Characterization of a Delta8-sphingolipid desaturase from higher plants: a stereochemical and mechanistic study on the origin of E,Z isomers.

[1]  G. Fabriàs,et al.  Stereospecificity of the (Z)-9 desaturase that converts (E)-11-tetradecenoic acid into (Z,E)-9,11-tetradecadienoic acid in the biosynthesis of Spodoptera littoralis sex pheromone. , 2001, Insect biochemistry and molecular biology.

[2]  P. H. Buist,et al.  Mechanism of fatty acid desaturation in the green alga Chlorella vulgaris. , 2001, European journal of biochemistry.

[3]  P. H. Buist,et al.  Dihydroceramide delta(4) desaturase initiates substrate oxidation at C-4. , 2001, Journal of the American Chemical Society.

[4]  A. Hetherington,et al.  Drought-induced guard cell signal transduction involves sphingosine-1-phosphate , 2001, Nature.

[5]  E. Heinz,et al.  Desaturases fused to their electron donor , 2001 .

[6]  P. H. Buist,et al.  Gamma-linolenic acid biosynthesis: cryptoregiochemistry of delta6 desaturation. , 2001, The Journal of organic chemistry.

[7]  J. Shanklin,et al.  Application of KIE and thia approaches in the mechanistic study of a plant stearoyl-ACP Δ9 desaturase , 2001 .

[8]  E. Heinz,et al.  Further characterization of Δ8-sphingolipid desaturases from higher plants , 2000 .

[9]  G. Fabriàs,et al.  Is Hydrogen Tunneling Involved in AcylCoA Desaturase Reactions? The Case of a Δ9 Desaturase That Transforms (E)‐11‐Tetradecenoic Acid into (Z,E)‐9,11‐Tetradecadienoic Acid , 2000 .

[10]  S. J. Ambrose,et al.  Characterization of the regiochemistry and cryptoregiochemistry of a Caenorhabditis elegans fatty acid desaturase (FAT-1) expressed in Saccharomyces cerevisiae. , 2000, Biochemistry.

[11]  J. Baldwin,et al.  Spectroscopic and Electronic Structure Description of the Reduced Binuclear Non-Heme Iron Active Site in Ribonucleotide Reductase from E. coli: Comparison to Reduced Δ9 Desaturase and Electronic Structure Contributions to Differences in O2 Reactivity , 2000 .

[12]  S. Lippard,et al.  Understanding the dioxygen reaction chemistry of diiron proteins through synthetic modeling studies , 2000 .

[13]  O. Thum,et al.  (6r,7r)4,5,6,7-H-2(4) -palmitoate and (8S,9R)-[8,9-H-2(2)]-L-erythro-sphinganine: Probes for the analysis of the stereochemical course of Delta(6)-desaturases from plants and insects , 1999 .

[14]  G. Fabriàs,et al.  Cryptoregiochemistry of the delta11-myristoyl-CoA desaturase involved in the biosynthesis of Spodoptera littoralis sex pheromone. , 1999, Biochemistry.

[15]  W. Boland,et al.  Stereochemistry of lepidopteran sex pheromone biosynthesis: a comparison of fatty acid CoA Delta 11-(Z)-desaturases in Bombyx mori and Manduca sexta female moths , 1999 .

[16]  E. Heinz,et al.  A Sphingolipid Desaturase from Higher Plants , 1998, The Journal of Biological Chemistry.

[17]  John Shanklin,et al.  DESATURATION AND RELATED MODIFICATIONS OF FATTY ACIDS1. , 1998, Annual review of plant physiology and plant molecular biology.

[18]  B. Fox,et al.  The fundamental, versatile role of diiron enzymes in lipid metabolism , 1998 .

[19]  P. H. Buist,et al.  Deciphering the Cryptoregiochemistry of Oleate Δ12 Desaturase: A Kinetic Isotope Effect Study , 1998 .

[20]  H. Rui,et al.  Activation of the Jak2-Stat5 Signaling Pathway in Nb2 Lymphoma Cells by an Anti-apoptotic Agent, Aurintricarboxylic Acid* , 1998, The Journal of Biological Chemistry.

[21]  G. Fabriàs,et al.  Stereospecificity of the (E)- and (Z)-11 Myristoyl CoA Desaturases in the Biosynthesis of Spodoptera littoralis Sex Pheromone , 1997 .

[22]  M. Ohnishi,et al.  Sphingoid Base Composition of Cerebrosides from Plant Leaves , 1997 .

[23]  Gunter Schneider,et al.  Crystal structure of delta9 stearoyl‐acyl carrier protein desaturase from castor seed and its relationship to other di‐iron proteins. , 1996, The EMBO journal.

[24]  P. H. Buist,et al.  USE OF DEUTERIUM KINETIC ISOTOPE EFFECTS TO PROBE THE CRYPTOREGIOCHEMISTRYOF DELTA 9 DESATURATION , 1996 .

[25]  M. VanNieuwenhze,et al.  Catalytic Asymmetric Dihydroxylation , 1994 .

[26]  F. Schneider,et al.  Effect of cerulenin on the synthesis of very-long-chain fatty acids in microsomes from leek seedlings. , 1993, Biochimica et biophysica acta.

[27]  P. Knochel,et al.  Cross-coupling between functionalized alkylcopper reagents and functionalized alkyl halides , 1993 .

[28]  W. Boland,et al.  Sex pheromone biosynthesis in Mamestra brassicae l. (lepidoptera: noctuidae); stereochemistry of the Δ11 desaturation , 1993 .

[29]  T. Takata,et al.  Oxidation of dihydroxyaromatics by hypervalent iodine oxides: a facil quinone synthesis , 1983 .

[30]  A. T. James,et al.  The stereochemistry of desaturations of long-chain fatty acids in Chlorella vulgaris. , 1968, The Biochemical journal.