Modelling phase transition in metastable liquids: application to cavitating and flashing flows

A hyperbolic two-phase flow model involving five partial differential equations is constructed for liquid–gas interface modelling. The model is able to deal with interfaces of simple contact where normal velocity and pressure are continuous as well as transition fronts where heat and mass transfer occur, involving pressure and velocity jumps. These fronts correspond to extra waves in the system. The model involves two temperatures and entropies but a single pressure and a single velocity. The closure is achieved by two equations of state that reproduce the phase diagram when equilibrium is reached. Relaxation toward equilibrium is achieved by temperature and chemical potential relaxation terms whose kinetics is considered infinitely fast at specific locations only, typically at evaporation fronts. Thus, metastable states are involved for locations far from these fronts. Computational results are compared to the experimental ones. Computed and measured front speeds are of the same order of magnitude and the same tendency of increasing front speed with initial temperature is reported. Moreover, the limit case of evaporation fronts propagating in highly metastable liquids with the Chapman–Jouguet speed is recovered as an expansion wave of the present model in the limit of stiff thermal and chemical relaxation.

[1]  Ernst Schmidt Properties of water and steam in SI-units , 1969 .

[2]  R. Menikoff,et al.  The Riemann problem for fluid flow of real materials , 1989 .

[3]  Richard Saurel,et al.  A multiphase model for compressible flows with interfaces, shocks, detonation waves and cavitation , 2001, Journal of Fluid Mechanics.

[4]  Joseph E. Shepherd,et al.  Evaporation waves in superheated dodecane , 1999, Journal of Fluid Mechanics.

[5]  J. E. Hilliard,et al.  Free Energy of a Nonuniform System. I. Interfacial Free Energy , 1958 .

[6]  Hervé Guillard,et al.  A five equation reduced model for compressible two phase flow problems , 2005 .

[7]  Steven F. Son,et al.  Two-Phase Modeling of DDT in Granular Materials: Reduced Equations , 2000 .

[8]  Richard Saurel,et al.  A relaxation-projection method for compressible flows. Part I: The numerical equation of state for the Euler equations , 2007, J. Comput. Phys..

[9]  Brij Lal,et al.  A textbook of sound , 1995 .

[10]  Gerd E. A. Meier,et al.  Wave splitting in a fluid of large heat capacity , 1987, Journal of Fluid Mechanics.

[11]  J. Edwards,et al.  Ausm schemes and extensions for low mach and multiphase flows , 1999 .

[12]  M. Baer,et al.  A two-phase mixture theory for the deflagration-to-detonation transition (ddt) in reactive granular materials , 1986 .

[13]  R. Abgrall,et al.  A Multiphase Godunov Method for Compressible Multifluid and Multiphase Flows , 1999 .

[14]  D. Stewart,et al.  Two-phase modeling of deflagration-to-detonation transition in granular materials: Reduced equations , 2001 .

[15]  M. Ishii Thermo-fluid dynamic theory of two-phase flow , 1975 .

[16]  Richard Saurel,et al.  A relaxation-projection method for compressible flows. Part II: Artificial heat exchanges for multiphase shocks , 2007, J. Comput. Phys..

[17]  Joseph E. Shepherd,et al.  Adiabatic evaporation waves , 1994 .

[18]  Richard Saurel,et al.  A multiphase model with internal degrees of freedom: application to shock–bubble interaction , 2003, Journal of Fluid Mechanics.

[19]  O. Metayer,et al.  Élaboration des lois d'état d'un liquide et de sa vapeur pour les modèles d'écoulements diphasiques Elaborating equations of state of a liquid and its vapor for two-phase flow models , 2004 .

[20]  P. B. Butler,et al.  Shock Development and Transition to Detonation Initiated by Burning in Porous Propellant Beds , 1981 .

[21]  P. A. Thompson,et al.  Adiabatic Waves in Liquid-Vapor Systems , 1990 .

[22]  Gad Hetsroni,et al.  Handbook of multiphase systems , 1982 .

[23]  G. Yadigaroglu,et al.  Explosive vaporization of superheated liquids by boiling fronts , 2001 .

[24]  Richard Saurel,et al.  Modelling detonation waves in heterogeneous energetic materials , 2004 .

[25]  Rémi Abgrall,et al.  Discrete equations for physical and numerical compressible multiphase mixtures , 2003 .

[26]  L. Hill,et al.  An experimental study of evaporation waves in a superheated liquid , 1990 .

[27]  Siegfried Müller,et al.  The Riemann Problem for the Euler Equations with Nonconvex and Nonsmooth Equation of State: Construction of Wave Curves , 2006, SIAM J. Sci. Comput..

[28]  Michel Barret,et al.  Computation of Flashing Flows In Variable Cross-Section Ducts , 2000 .

[29]  P. B. Butler,et al.  Numerical Study of Cavitation in the Wake of a Hypervelocity Underwater Projectile , 1999 .

[30]  O. Lebaigue,et al.  The second gradient method for the direct numerical simulation of liquid—vapor flows with phase change , 2001 .

[31]  Richard Saurel,et al.  Modelling evaporation fronts with reactive Riemann solvers , 2005 .

[32]  G. Meier,et al.  Complete adiabatic evaporation of highly superheated liquid jets , 1992, Journal of Fluid Mechanics.

[33]  Richard Saurel,et al.  Shock jump relations for multiphase mixtures with stiff mechanical relaxation , 2007 .

[34]  Richard Saurel,et al.  A compressible flow model with capillary effects , 2005 .