Recent developments in polymer synthesis

Recent developments in polymer synthesis are reviewed, especially those methods that lead to well defined structures: group-transfer polymerization, living cationic and anionic polymerization from cyclic and acyclic monomers using new initiating systems, metathesis polymerizations with new catalysts. Pseudo-living radical polymerizations, leading to new block copolymers and new mechanisms of radical ring opening, leading to new polymers and copolymers are included. From the field of stepwise polymerization, new developments in phase-transfer catalysis and activated polycondensation mechanisms are described. New polymer architecture, important for modern applications in new materials is represented by the section on liquid-crystalline polymers.

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