Integration of high-k gate stack systems into planar CMOS process flows

We review several gate stack fabrication issues critical for robust, commercially viable tools, including assessment of possible fab contamination due to the higher-k gate dielectrics and the role of subsequent thermal procedures during, for example, source/drain anneals (including the importance of the oxygen partial pressure) to ensure their compatibility with conventional planar polysilicon CMOS transistor fabrication processes.

[1]  J. Meindl,et al.  Limits on silicon nanoelectronics for terascale integration. , 2001, Science.

[2]  S. Addepalli,et al.  Dielectric breakdown of ultrathin aluminum oxide films induced by scanning tunneling microscopy , 2000 .

[3]  W. Epling,et al.  Evidence of aluminum silicate formation during chemical vapor deposition of amorphous Al2O3 thin films on Si(100) , 1999 .

[4]  T. P. Ma,et al.  Making Silicon Nitride Film a Viable Gate Dielectric , 1998 .

[5]  K. Ahmed,et al.  Characterization of ultra-thin oxides using electrical C-V and I-V measurements , 1998 .

[6]  Harald F. Okorn-Schmidt,et al.  Characterization of silicon surface preparation processes for advanced gate dielectrics , 1999, IBM J. Res. Dev..

[7]  A. Kingon,et al.  Structure and stability of La2O3/SiO2 layers on Si(001) , 2001 .

[8]  G. Bersuker,et al.  Conventional n-channel MOSFET devices using single layer HfO/sub 2/ and ZrO/sub 2/ as high-k gate dielectrics with polysilicon gate electrode , 2001, International Electron Devices Meeting. Technical Digest (Cat. No.01CH37224).

[9]  Chenming Hu,et al.  MOS capacitance measurements for high-leakage thin dielectrics , 1999 .

[10]  Masao Fukuma New frontiers of sub-100 nm VLSI technology-moving toward device and circuit co-design , 2000, 2000 Symposium on VLSI Technology. Digest of Technical Papers (Cat. No.00CH37104).

[11]  Qi Xiang,et al.  Limits of gate-oxide scaling in nano-transistors , 2000, 2000 Symposium on VLSI Technology. Digest of Technical Papers (Cat. No.00CH37104).

[12]  E. Cartier,et al.  Robustness of ultrathin aluminum oxide dielectrics on Si(001) , 2001 .

[13]  Yuan Taur,et al.  Device scaling limits of Si MOSFETs and their application dependencies , 2001, Proc. IEEE.

[14]  Tso-Ping Ma,et al.  Making silicon nitride film a viable gate dielectric , 1998 .

[15]  I. Baumvol,et al.  Stability of zirconium silicate films on Si under vacuum and O2 annealing , 2001 .

[16]  P. Packan,et al.  Pushing the Limits , 1999, Science.

[17]  T. Higman Comparison of conductance and capacitance techniques for measurement of interface states in thin oxides , 2001 .

[18]  H.-S.P. Wong,et al.  Carrier mobility enhancement in strained Si-on-insulator fabricated by wafer bonding , 2001, 2001 Symposium on VLSI Technology. Digest of Technical Papers (IEEE Cat. No.01 CH37184).

[19]  J. Meindl,et al.  A circuit-level perspective of the optimum gate oxide thickness , 2001 .

[20]  Heung-Jae Cho,et al.  Boron penetration in p+polycrystalline-Si/Al2O3/Si metal–oxide–semiconductor system , 2000 .

[21]  Yoshio Nishi,et al.  Limits of integrated-circuit manufacturing , 2001, Proc. IEEE.

[22]  J. Robertson Band offsets of wide-band-gap oxides and implications for future electronic devices , 2000 .

[23]  Hyunsang Hwang,et al.  Electrical characteristics of ZrOxNy prepared by NH3 annealing of ZrO2 , 2001 .

[24]  T. Nigam,et al.  Temperature acceleration of oxide breakdown and its impact on ultra-thin gate oxide reliability , 1999, 1999 Symposium on VLSI Technology. Digest of Technical Papers (IEEE Cat. No.99CH36325).

[25]  Thomas Skotnicki Analysis of the silicon technology roadmap How far can CMOS go , 2000 .

[26]  K. Saraswat,et al.  Electrical and materials properties of ZrO2 gate dielectrics grown by atomic layer chemical vapor deposition , 2001 .

[27]  P. Packan Scaling Transistors into the Deep-Submicron Regime , 2000 .

[28]  N. Miyata,et al.  Study of ultrathin Al2O3/Si(001) interfaces by using scanning reflection electron microscopy and x-ray photoelectron spectroscopy , 2001 .

[29]  B. Vermeire,et al.  The effect of hafnium or zirconium contamination on MOS processes , 2002, 13th Annual IEEE/SEMI Advanced Semiconductor Manufacturing Conference. Advancing the Science and Technology of Semiconductor Manufacturing. ASMC 2002 (Cat. No.02CH37259).

[30]  Jongwook Jeon,et al.  Effect of polysilicon gate on the flatband voltage shift and mobility degradation for ALD-Al/sub 2/O/sub 3/ gate dielectric , 2000, International Electron Devices Meeting 2000. Technical Digest. IEDM (Cat. No.00CH37138).

[31]  Evgeni P. Gusev,et al.  Structure and stability of ultrathin zirconium oxide layers on Si(001) , 2000 .

[32]  G. Lucovsky,et al.  Microscopic model for enhanced dielectric constants in low concentration SiO2-rich noncrystalline Zr and Hf silicate alloys , 2000 .

[33]  G. D. Wilka,et al.  APPLIED PHYSICS REVIEW High- k gate dielectrics: Current status and materials properties considerations , 2001 .

[34]  Angus I. Kingon,et al.  High temperature stability in lanthanum and zirconia-based gate dielectrics , 2001 .

[35]  Jack C. Lee,et al.  Ultrathin zirconium silicate film with good thermal stability for alternative gate dielectric application , 2000 .

[36]  D. Kwong,et al.  High quality ultra thin CVD HfO/sub 2/ gate stack with poly-Si gate electrode , 2000, International Electron Devices Meeting 2000. Technical Digest. IEDM (Cat. No.00CH37138).

[37]  Jack C. Lee,et al.  MOSFET devices with polysilicon on single-layer HfO/sub 2/ high-K dielectrics , 2000, International Electron Devices Meeting 2000. Technical Digest. IEDM (Cat. No.00CH37138).

[38]  Heiji Watanabe Interface engineering of a ZrO2/SiO2/Si layered structure by in situ reoxidation and its oxygen-pressure-dependent thermal stability , 2001 .

[39]  H. Zhang,et al.  High permittivity thin film nanolaminates , 2000 .

[40]  D. Schlom,et al.  Thermodynamic stability of binary oxides in contact With silicon , 1996 .

[41]  P. Roman,et al.  Studies of high-k dielectrics deposited by liquid source misted chemical deposition in MOS gate structures , 2001, 2001 IEEE/SEMI Advanced Semiconductor Manufacturing Conference (IEEE Cat. No.01CH37160).

[42]  J. L. Duggan,et al.  Thermally induced Zr incorporation into Si from zirconium silicate thin films , 2001 .

[43]  W.J. Chen,et al.  High quality La/sub 2/O/sub 3/ and Al/sub 2/O/sub 3/ gate dielectrics with equivalent oxide thickness 5-10 /spl Aring/ , 2000, 2000 Symposium on VLSI Technology. Digest of Technical Papers (Cat. No.00CH37104).

[44]  Yuan Taur,et al.  Modeling and characterization of quantization, polysilicon depletion, and direct tunneling effects in MOSFETs with ultrathin oxides , 1999, IBM J. Res. Dev..

[45]  R. V. van Dover,et al.  Si-doped aluminates for high temperature metal-gate CMOS: Zr-Al-Si-O, a novel gate dielectric for low power applications , 2000, International Electron Devices Meeting 2000. Technical Digest. IEDM (Cat. No.00CH37138).

[46]  H. Lemke Properties of Silicon Crystals Doped with Zirconium or Hafnium , 1990 .

[47]  Kevin K. H. Chan,et al.  80 nm poly':'silicon gated n-FETs with ultra-thin Ah03 gate dielectric for ULSI applications , 2000 .

[48]  Eduard A. Cartier,et al.  Materials characterization of ZrO2–SiO2 and HfO2–SiO2 binary oxides deposited by chemical solution deposition , 2001 .

[49]  H. Huff,et al.  Sources of resonance-related errors in capacitance versus voltage measurement systems , 2000 .

[50]  H. Ade,et al.  Electronic structure of noncrystalline transition metal silicate and aluminate alloys , 2001 .

[51]  Eduard A. Cartier,et al.  High-resolution depth profiling in ultrathin Al2O3 films on Si , 2000 .

[52]  In-Seok Yeo,et al.  Characteristics of Al/sub 2/O/sub 3/ gate dielectric prepared by atomic layer deposition for giga scale CMOS DRAM devices , 2000, 2000 Symposium on VLSI Technology. Digest of Technical Papers (Cat. No.00CH37104).

[53]  James D. Plummer,et al.  Material and process limits in silicon VLSI technology , 2001, Proc. IEEE.

[54]  John S. Suehle,et al.  Electrical conduction and dielectric breakdown in aluminum oxide insulators on silicon , 2000 .

[55]  Eduard A. Cartier,et al.  Atomic beam deposition of lanthanum- and yttrium-based oxide thin films for gate dielectrics , 2000 .

[56]  Shin Yokoyama,et al.  Atomic-layer-deposited silicon-nitride/SiO2 stacked gate dielectrics for highly reliable p-metal–oxide–semiconductor field-effect transistors , 2000 .

[57]  Kaustav Banerjee,et al.  Interconnect limits on gigascale integration (GSI) in the 21st century , 2001, Proc. IEEE.

[58]  Jon-Paul Maria,et al.  Alternative dielectrics to silicon dioxide for memory and logic devices , 2000, Nature.

[59]  Process and Manufacturing Challenges for High-K Gate Stack Systems , 1999 .

[60]  Dim-Lee Kwong,et al.  Thermal stability of ultrathin ZrO2 films prepared by chemical vapor deposition on Si(100) , 2001 .

[61]  Jack C. Lee,et al.  Thermal stability and electrical characteristics of ultrathin hafnium oxide gate dielectric reoxidized with rapid thermal annealing , 2000 .

[62]  Tooru Katsumata,et al.  Interfacial reactions between thin rare-earth-metal oxide films and Si substrates , 2001 .

[63]  S.J. Lee,et al.  Performance and reliability of ultra thin CVD HfO/sub 2/ gate dielectrics with dual poly-Si gate electrodes , 2001, 2001 Symposium on VLSI Technology. Digest of Technical Papers (IEEE Cat. No.01 CH37184).

[64]  R. Solanki,et al.  Atomic Layer Deposition of High Dielectric Constant Nanolaminates , 2001 .

[65]  A. Chin,et al.  Electrical characteristics of high quality La2O3 gate dielectric with equivalent oxide thickness of 5 /spl Aring/ , 2000, IEEE Electron Device Letters.

[66]  Gordon E. Moore,et al.  Lithography and the future of Moore's law , 1995, Advanced Lithography.

[67]  Tahir Ghani,et al.  Scaling challenges and device design requirements for high performance sub-50 nm gate length planar CMOS transistors , 2000, 2000 Symposium on VLSI Technology. Digest of Technical Papers (Cat. No.00CH37104).

[68]  Eduard A. Cartier,et al.  Molecular-beam-deposited yttrium-oxide dielectrics in aluminum-gated metal–oxide–semiconductor field-effect transistors: Effective electron mobility , 2001 .