论文信息 - Statistical thermodynamics of oligomer–polymer interactions

Statistical thermodynamics of oligomer–polymer interactions

A new method for formulating partition functions for a system of particles interacting on a one‐dimensional lattice has recently been developed.3,4 In this paper the method is applied to oligomer–polymer systems. The details of the connection between this method and the matrix formulation are first established. The method is then used to find expressions for the partition function of an oligomer–polymer system when the oligomers have a distribution of lengths and an alternating sequence.

C. DeLisi | Charles Delisi

[1] C. DeLisi. Cooperative phenomena in homopolymers. An alternative formulation of the partition function , 1974 .

[2] D. Crothers. Statistical thermodynamics of nucleic acid melting transitions with coupled binding equilibria , 1971, Biopolymers.

[3] G. F. Newell,et al. Statistical thermodynamic theory for helix-coil transitions involving poly- and oligonucleotides. II. The case of partial binding. , 1965, The Journal of chemical physics.

[4] Shneior Lifson,et al. Partition Functions of Linear‐Chain Molecules , 1964 .

[5] B. Zimm,et al. Theory of helix–coil transitions involving complementary poly‐ and oligo‐nucleotides. I. The complete binding case , 1963 .

[6] B. Zimm,et al. Theory of the One‐Dimensional Phase Transition in Polypeptide Chains , 1958 .