddus Metalation of Toluene. The Question of Kinetic vs. Thermodynamic Control , 1966 .

[186]  Manfred Schlosser,et al.  Cis-selektive Olefinsynthesen , 1966 .

[187]  J. Pospíšil,et al.  On the interaction of organolithium compounds with sodium and potassium alkoxides. A new method for the synthesis of organosodium and organopotassium compounds , 1966 .

[188]  R. A. Finnegan,et al.  Organometallic Chemistry. VII. The Reactions of Amylsodium with Norbornene, endo-5-Hydroxymethylnorbornene, Nortricyclene, and Norbornadiene1,2 , 1964 .

[189]  C. D. Broaddus A Comparison of Alkylpotassium and Alkylsodium Reagents in Metalation of α-Olefins , 1964 .

[190]  M. Schlosser Organosodium and Organopotassium Compounds Part I: Properties and Reactions , 1964 .

[191]  M. Schlosser Natrium- und kalium-organische Verbindungen. Teil I: Eigenschaften und Reaktionsweisen [1] , 1964 .

[192]  R. A. Benkeser,et al.  Factors Governing Orientation in Metalation Reactions. II. The Metalation of Isopropylbenzene withn-Amylsodium andn-Amylpotassium , 1963 .

[193]  T. J. Logan,et al.  Vinyl Proton Abstraction during Metalation of α-Olefins , 1963 .

[194]  D. Bryce-smith 1136. Organometallic compounds of the alkali metals. Part VII. Orientation in protophilic aromatic metallation by ethylsodium and ethyl-lithium–potassium reagents: factors influencing the reactivity of metallating reagents , 1963 .

[195]  R. A. Benkeser,et al.  Factors Governing Orientation in Metalation Reactions. I. The Metalation of Ethylbenzene with Organosodium and Organopotassium Compounds , 1962 .

[196]  John D. Roberts,et al.  Nuclear Magnetic Resonance Spectroscopy. γ,γ-Dimethylallylmagnesium Bromide , 1962 .

[197]  V. Ramanathan,et al.  Some Reactions of 2-Furyllithium1 , 1962 .

[198]  R. A. Finnegan,et al.  The reaction of bicyclo[2.2.1]Heptadiene with amylsodium a novel cleavage reaction , 1962 .

[199]  R. A. Benkeser,et al.  FACTORS GOVERNING ORIENTATION IN HETEROGENEOUS METALATION REACTIONS , 1960 .

[200]  John D. Roberts,et al.  Nuclear Magnetic Resonance Spectra. Allylmagnesium Bromide , 1959 .

[201]  A. Morton,et al.  Metalation of Cumene1 , 1958 .

[202]  A. Morton,et al.  Influence of Alkoxides and the Dimetalation of Some Alkylaryl Hydrocarbons1 , 1958 .

[203]  A. Morton,et al.  Notes. Metalation of Cyclopropane by Amylsodium , 1958 .

[204]  H. Gilman,et al.  Notes - Metalation of Aryl Fluorides in Tetrahydrofuran , 1957 .

[205]  R. A. Benkeser,et al.  Metalations With Organosodium Compounds , 1957 .

[206]  F. Collins,et al.  CONDENSATIONS BY SODIUM. XXXVIII. THE METALATION OF tert-BUTYLBENZENE BY AMYLSODIUM AND THE EFFECTS OF ASSOCIATED SALTS1, 2 , 1955 .

[207]  A. Morton,et al.  Condensations by Sodium. XXXVII. The Dimetalation of Benzene, Thiophene, p-t-Butylphenol, Isopropylbenzene and sec-Butylbenzene and the Effect of Alkoxides on the meta:para Ratio for Benzene1,2 , 1954 .

[208]  G. Wittig Fortschritte auf dem Gebiet der organischen Aniono‐Chemie , 1954 .

[209]  D. Bryce-smith Organometallic compounds of the alkali metals. Part III. Metallation of alkylbenzenes by alkyl-sodium and -potassium compounds. The character of aromatic metallation reactions , 1954 .

[210]  D. Bryce-smith,et al.  177. Organometallic compounds of the alkali metals. Part II. The metallation and dimetallation of benzene , 1953 .

[211]  A. Brachman,et al.  Condensations by Sodium. XXXI. The Effect of Salts and Other Substances on the Alkylation of Toluene, a Modified Wurtz Reaction1 , 1951 .

[212]  V. B. Baker,et al.  Polymerization. XII. The Metalation of Olefins and Dienes and their Use in Alfin Polymerization of Butadiene1 , 1950 .

[213]  A. Morton,et al.  Polymerization; the structure of the alfin catalyst. , 1947, Journal of the American Chemical Society.

[214]  R. Letsinger,et al.  Polymerization. VI. The Alfin Catalysts1a , 1947 .

[215]  John D. Roberts,et al.  Metalation of Benzotrifluoride , 1946 .

[216]  R. Letsinger,et al.  Condensations by Sodium. XXX. The Metalation of Olefins and the Preparation of β,γ-Unsaturated Acids , 1945 .

[217]  A. Morton,et al.  The Metalation of Isopropylbenzene, Condensations by Sodium. XXIX , 1945 .

[218]  A. Morton The Chemical Behavior of the Organoalkali Compounds. , 1944 .

[219]  E. L. Little,et al.  Condensations by Sodium. XXVI. Metalation of Benzene, Toluene and Xylene. The Orienting Influence of Sodium and the Influence of Alkyl Groups on Metalation , 1943 .

[220]  G. M. Richardson,et al.  Condensations by Sodium. XX. Preparation and Properties of Organosodium Compounds Derived from Butyl and Propyl Chlorides1 , 1941 .

[221]  G. Wittig,et al.  Über das Verhalten der halogenierten Anisole gegen Phenyl‐lithium (V. Mitteil. über die Reaktionsweise des Phenyl‐lithiums) , 1940 .

[222]  H. Gilman,et al.  Relative Reactivities of Organometallic Compounds. XX.* Metalation , 1939 .

[223]  A. Morton,et al.  Condensations by Sodium. XIII. The Wurtz-Fittig Synthesis of Amylbenzene and Some Reactions of Benzylsodium , 1938 .

[224]  Leoni I Palmer,et al.  Condensations by Sodium. XII. Mechanism of Formation of Phenylmalonic Acid and the Syntheses of Butyl- and Phenylmalonic Acids from Monocarboxylic Acids , 1938 .

[225]  H. Gilman,et al.  RELATIVE REACTIVITIES OF ORGANOMETALLIC COMPOUNDS. XVII. THE AZO LINKAGE , 1937 .

[226]  A. Morton,et al.  Condensations by Sodium. VIII. Solvent Exchange Reactions, Preparation of Phenylmalonic Acid, and Comments on Some Mechanisms of Reactions which Employ Sodium , 1936 .

[227]  I. Hechenbleikner,et al.  Condensations by Sodium. VI. Malonic Acids from Mercury Dialkyls , 1936 .

[228]  P. Schorigin Synthesen mittels Natrium und Halogenalkylen , 1908 .