Fractionation of trace metals in surface water with screen filters

Abstract Size fractionation of solid particulate phases serving as carriers of trace elements (e.g. Al, Cd, Cu, Fe, Mn and Zn) in surface waters was conducted by pressure filtration using screen filters with defined pore sizes in the range 5-0.015 μm. The particle size distribution in solution was determined by Photon Correlation Spectroscopy. The accumulation of solids on the filter surface was demonstrated, leading to a successive reduction of the efficient pore size (‘clogging’). Thus, filters with a defined pore size of 0.40 μm and a diameter of 47 mm had an apparent separation efficiency corresponding to a pore size of 0.015 μm after filtration of 100 ml containing approximately 100 mg/l of suspended solids. Aluminium and iron were almost exclusively present in the particle size range 5-0.20 μm. Copper and manganese were retained to 45% and zinc and cadmium to 30% by the 0.015-μm pore size filter.

[1]  M. Piscator The Dependence of Toxic Reactions on the Chemical Species of Elements , 1986 .

[2]  B. Salbu,et al.  Size fractionation techniques in the determination of elements associated with particulate or colloidal materials in natural fresh waters. , 1985, Talanta.

[3]  C. Johnson The regulation of trace element concentrations in river and estuarine waters contaminated with acid mine drainage: The adsorption of Cu and Zn on amorphous Fe oxyhydroxides , 1986 .

[4]  R. James,et al.  The adsorption of aqueous heavy metals on inorganic minerals , 1977 .

[5]  B. Allard,et al.  Environmental Impacts of an Old Mine Tailings Deposit — Metal Adsorption by Particulate Matter , 1987 .

[6]  S. Eisenreich,et al.  Characterization of soluble and colloidal phase metal complexes in river water by ultrafiltration. A mass-balance approach. , 1981, Environmental science & technology.

[7]  D. Jones,et al.  Processes controlling metal ion attenuation in acid mine drainage streams , 1983 .

[8]  W. Salomons,et al.  Chemical Species and Metal Transport in Lakes , 1986 .

[9]  P. Benes,et al.  Migration forms of trace elements in natural fresh waters and the effect of the water storage , 1975 .

[10]  J. Gentry,et al.  Clogging in nuclepore filters , 1978 .

[11]  P. Sandén Estimation and simulation of metal mass transport in an old mining area , 1991 .

[12]  D. Kinniburgh,et al.  Adsorption of alkaline earth transition and heavy metal cations by hydrous oxide gels of iron and aluminum , 1976 .

[13]  B. Hart,et al.  A new dialysis-ion exchange technique for determining the forms of trace metals in water , 1977 .

[14]  M. Meybeck,et al.  Elemental mass-balance of material carried by major world rivers , 1979 .

[15]  A. Ledin,et al.  Applicability of photon correlation spectroscopy for measurement of concentration and size distribution of colloids in natural waters , 1993 .

[16]  B. Allard,et al.  Characterization of suspended solids in a stream receiving acid mine effluents, Bersbo, Sweden , 1988 .

[17]  D. Laxen,et al.  Comparison of filtration techniques for size distribution in freshwaters , 1982 .

[18]  L. Sigg,et al.  Adsorption of trace metals on aluminium oxide: A simulation of processes in freshwater systems by close approximation to natural conditions , 1988 .

[19]  Wim Salomons,et al.  Metals in the Hydrocycle. , 1983 .

[20]  L. Danielsson On the use of filters for distinguishing between dissolved and particulate fractions in natural waters , 1982 .

[21]  P. Benes,et al.  In Situ Dialysis for the Determination of the State of Trace Elements In Natural Waters , 1974 .

[22]  E. Sholkovitz,et al.  Adsorption (co‐precipitation) of trace metals at natural concentrations on hydrous ferric oxide in lake water samples , 1981 .