Current instability phenomena in ZnO varistors under a continuous ac stress

A zinc oxide (ZnO) varistor subjected to a 60‐Hz voltage below the characteristic turn‐on voltage exhibits an increase in the resistive component of current with time. The rate of current increase with time can be increased with an increase in applied voltage and/or temperature. An analysis of current rise with an applied 60‐Hz voltage stress and current decay with no voltage stress data obtained for ZnO varistors indicates that the current instability phenomena is associated with the diffusion of interstitial zinc in the depletion layer regions adjacent to the ZnO‐ZnO grain boundary.

[1]  Current Creep in Nonohmic ZnO Ceramics , 1979 .

[2]  M. Matsuoka Nonohmic Properties of Zinc Oxide Ceramics , 1971 .

[3]  Atsushi Iga,et al.  Degradation mechanism of non-Ohmic zinc oxide ceramics , 1980 .

[4]  K. W. Böer,et al.  Self‐Activated Semiconductivity in CdS Single Crystals , 1963 .

[5]  R. Einzinger Metal oxide varistor action -a homojunction breakdown mechanism , 1978 .

[6]  E. L. Williams,et al.  II. Diffusion of zinc and oxygen in zinc oxide , 1959 .

[7]  S. Tominaga,et al.  Electrical Conduction of ZnO Varistors under Continuous DC Stress , 1980 .

[8]  J. D. Levine Theory of varistor electronic properties , 1975 .

[9]  W. Heywang,et al.  Resistivity Anomaly in Doped Barium Titanate , 1964 .

[10]  D. G. Thomas Interstitial zinc in zinc oxide , 1957 .

[11]  P. R. Emtage,et al.  The physics of zinc oxide varistors , 1977 .

[12]  T. Gupta,et al.  A barrier model for ZnO varistors , 1979 .

[13]  W. Morris Physical properties of the electrical barriers in varistors , 1976 .

[14]  H. R. Philipp,et al.  Theory of conduction in ZnO varistors , 1979 .

[15]  Kazuo Eda,et al.  Conduction mechanism of non‐Ohmic zinc oxide ceramics , 1978 .

[16]  R. Lindner,et al.  Die Diffusion von radioaktivem Zink in Zink-Eisen-Spinell und Zinkoxyd. , 1952 .

[17]  H. R. Philipp,et al.  The physics of metal oxide varistors , 1975 .

[18]  H. Goldsmid,et al.  DIffusion in Semiconductors , 1970 .

[19]  J. Bernasconi,et al.  Investigation of various models for metal oxide varistors , 1976 .