Palladium-catalyzed annulation

Abstract The palladium-catalyzed annulation of cyclic and bicyclic alkenes, unsaturated cyclopropanes and cyclobutanes, allenes, 1,3- and 1,4-dienes, as well as internal alkynes, by appropriately-substituted aryl or vinylic halides and triflates provides a very efficient, yet versatile route to a wide variety of heterocycles and carbocycles.

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