Fast charge implications: Pack and cell analysis and comparison

Abstract This study investigates the effect of 50-kW (about 2C) direct current fast charging on a full-size battery electric vehicle's battery pack in comparison to a pack exclusively charged at 3.3 kW, which is the common alternating current Level 2 charging power level. Comparable scaled charging protocols are also independently applied to individual cells at three different temperatures, 20 °C, 30 °C, and 40 °C, to perform a comparative analysis with the packs. Dominant cell-level aging modes were identified through incremental capacity analysis and compared with full packs to gain a clear understanding of additional key factors that affect pack aging. While the cell-level study showed a minor impact on performance due to direct current fast charging, the packs showed a significantly higher rate of capacity fade under similar charging protocols. This indicates that pack-level aging cannot be directly extrapolated from cell evaluation. Delayed fast charging, completing shortly before discharge, was found to have less of an impact on battery degradation than conventional alternating current Level 2 charging.

[1]  Shengbo Zhang The effect of the charging protocol on the cycle life of a Li-ion battery , 2006 .

[2]  James Marcicki,et al.  Modeling, Parametrization, and Diagnostics for Lithium-Ion Batteries with Automotive Applications , 2012 .

[3]  Tsutomu Ohzuku,et al.  Formation of Lithium‐Graphite Intercalation Compounds in Nonaqueous Electrolytes and Their Application as a Negative Electrode for a Lithium Ion (Shuttlecock) Cell , 1993 .

[4]  Venkat R. Subramanian,et al.  Effect of Porosity, Thickness and Tortuosity on Capacity Fade of Anode , 2015 .

[5]  Doron Aurbach,et al.  On the correlation between surface chemistry and performance of graphite negative electrodes for Li ion batteries , 1999 .

[6]  Marshall C. Smart,et al.  Lithium Plating Behavior in Lithium-Ion Cells , 2010 .

[7]  Marc Doyle,et al.  Mathematical Modeling of the Lithium Deposition Overcharge Reaction in Lithium‐Ion Batteries Using Carbon‐Based Negative Electrodes , 1999 .

[8]  Thanh Tu Vo,et al.  New charging strategy for lithium-ion batteries based on the integration of Taguchi method and state of charge estimation , 2015 .

[9]  J. Schmidt,et al.  Analysis and prediction of the open circuit potential of lithium-ion cells , 2013 .

[10]  Kang Xu,et al.  Study of the charging process of a LiCoO2-based Li-ion battery , 2006 .

[11]  Tanvir R. Tanim,et al.  Aging formula for lithium ion batteries with solid electrolyte interphase layer growth , 2015 .

[12]  J. C. Burns,et al.  In-Situ Detection of Lithium Plating Using High Precision Coulometry , 2015 .

[13]  James Francfort,et al.  Enabling fast charging – Battery thermal considerations , 2017 .

[14]  B. Nykvist,et al.  Rapidly falling costs of battery packs for electric vehicles , 2015 .

[15]  Simon F. Schuster,et al.  Lithium-ion cell-to-cell variation during battery electric vehicle operation , 2015 .

[16]  A. Savitzky,et al.  Smoothing and Differentiation of Data by Simplified Least Squares Procedures. , 1964 .

[17]  Richard Barney Carlson,et al.  Enabling fast charging - Infrastructure and economic considerations , 2017 .

[18]  T. Baumhöfer,et al.  Production caused variation in capacity aging trend and correlation to initial cell performance , 2014 .

[19]  Kevin G. Gallagher,et al.  Optimizing areal capacities through understanding the limitations of lithium-ion electrodes , 2016 .

[20]  David Anseán,et al.  Fast charging technique for high power lithium iron phosphate batteries: A cycle life analysis , 2013 .

[21]  C. Delacourt,et al.  Postmortem analysis of calendar-aged graphite/LiFePO4 cells , 2013 .

[22]  Sebastian Paul,et al.  Analysis of ageing inhomogeneities in lithium-ion battery systems , 2013 .

[23]  Richard Barney Carlson,et al.  Enabling fast charging – Vehicle considerations , 2017 .

[24]  Yun-Sung Lee,et al.  The study of electrochemical properties and lithium deposition of graphite at low temperature , 2012 .

[25]  M. Dubarry,et al.  Operando lithium plating quantification and early detection of a commercial LiFePO 4 cell cycled under dynamic driving schedule , 2017 .

[26]  Rajeswari Chandrasekaran,et al.  Quantification of bottlenecks to fast charging of lithium-ion-insertion cells for electric vehicles , 2014 .

[27]  M. Dubarry,et al.  Cell degradation in commercial LiFePO4 cells with high-power and high-energy designs , 2014 .

[28]  Richard Barney Carlson,et al.  Enabling fast charging – A battery technology gap assessment , 2017 .

[29]  Matthieu Dubarry,et al.  Synthesize battery degradation modes via a diagnostic and prognostic model , 2012 .