论文信息 - N‐Heterocyclic Carbene Catalyzed Switchable Reactions of Enals with Azoalkenes: Formal [4 + 3] and [4 + 1] Annulations for the Synthesis of 1,2‐Diazepines and Pyrazoles.

N‐Heterocyclic Carbene Catalyzed Switchable Reactions of Enals with Azoalkenes: Formal [4 + 3] and [4 + 1] Annulations for the Synthesis of 1,2‐Diazepines and Pyrazoles.

Various 1,2-diazepine derivatives are synthesized by regio- and enantioselective formal [4 + 3] annulation reaction between enals and in situ formed azoalkenes.

Constantin G. Daniliuc | Frank Glorius | Basudev Sahoo | Chang Guo

[1] Frank Glorius,et al. N-heterocyclic carbene catalyzed switchable reactions of enals with azoalkenes: formal [4 + 3] and [4 + 1] annulations for the synthesis of 1,2-diazepines and pyrazoles. , 2014, Journal of the American Chemical Society.