Facile Synthesis of High-Molecular-Weight Vinyl Sulfone (Sulfoxide) Modified Polyethylenes via Coordination–Insertion Copolymerization

Vinyl sulfones or sulfoxides are problematic monomers to polymerize via any polymerization mechanism. In this contribution, a comprehensive picture of ethylene/vinyl sulfone (sulfoxide) copolymeriz...

[1]  Changle Chen,et al.  Polar-Functionalized, Crosslinkable, Self-Healing and Photoresponsive Polyolefins. , 2019, Angewandte Chemie.

[2]  Changle Chen,et al.  Emerging Palladium and Nickel Catalysts for Copolymerization of Olefins with Polar Monomers. , 2019, Angewandte Chemie.

[3]  Yue-sheng Li,et al.  Elaborate Tuning in Ligand Makes a Big Difference in Catalytic Performance: Bulky Nickel Catalysts for (Co)polymerization of Ethylene with Promising Vinyl Polar Monomers , 2019, ChemCatChem.

[4]  A. Takahara,et al.  Synthesis of Self-Healing Polymers by Scandium-Catalyzed Copolymerization of Ethylene and Anisylpropylenes. , 2019, Journal of the American Chemical Society.

[5]  Xuequan Zhang,et al.  Structurally simple dinuclear nickel catalyzed olefin copolymerization with polar monomers , 2018, Journal of Catalysis.

[6]  M. Brookhart,et al.  Exploring Ethylene/Polar Vinyl Monomer Copolymerizations Using Ni and Pd α-Diimine Catalysts. , 2018, Accounts of chemical research.

[7]  Yue-sheng Li,et al.  Robust Bulky [P,O] Neutral Nickel Catalysts for Copolymerization of Ethylene with Polar Vinyl Monomers , 2018 .

[8]  Changle Chen,et al.  A Versatile Ligand Platform for Palladium- and Nickel-Catalyzed Ethylene Copolymerization with Polar Monomers. , 2018, Angewandte Chemie.

[9]  T. Shiono,et al.  Highly Robust Nickel Catalysts Containing Anilinonaphthoquinone Ligand for Copolymerization of Ethylene and Polar Monomers , 2017 .

[10]  O. Daugulis,et al.  Nickel-Catalyzed Copolymerization of Ethylene and Vinyltrialkoxysilanes: Catalytic Production of Cross-Linkable Polyethylene and Elucidation of the Chain-Growth Mechanism. , 2017, Journal of the American Chemical Society.

[11]  Yi Luo,et al.  A Second-Coordination-Sphere Strategy to Modulate Nickel- and Palladium-Catalyzed Olefin Polymerization and Copolymerization. , 2017, Angewandte Chemie.

[12]  Samir H. Chikkali,et al.  Reactivity of Difunctional Polar Monomers and Ethylene Copolymerization: A Comprehensive Account , 2017 .

[13]  Z. Hou,et al.  Heteroatom-assisted olefin polymerization by rare-earth metal catalysts , 2017, Science Advances.

[14]  Guodong Liang,et al.  Enhancing Thermal Stability and Living Fashion in α-Diimine–Nickel-Catalyzed (Co)polymerization of Ethylene and Polar Monomer by Increasing the Steric Bulk of Ligand Backbone , 2017 .

[15]  Y. Oishi,et al.  Nickel Catalyzed Copolymerization of Ethylene and Alkyl Acrylates. , 2017, Journal of the American Chemical Society.

[16]  Changle Chen,et al.  Rational Design of High-Performance Phosphine Sulfonate Nickel Catalysts for Ethylene Polymerization and Copolymerization with Polar Monomers , 2017 .

[17]  O. Daugulis,et al.  Mechanistic Studies of Pd(II)-Catalyzed Copolymerization of Ethylene and Vinylalkoxysilanes: Evidence for a β-Silyl Elimination Chain Transfer Mechanism. , 2016, Journal of the American Chemical Society.

[18]  K. Winey,et al.  High Melting Precision Sulfone Polyethylenes Synthesized by ADMET Chemistry , 2016 .

[19]  G. Coates,et al.  Semi-Crystalline Polar Polyethylene: Ester-Functionalized Linear Polyolefins Enabled by a Functional-Group-Tolerant, Cationic Nickel Catalyst. , 2016, Angewandte Chemie.

[20]  K. Nozaki,et al.  Copolymerization of Ethylene and Polar Monomers by Using Ni/IzQO Catalysts. , 2016, Angewandte Chemie.

[21]  S. Mecking,et al.  Reactivity of Functionalized Vinyl Monomers in Insertion Copolymerization , 2016 .

[22]  K. Nozaki,et al.  Copolymerization of Propylene and Polar Monomers Using Pd/IzQO Catalysts. , 2015, Journal of the American Chemical Society.

[23]  S. Mecking,et al.  Post-metallocenes in the industrial production of polyolefins. , 2014, Angewandte Chemie.

[24]  R. F. Jordan,et al.  Copolymerization of Ethylene and Methyl Acrylate by Cationic Palladium Catalysts That Contain Phosphine-Diethyl Phosphonate Ancillary Ligands , 2014 .

[25]  Yue-sheng Li,et al.  Syntheses of Well-Defined Functional Isotactic Polypropylenes via Efficient Copolymerization of Propylene with ω-Halo-α-alkenes by Post-metallocene Hafnium Catalyst , 2014 .

[26]  V. Goldbach,et al.  Electronic Influences in Phosphinesulfonato Palladium(II) Polymerization Catalysts , 2013 .

[27]  S. Mecking,et al.  Incorporation of vinyl chloride in insertion polymerization. , 2013, Angewandte Chemie.

[28]  Ayusman Sen,et al.  Ortho-phosphinobenzenesulfonate: a superb ligand for palladium-catalyzed coordination-insertion copolymerization of polar vinyl monomers. , 2013, Accounts of chemical research.

[29]  Yong Tang,et al.  Copolymerization of Ethylene with Functionalized Olefins by [ONX] Titanium Complexes , 2013 .

[30]  Y. Ota,et al.  Ethylene/allyl monomer cooligomerization by nickel/phosphine-sulfonate catalysts. , 2012, Dalton transactions.

[31]  K. Nozaki,et al.  Synthesis of functional polyolefins using cationic bisphosphine monoxide-palladium complexes. , 2012, Journal of the American Chemical Society.

[32]  S. Mecking,et al.  Limits of Activity : Weakly Coordinating Ligands in Arylphosphinesulfonato Palladium(II) Polymerization Catalysts , 2012 .

[33]  S. Mecking,et al.  Mechanistic insights into polar monomer insertion polymerization from acrylamides. , 2012, Journal of the American Chemical Society.

[34]  L. Cavallo,et al.  Mechanistic insights on acrylate insertion polymerization. , 2010, Journal of the American Chemical Society.

[35]  S. Mecking,et al.  Catalytic Copolymerization of Ethylene with Vinyl Sulfones , 2010 .

[36]  Zheng Wang,et al.  [O-NSR]TiCl3-catalyzed copolymerization of ethylene with functionalized olefins. , 2009, Angewandte Chemie.

[37]  K. Nozaki,et al.  Coordination-insertion copolymerization of fundamental polar monomers. , 2009, Chemical reviews.

[38]  K. Nozaki,et al.  Copolymerization of vinyl acetate with ethylene by palladium/alkylphosphine-sulfonate catalysts. , 2009, Journal of the American Chemical Society.

[39]  B. Goodall,et al.  Kinetic and Mechanistic Aspects of Ethylene and Acrylates Catalytic Copolymerization in Solution and in Emulsion , 2009 .

[40]  H. Möller,et al.  Mechanistic insights on the copolymerization of polar vinyl monomers with neutral Ni(II) catalysts. , 2009, Journal of the American Chemical Society.

[41]  Philipp Roesle,et al.  Insertion polymerization of acrylate. , 2009, Journal of the American Chemical Society.

[42]  R. Smith,et al.  Polymers : A Property Database, Second Edition , 2008 .

[43]  Changle Chen,et al.  Multiple insertion of a silyl vinyl ether by (alpha-diimine)PdMe+ species. , 2008, Journal of the American Chemical Society.

[44]  R. F. Jordan,et al.  Copolymerization of ethylene and vinyl fluoride by (phosphine-sulfonate)Pd(Me)(py) catalysts. , 2007, Journal of the American Chemical Society.

[45]  Z. Guan,et al.  Efficient incorporation of polar comonomers in copolymerizations with ethylene using a cyclophane-based Pd(II) alpha-diimine catalyst. , 2007, Journal of the American Chemical Society.

[46]  J. Vela,et al.  Copolymerization of ethylene and alkyl vinyl ethers by a (phosphine- sulfonate)PdMe catalyst. , 2007, Journal of the American Chemical Society.

[47]  K. Nozaki,et al.  Formation of linear copolymers of ethylene and acrylonitrile catalyzed by phosphine sulfonate palladium complexes. , 2007, Journal of the American Chemical Society.

[48]  P. White,et al.  Reactions of vinyl acetate and vinyl trifluoroacetate with cationic diimine Pd(II) and Ni(II) alkyl complexes: identification of problems connected with copolymerizations of these monomers with ethylene. , 2005, Journal of the American Chemical Society.

[49]  R. van Ginkel,et al.  Palladium catalysed copolymerisation of ethene with alkylacrylates: polar comonomer built into the linear polymer chain. , 2002, Chemical communications.

[50]  S. Mecking.  Olefin Polymerization by Late Transition Metal Complexes-A Root of Ziegler Catalysts Gains New Ground. , 2001, Angewandte Chemie.

[51]  M. Watson,et al.  Functionalized polyethylene via acyclic diene metathesis polymerization: Effect of precise placement of functional groups , 2000 .

[52]  B. Novak,et al.  Copolymerization of polar monomers with olefins using transition-metal complexes. , 2000, Chemical reviews.

[53]  R. Balicki.  A Mild and Efficient Procedure for the Oxidation of Organic Sulfides to Sulfones by Use Of Urea-Hydrogen Peroxide/Trifluoroacetic Anhydride System , 1999 .

[54]  S. Mecking,et al.  Mechanistic Studies of the Palladium-Catalyzed Copolymerization of Ethylene and α-Olefins with Methyl Acrylate , 1998 .

[55]  S. Mecking,et al.  Copolymerization of Ethylene and Propylene with Functionalized Vinyl Monomers by Palladium(II) Catalysts , 1996 .

[56]  Maurice Brookhart,et al.  New Pd(II)- and Ni(II)-Based Catalysts for Polymerization of Ethylene and .alpha.-Olefins , 1995 .

[57]  K. Fujimori.  Cyclocopolymerization of Divinyl Sulfone with Vinyl Ethers , 1976 .

[58]  J. P. Schroeder,et al.  Notes anionic polymerization of methyl vinyl sulfone , 1972 .

[59]  Jin-Yong Dong,et al.  Design and synthesis of structurally well-defined functional polypropylenes via transition metal-mediated olefin polymerization chemistry , 2006 .