Reactive dual magnetron sputtering of Ta2O5 and Al2O3: optical and structural properties and thin film applications

In this paper we perform a systematic investigation and optimization of lambda controlled, reactive ion beam sputter deposition process conditions for a range of optical materials. The deposited films are compared for suitability for applications such as planar waveguides for optical interconnect, laser device manufacture, multi-layer interference filters, and precision optical mirrors. Thin films of tantalum pentoxide and aluminum oxide were deposited using a reactive dual-magnetron sputtering system (Leybold Optics Helios Pro). Deposited film quality was optimized as a function of plasma power and gas flow, and an optimum oxygen working point was determined for each material. Lambda control methods were used for the purpose of optimizing optical quality of the layer. Deposited layers were characterized by variable angle spectroscopic ellipsometry (VASE), X-ray diffraction (XRD) and SEM imaging. Waveguide losses were measured for each sample using a prism coupling arrangement. Tantalum pentoxide slab waveguides with loss as low as 1dB/cm were produced ideal for waveguide applications. Interference filters/mirrors consisting of alternating SiO2, and Ta2O5 or Al2O3 material layers were deposited and characterized. Reflectivity and transmission of the deposited mirrors was compared to the theoretical design. Good agreement between the theory and the practical filter/mirror designs was achieved confirming the material film quality.

[1]  J. M. Albella,et al.  Reactive sputtered Ta2O5 antireflection coatings , 1983 .

[2]  D. Shepherd,et al.  Erbium-Doped Waveguide Laser in Tantalum Pentoxide , 2010, IEEE Photonics Technology Letters.

[3]  C. Thomason,et al.  High Density Double and Triple Layer Tantalum Pentoxide Decoupling Capacitors , 2007, IEEE Transactions on Components and Packaging Technologies.

[4]  Elena Atanassova,et al.  Electrical characteristics of Ta2O5 based capacitors with different gate electrodes , 2006 .

[5]  S. Lau,et al.  OPTICAL PROPERTIES OF FILTERED CATHODIC VACUUM ARC-DEPOSITED ZIRCONIUM OXIDE THIN FILMS , 2003 .

[6]  M. Hon,et al.  The effect of residual stress on the adhesion of PECVD-coated aluminum oxide film on glass , 1996 .

[7]  M. E. Graham,et al.  Reactive direct current magnetron sputtering of aluminum oxide coatings , 1995 .

[8]  R. Willey Design of blocking filters of any narrow bandwidth. , 2007, Applied optics.

[9]  Sung-Dong Cho,et al.  Study on the amorphous Ta2O5 thin film capacitors deposited by dc magnetron reactive sputtering for multichip module applications , 1999 .

[10]  E. Wallin,et al.  Phase control of Al2O3 thin films grown at low temperatures , 2006 .

[11]  Maryam Olsson,et al.  High rate reactive dc magnetron sputter deposition of Al2O3 films , 1998 .

[12]  Shiuh Chao,et al.  Refractive index variation of amorphous Ta2O5 film fabricated by ion beam sputtering with RF bias power , 2009 .

[13]  R W Eason,et al.  Dielectric binary oxide films as waveguide laser media: a review , 2008, Journal of physics. Condensed matter : an Institute of Physics journal.

[14]  J. Gottmann,et al.  Pulsed laser deposition of ceramic thin films using different laser sources , 1998 .

[15]  A. Sobczyk-Guzenda,et al.  Characterization of thin TiO2 films prepared by plasma enhanced chemical vapour deposition for optical and photocatalytic applications , 2009 .

[16]  S. Raoux,et al.  Formation of metal oxides by cathodic arc deposition , 1995 .

[17]  Steffen Wilbrandt,et al.  Plasma ion assisted deposition of aluminium oxide and aluminium oxifluoride layers for applications in the ultraviolet spectral range , 2011 .

[18]  G. J. Parker,et al.  Structural and optical properties of yttrium oxide thin films for planar waveguiding applications , 2010 .

[19]  A. S. Hovhannisyan Single-layer antireflection coatings for GaAs solar cells , 2008 .

[20]  N. Sandler,et al.  Tantalum pentoxide for advanced DRAM applications , 1996 .

[21]  C. Hoffmann,et al.  Evanescent field Sensors Based on Tantalum Pentoxide Waveguides – A Review , 2008, Sensors.