Prediction of the effective moisture diffusivity in gelatinized food systems

Abstract Gelatinized food systems develop a porous structure during dehydration; therefore, the moisture diffusivity calculated from such experiments should be considered as an effective diffusion coefficient. In this work, the effective moisture diffusivity of gelatinized starches was determined from drying experiments using the method of slopes. A methodology is presented which permits the calculation of the effective moisture diffusivity from the diffusion coefficients of the two phases (air-solid) and the porosity of the system. The diffusion coefficient of the homogenous solid phase (gel) was estimated from the calculated values of the effective diffusion coefficient, using non-linear regression analysis. Its value depends on the moisture content and temperature and varies in the range 1·4 × 10 −11 to 2·6 × 10 −10 m 2 /s for Amioca and 4·1 × 10 −11 to 3·2 × 10 −10 m 2 /s for Hylon 7.

[1]  Vaios T. Karathanos,et al.  Effect of Sugars on the Water Diffusivity in Hydrated Granular Starches , 1989 .

[2]  J. K. Liou,et al.  An approximate method for the nonlinear diffusion problem with a power relation between diffusion coefficient and concentration—II. Computation of concentration profiles , 1982 .

[3]  W. Higuchi,et al.  Theoretical analysis of diffusional movement through heterogeneous barriers , 1960 .

[4]  C. Tong,et al.  Effective Moisture Diffusivity in Porous Materials as a Function of Temperature and Moisture Content , 1990 .

[5]  S. Cheng,et al.  The prediction of the thermal conductivity of two and three phase solid heterogeneous mixtures , 1969 .

[6]  Enrique Rotstein,et al.  Prediction of Thermal Conductivity of Vegetable Foods by the Effective Medium Theory , 1986 .

[7]  Ernst Behrens,et al.  Thermal Conductivities of Composite Materials , 1968 .

[8]  J. Throne,et al.  Methods for predicting the thermal conductivity of composite systems: A review , 1976 .

[9]  Zacharias B. Maroulis,et al.  Application of the GAB model to the moisture sorption isotherms for dried fruits , 1988 .

[10]  O. W. Witzell,et al.  THERMAL CONDUCTIVITY OF GRAPHITE-SILICONE OIL AND GRAPHITE-WATER SUSPENSIONS , 1958 .

[11]  H. W. Russell PRINCIPLES OF HEAT FLOW IN POROUS INSULATORS , 1935 .

[12]  Pradeep B. Deshpande,et al.  Thermal Conductivity of Two-Phase Systems , 1972 .

[13]  Vaios T. Karathanos,et al.  Comparison of Two Methods of Estimation of the Effective Moisture Diffusivity from Drying Data , 1990 .

[14]  Vaios T. Karathanos,et al.  Prediction of Moisture Diffusivity in Granular Materials, with Special Applications to Foods , 1991 .

[15]  John Crank,et al.  The Mathematics Of Diffusion , 1956 .

[16]  S. Prager,et al.  Diffusion in Inhomogeneous Media , 1960 .