论文信息 - Synthesis of dimethyl carbonate from ethylene carbonate and methanol using TS-1 as solid base catalyst - 字舞流文

Synthesis of dimethyl carbonate from ethylene carbonate and methanol using TS-1 as solid base catalyst

The titanium silicate molecular sieve, TS-1, exchanged with an aqueous solution of K2CO3 is an excellent heterogeneous catalyst for the synthesis of dimethyl carbonate by an ester exchange reaction between ethylene carbonate and methanol.

T. Tatsumi | Y. Watanabe | K. Koyano

[1] G. Bellussi,et al. Metal Ions Associated to the Molecular Sieve Framework: Possible Catalytic Oxidation Sites , 1995 .

[2] P. Ratnasamy,et al. Catalytic properties of titanium silicalites: IV. Vapour phase beckmann rearrangement of cyclohexanone oxime , 1992 .

[3] S. Sivaram,et al. Dialkyl and diaryl carbonates by carbonate interchange reaction with dimethyl carbonate , 1992 .

[4] J. F. Knifton,et al. Ethylene glycol—dimethyl carbonate cogeneration , 1991 .

[5] Mark E. Davis,et al. Catalytic Activity of Titanium Silicates Synthesized in the Presence of Alkali-Metal and Alkaline-Earth Ions , 1995 .

[6] A. Auroux,et al. Acidic properties of titanium-silicalites-1 , 1994 .

[7] A. Zecchina,et al. Spectroscopic Characterization of Silicalite and Titanium-Silicalite , 1989 .