Low-temperature fabrication of L10 ordered FePt alloy by alternate monatomic layer deposition

L10 ordered FePt alloy films with large magnetic anisotropy have been successfully prepared by alternating Fe(001) and Pt(001) monatomic layers on MgO (001) substrates at low temperatures below 230 °C. In addition to the fundamental (002) peak, (001) and (003) superlattice peaks have clearly been observed in the x-ray diffraction patterns for all the samples, indicating the formation of L10 ordered structure. The magnetization measurements show that all the samples are perpendicularly magnetized. Large uniaxial magnetic anisotropy (Ku=3.0×107 erg/cc) and high chemical ordering (long-range order parameter S=0.7±0.1) have been obtained even at the substrate temperature Ts=200 °C. The magnetization curves show good magnetic squareness (Mr/Ms∼0.9) for the samples grown at Ts⩾160 °C.

[1]  Robert Sinclair,et al.  Epitaxial PtFe(001) thin films on MgO(001) with perpendicular magnetic anisotropy , 1993 .

[2]  N. Kikuchi,et al.  Lowering of ordering temperature for fct Fe–Pt in Fe/Pt multilayers , 2001 .

[3]  B. Clemens,et al.  Enhanced magneto‐optic Kerr rotation in epitaxial PtFe(001) and PtCo(001) thin films , 1993 .

[4]  K. Hono,et al.  Artificial modulation of magnetic structures on a monatomic layer scale in Co/Ru superlattices , 2001 .

[5]  C. Chappert,et al.  Chemical order induced by He+ ion irradiation in FePt (001) films , 2000 .

[6]  Robert Sinclair,et al.  DIRECT FORMATION OF ORDERED COPT AND FEPT COMPOUND THIN FILMS BY SPUTTERING , 1995 .

[7]  Y. H. Chang,et al.  Magnetic properties and microstructure of iron-platinum thin films , 1992 .

[8]  Scott,et al.  Enhanced magneto-optical Kerr effect in spontaneously ordered FePt alloys: Quantitative agreement between theory and experiment. , 1994, Physical review. B, Condensed matter.

[9]  Masato Watanabe,et al.  Perpendicular Magnetization of Epitaxial FePt(001) Thin Films with High Squareness and High Coercive Force , 1996 .

[10]  David J. Sellmyer,et al.  Magnetic properties and structure of Fe/Pt thin films , 1995 .

[11]  H. Nakajima,et al.  Artificial fabrication of an L10‐type ordered FeAu alloy by alternate monatomic deposition , 1995 .

[12]  H. Nakajima,et al.  Perpendicular magnetic anisotropy and magneto-optical Kerr rotation in FePt(001) monoatomic multilayers , 1995 .