论文信息 - CO2 hydrogenation over carbide catalysts

CO2 hydrogenation over carbide catalysts

Carbides such as Mo 2 C, Fe 3 C, and WC have proved to be effective catalysts for hydrogenation of CO 2 . Mo 2 C and Fe 3 C showed high CO 2 conversion and good methanol selectivity at 220°C. A considerable amount of dimethylether was produced over WC. TaC and SiC were almost inactive. Copper promoted carbide catalysts were also tested for CO 2 hydrogenation

[1] A. Guerrero-Ruíz,et al. Hydrogenation of CO2 on carbon-supported nickel and cobalt , 1985 .

[2] A. Kiennemann,et al. Reaction of carbon dioxide and hydrogen on supported palladium catalysts , 1982 .

[3] F. Solymosi,et al. Hydrogenation of CO2 to CH4 over alumina-supported noble metals , 1980 .

[4] M. Boudart,et al. Platinum-Like Behavior of Tungsten Carbide in Surface Catalysis , 1973, Science.

[5] C. H. Bartholomew,et al. Hydrogenation of CO2 on group VIII metals: I. Specific activity of NiSiO2 , 1981 .

[6] E. Miyazaki,et al. Catalysis by transition metal carbides: V. Kinetic measurements of hydrogenation of CO over TaC, TiC, and Mo2C catalysts , 1984 .

[7] R. E. Watson,et al. Electronic Structure and Catalytic Behavior of Tungsten Carbide , 1974, Science.

[8] R. Kieffer,et al. Reaction of CO-H2 and CO2-H2 on copper-zinc catalysts promoted by metal oxides of groups III and IV , 1982 .

[9] R. Sneeden,et al. Oxide-supported copper catalysts prepared from copper formate: Differences in behavior in methanol synthesis from CO/H2 and CO2/H2 mixtures , 1986 .

[10] Y. Inoue,et al. Catalysis by Transition Metal Carbides. VI. Hydrogenation of Carbon Monoxide over WC, W2C, and W Powder Catalysts , 1985 .