Electrical spin injection and detection in molybdenum disulfide multilayer channel

Molybdenum disulfide has recently emerged as a promising two-dimensional semiconducting material for nano-electronic, opto-electronic and spintronic applications. However, the demonstration of an electron spin transport through a semiconducting MoS2 channel remains challenging. Here we show the evidence of the electrical spin injection and detection in the conduction band of a multilayer MoS2 semiconducting channel using a two-terminal spin-valve configuration geometry. A magnetoresistance around 1% has been observed through a 450 nm long, 6 monolayer thick MoS2 channel with a Co/MgO tunnelling spin injector and detector. It is found that keeping a good balance between the interface resistance and channel resistance is mandatory for the observation of the two-terminal magnetoresistance. Moreover, the electron spin-relaxation is found to be greatly suppressed in the multilayer MoS2 channel with an in-plane spin polarization. The long spin diffusion length (approximately ∼235 nm) could open a new avenue for spintronic applications using multilayer transition metal dichalcogenides.

[1]  Albert Fert,et al.  Conditions for efficient spin injection from a ferromagnetic metal into a semiconductor , 2001 .

[2]  Wang Yao,et al.  Coupled spin and valley physics in monolayers of MoS2 and other group-VI dichalcogenides. , 2011, Physical review letters.

[3]  Zhi-Gang Yu,et al.  Variable range hopping and electrical conductivity along the DNA double helix. , 2001, Physical review letters.

[4]  Wang Yao,et al.  Valley polarization in MoS2 monolayers by optical pumping. , 2012, Nature nanotechnology.

[5]  M. Kamalakar,et al.  High-performance molybdenum disulfide field-effect transistors with spin tunnel contacts. , 2014, ACS nano.

[6]  Oriol López Sánchez,et al.  Valley Polarization by Spin Injection in a Light-Emitting van der Waals Heterojunction , 2016, Nano letters.

[7]  G. Schmidt,et al.  Fundamental obstacle for electrical spin injection from a ferromagnetic metal into a diffusive semiconductor , 1999, cond-mat/9911014.

[8]  Keliang He,et al.  Control of valley polarization in monolayer MoS2 by optical helicity. , 2012, Nature nanotechnology.

[9]  J. Shan,et al.  Atomically thin MoS₂: a new direct-gap semiconductor. , 2010, Physical review letters.

[10]  P. Tan,et al.  Robust optical emission polarization in MoS2 monolayers through selective valley excitation , 2012, 1206.5128.

[11]  Hongzheng Chen,et al.  Graphene-like two-dimensional materials. , 2013, Chemical reviews.

[12]  F. Miao,et al.  Hopping transport through defect-induced localized states in molybdenum disulphide , 2013, Nature Communications.

[13]  K. Ko'smider,et al.  Large spin splitting in the conduction band of transition metal dichalcogenide monolayers , 2013, 1311.0049.

[14]  Lain‐Jong Li,et al.  Synthesis of Large‐Area MoS2 Atomic Layers with Chemical Vapor Deposition , 2012, Advanced materials.

[15]  H. Wen,et al.  Control of Schottky barriers in single layer MoS2 transistors with ferromagnetic contacts. , 2013, Nano letters.

[16]  P. Kim,et al.  Electron transport in disordered graphene nanoribbons. , 2009, Physical review letters.

[17]  S. Ferrari,et al.  Author contributions , 2021 .

[18]  A. Radenović,et al.  Single-layer MoS2 transistors. , 2011, Nature nanotechnology.

[19]  G. Wang,et al.  Giant enhancement of the optical second-harmonic emission of WSe(2) monolayers by laser excitation at exciton resonances. , 2015, Physical review letters.

[20]  Jeff M. Byers,et al.  Spin Dynamics in Semiconductors , 2002 .

[21]  Mikhail I. Dyakonov Spin physics in semiconductors , 2008 .

[22]  P. Ajayan,et al.  Second harmonic microscopy of monolayer MoS 2 , 2013, 1302.3935.

[23]  Luyi Yang,et al.  Long-lived nanosecond spin relaxation and spin coherence of electrons in monolayer MoS2 and WS2 , 2015, Nature Physics.

[24]  A. Fert,et al.  Enhancement of the spin signal in permalloy/gold multiterminal nanodevices by lateral confinement , 2012 .

[25]  Weiwei Zhao,et al.  Layer-by-layer thinning of MoS2 by plasma. , 2013, ACS nano.

[26]  B. Radisavljevic,et al.  Mobility engineering and a metal-insulator transition in monolayer MoS₂. , 2013, Nature materials.

[27]  F. Xiu,et al.  Controllable Schottky Barriers between MoS2 and Permalloy , 2014, Scientific Reports.

[28]  D. Allwood,et al.  Magnetic domain wall propagation in nanowires under transverse magnetic fields , 2008 .

[29]  A. Fert,et al.  Spin transport in multiterminal devices: Large spin signals in devices with confined geometry , 2010 .

[30]  H. Jaffrès,et al.  Spin-polarized inelastic tunneling through insulating barriers. , 2009, Physical review letters.

[31]  J. Appenzeller,et al.  High performance multilayer MoS2 transistors with scandium contacts. , 2013, Nano letters.

[32]  R. Rold'an,et al.  Spin-orbit-mediated spin relaxation in monolayer MoS2 , 2013, 1303.5860.

[33]  A. Fert,et al.  Enhancement of the spin accumulation at the interface between a spin-polarized tunnel junction and a semiconductor. , 2008, Physical review letters.

[34]  D. Lacour,et al.  Electrical control of interfacial trapping for magnetic tunnel transistor on silicon , 2014 .

[35]  Xiang Zhang,et al.  Electrical generation and control of the valley carriers in a monolayer transition metal dichalcogenide. , 2016, Nature nanotechnology.

[36]  M. W. Wu,et al.  Electron spin relaxation due to D'yakonov-Perel' and Elliot-Yafet mechanisms in monolayer MoS 2 : Role of intravalley and intervalley processes , 2013, 1312.6985.

[37]  Kaustav Banerjee,et al.  Electrical contacts to two-dimensional semiconductors. , 2015, Nature materials.

[38]  Ji Feng,et al.  Valley-selective circular dichroism of monolayer molybdenum disulphide , 2012, Nature Communications.