Opportunities and Challenges with Polyalkylene Glycol for Engine Oil Application

Base oil plays an important role in engine oil formulation in delivering overall performance attributes in addition to additives. Non-traditional base oil like polyalkylene glycol (PAG) did not get much attention in the past for formulating automotive engine oil. This investigation explored PAGs for enhancing engine oil performance primarily for fuel economy benefit over traditional mineral oil-based formulations. This paper highlights key findings from an extensive investigation, parts of which were published in detail elsewhere, and identifying opportunities and challenges. Several PAG chemistries were investigated depending on their feedstock material. Friction performance was evaluated by several methods starting with laboratory bench tests to engine components to chassis roll dynamometer tests. Durability was also evaluated from laboratory bench tests to engine components to ASTM sequence tests. The investigation revealed that significant friction reduction or fuel economy gain can be achieved with PAG oil but wear protection capability, piston deposit, and varnish require much improvement requiring identification/development of additive components. A few alternative routes for performance improvement are suggested.

[1]  A. Gangopadhyay,et al.  Friction and Wear Reduction Mechanism of Polyalkylene Glycol-Based Engine Oils , 2018 .

[2]  D. G. McWatt,et al.  Valvetrain Friction and Wear Performance of Polyalkylene Glycol Engine Oils , 2018 .

[3]  A. Gangopadhyay,et al.  Enhanced Anti-Wear Performance Induced by Innovative Base Oil in Low Viscosity Engine Oil , 2017 .

[4]  D. Sander,et al.  Friction Reduction Tested for a Downsized Diesel Engine with Low-Viscosity Lubricants Including a Novel Polyalkylene Glycol , 2017 .

[5]  A. Gangopadhyay,et al.  Friction Reduction in Lubricated Rough Contacts: Numerical and Experimental Studies , 2016 .

[6]  M. Greaves,et al.  Film forming behaviour of oil soluble polyalkylene glycols , 2015 .

[7]  M. Woydt,et al.  Stribeck-Type Curves of Alternative Engine Oils: Part I: Gray Cast Iron Liners , 2014 .

[8]  C·皮埃尔,et al.  Amine alkoxylates compositions and their use as lubricant additives , 2013 .

[9]  M. Woydt Polyalkylene Glycols as Next Generation Engine Oils , 2011 .

[10]  M. Masuko,et al.  Friction reducing effect of multiply adsorptive organic polymer , 2009 .

[11]  M. Woydt No/Low SAP and Alternative Engine Oil Development and Testing , 2007 .

[12]  Eric Fitamen,et al.  Validation of Oxidative Stability of Factory Fill and Alternative Engine Oils Using the Iron Catalyzed Oxidation Test , 2007 .

[13]  M. Kano,et al.  Ultralow friction of DLC in presence of glycerol mono-oleate (GNO) , 2005 .

[14]  A. Murase,et al.  TOF-SIMS study on the adsorption behavior of mixtures of a phosphite and a friction modifier onto ferrous material , 2003 .

[15]  H. Spikes,et al.  Friction-Enhancing Properties of ZDDP Antiwear Additive: Part I—Friction and Morphology of ZDDP Reaction Films , 2003 .

[16]  Kiyotaka Nakamura,et al.  Development of the Sequence IVA Valve Train Wear Lubricant Test: Part 1 , 2000 .

[17]  H. Spikes,et al.  Friction and Wear Behavior of Zinc Dialkyldithiophosphate Additive , 2000 .

[18]  T. E. Kiovsky,et al.  Fuel efficient lubricants and the effect of special base oils , 1994 .

[19]  Mineo Kagaya,et al.  High viscosity index petroleum base stocks: the high potential base stocks for fuel economy automotive lubricants , 1992 .

[20]  デビツド・ケンビン・ウオルターズ,et al.  Polyalkylene glycol lubricant composition , 1991 .

[21]  William Bate Hardy,et al.  Boundary Lubrication. The Paraffin Series , 1922 .