Reactivity of surface species in heterogeneous catalysts probed by in situ X-ray absorption techniques.

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[1]  N. Binsted,et al.  A rapid, exact curved-wave theory for EXAFS calculations , 1984 .

[2]  W. L. Holstein,et al.  Impregnation of alumina with copper chloride-modeling of impregnation kinetics and internal copper profiles , 1983 .

[3]  M J Rosseinsky,et al.  Design, chirality, and flexibility in nanoporous molecule-based materials. , 2005, Accounts of chemical research.

[4]  K. Lillerud,et al.  FTIR adsorption studies of H2O and CH3OH in the isostructural H-SSZ-13 and H-SAPO-34: formation of H-bonded adducts and protonated clusters. , 2005, The journal of physical chemistry. B.

[5]  L. Mussmann,et al.  Characterization and catalytic investigation of Fe-ZSM5 for urea-SCR , 2007 .

[6]  Piero Ugliengo,et al.  Can Cu+-Exchanged Zeolites Store Molecular Hydrogen? An Ab-Initio Periodic Study Compared with Low-Temperature FTIR , 2004 .

[7]  T. Shiraiwa The Theory of the Fine Structure of the X-ray Absorption Spectrum, II. , 1958 .

[8]  J. Rehr,et al.  Comparison between X-ray Absorption Spectroscopy, Anomalous Wide Angle X-ray Scattering, Anomalous Small Angle X-ray Scattering, and Diffraction Anomalous Fine Structure Techniques Applied to Nanometer-Scale Metallic Clusters , 1997 .

[9]  S. Bordiga,et al.  Orthorhombic and monoclinic silicalites: structure, morphology, vibrational properties and crystal defects. , 1994 .

[10]  A. Kahn-Harari,et al.  Spectroscopic characterization of chromium (IV, V, VI) in Cr:Li2MSiO4 (M=Mg,Zn) , 2003 .

[11]  A. Longo,et al.  Distorted f.c.c. arrangement of gold nanoclusters: a model of spherical particles with microstrains and stacking faults , 2008 .

[12]  F. Ribeiro,et al.  Determination of CO, H2O and H2 coverage by XANES and EXAFS on Pt and Au during water gas shift reaction. , 2010, Physical chemistry chemical physics : PCCP.

[13]  R. Frahm New method for time dependent x-ray absorption studies , 1989 .

[14]  S. Bare,et al.  An in situ x-ray absorption spectroscopic cell for high temperature gas-flow measurements , 1998 .

[15]  J. Klinowski,et al.  EXAFS studies of iron-substituted zeolite ZSM-5 , 1992 .

[16]  Xinwen Guo,et al.  Enhanced Catalytic Oxidation by Hierarchically Structured TS-1 Zeolite , 2010 .

[17]  J. Rehr,et al.  Comment on "Operando DRIFTS and XANES Study of Deactivating Effect of CO2 on a Ce0.8Cu0.2O2 CO-PROX Catalyst" , 2011 .

[18]  T. Schmitt,et al.  Resonant inelastic x-ray scattering at the oxygen K resonance of NiO: nonlocal charge transfer and double-singlet excitations. , 2006, Physical review letters.

[19]  F. Cotton,et al.  After 155 Years, A Crystalline Chromium Carboxylate with a Supershort Cr−Cr Bond , 2000 .

[20]  C. Lamberti,et al.  Formation of Nonplanar CuI(CO)3Tricarbonyls on CuI–ZSM-5:An FTIR Study at 80 K , 1998 .

[21]  J. Grunwaldt,et al.  On the presence of Fe(IV) in Fe-ZSM-5 and FeSrO3-x --unequivocal detection of the 3d4 spin system by resonant inelastic X-ray scattering. , 2006, The journal of physical chemistry. B.

[22]  A. Dent,et al.  Tracing the conversion of aurichalcite to a copper catalyst by combined X-ray absorption and diffraction , 1991, Nature.

[23]  C. Lamberti,et al.  Effect of Selective Area Growth mask width on Multi-Quantum-Well Electroabsorption Modulated Lasers investigated by synchrotron radiation X-ray microprobe , 2012 .

[24]  R. Prins,et al.  Analysis of in situ EXAFS data of supported metal catalysts using the third and fourth cumulant. , 2006, Physical chemistry chemical physics : PCCP.

[25]  Dean R. Haeffner,et al.  Mapping the chemical states of an element inside a sample using tomographic x-ray absorption spectroscopy , 2003 .

[26]  A. Corma,et al.  Direct Synthesis and Characterization of Hydrophobic Aluminum-Free Ti−Beta Zeolite , 1998 .

[27]  Parr,et al.  Development of the Colle-Salvetti correlation-energy formula into a functional of the electron density. , 1988, Physical review. B, Condensed matter.

[28]  T. Tyliszczak,et al.  An in-situ cell for characterization of solids by soft X-ray absorption , 2004 .

[29]  Michael Stöcker,et al.  Methanol-to-hydrocarbons: catalytic materials and their behavior 1 Dedicated to my wife Wencke Ophau , 1999 .

[30]  A. MacDowell,et al.  0.1–10 keV soft X-ray beamline for surface EXAFS studies at the Daresbury SRS , 1986 .

[31]  P. Eisenberger,et al.  Extended x-ray absorption fine structure—its strengths and limitations as a structural tool , 1981 .

[32]  B. Weckhuysen,et al.  A quantitative diffuse reflectance spectroscopy study of supported chromium catalysts , 1993 .

[33]  Y. Joly Calculating X-ray absorption near-edge structure at very low energy. , 2003, Journal of synchrotron radiation.

[34]  C. H. Shaw,et al.  The Fine Structure of the X-Ray Absorption Limits of Bromine and Chlorine , 1940 .

[35]  J. Rehr,et al.  Ab initio curved-wave x-ray-absorption fine structure. , 1991, Physical review. B, Condensed matter.

[36]  M. Janousch,et al.  High energy resolution off-resonant spectroscopy at sub-second time resolution: (Pt(acac)2) decomposition. , 2012, Chemical communications.

[37]  N. Mizuno,et al.  Removal of nitrogen monoxide through a novel catalytic process. 2. Infrared study on surface reaction of nitrogen monoxide adsorbed on copper ion-exchanged ZSM-5 zeolites , 1992 .

[38]  S. Che,et al.  Palladium nanoparticles supported on MOF-5: A highly active catalyst for a ligand- and copper-free Sonogashira coupling reaction , 2010 .

[39]  A. Dent,et al.  Structural characterisation of solution species implicated in the palladium-catalysed Heck reaction by Pd K-edge X-ray absorption spectroscopy: palladium acetate as a catalyst precursor , 2002 .

[40]  B. Weckhuysen,et al.  Integrated laser and electron microscopy correlates structure of fluid catalytic cracking particles to Brønsted acidity. , 2012, Angewandte Chemie.

[41]  Elina Färm,et al.  Ultra-high resolution zone-doubled diffractive X-ray optics for the multi-keV regime. , 2011, Optics express.

[42]  A. Dent,et al.  Scanning and energy dispersive EXAFS studies of ethyl transmetallation in an alkene oligomerisation catalyst , 1996 .

[43]  L. Azároff THEORY OF EXTENDED FINE STRUCTURE OF X-RAY ABSORPTION EDGES , 1963 .

[44]  A. E. Palomares,et al.  On the researching of a new zeolite structure for the selective catalytic reduction of NO: The possibilities of Cu-exchanged IM5 , 2000 .

[45]  Tadashi Matsushita,et al.  A Fast X-Ray Absorption Spectrometer for Use with Synchrotron Radiation , 1981 .

[46]  J. Klinowski,et al.  Gallium EXAFS and solid-state NMR studies of Ga-substituted MFI-type zeolites , 1990 .

[47]  J. Rehr,et al.  Atomic-XAFS and XANES , 1995 .

[48]  S. Nguyen,et al.  Selective bifunctional modification of a non-catenated metal-organic framework material via "click" chemistry. , 2009, Journal of the American Chemical Society.

[49]  Chuan-De Wu,et al.  A homochiral porous metal-organic framework for highly enantioselective heterogeneous asymmetric catalysis. , 2005, Journal of the American Chemical Society.

[50]  M. Fröba,et al.  A new in situ cell for XAFS investigations. , 2004, Journal of synchrotron radiation.

[51]  C. Lamberti,et al.  Synchrotron study of oxygen depletion in a Bi-2212 whisker annealed at 363 K. , 2009, Journal of synchrotron radiation.

[52]  H. Dalton,et al.  A stopped-flow kinetic study of soluble methane mono-oxygenase from Methylococcus capsulatus (Bath). , 1989, The Biochemical journal.

[53]  Robert Schlögl,et al.  CO Formation/Selectivity for steam reforming of methanol with a commercial CuO/ZnO/Al2O3 catalyst , 2004 .

[54]  Sangeeta,et al.  First results from a dispersive EXAFS beamline developed at INDUS-2 synchrotron source at RRCAT, Indore, India , 2009 .

[55]  T. Kawai,et al.  Design of a high-temperature and high-pressure liquid flow cell for x-ray absorption fine structure measurements under catalytic reaction conditions. , 2008, The Review of scientific instruments.

[56]  O. Kröcher,et al.  The State of the Art in Selective Catalytic Reduction of NOx by Ammonia Using Metal‐Exchanged Zeolite Catalysts , 2008 .

[57]  A. Frenkel,et al.  Modeling the structure and composition of nanoparticles by extended X-ray absorption fine-structure spectroscopy. , 2011, Annual review of analytical chemistry.

[58]  M. Labrador,et al.  Sorption of Ni by "lithiophorite-asbolane" intermediates in Moa Bay lateritic deposits, eastern Cuba , 2010 .

[59]  M. Fleet,et al.  Surface modification study of borate materials from B K-edge X-ray absorption spectroscopy , 1998 .

[60]  M. Herskowitz,et al.  NO oxidation kinetics on iron zeolites: influence of framework type and iron speciation , 2004 .

[61]  B. Weckhuysen,et al.  REDOX BEHAVIOR AND DISPERSION OF SUPPORTED CHROMIUM CATALYSTS , 1995 .

[62]  J. Simpson,et al.  Origin of the Exceptional Negative Thermal Expansion in Metal-Organic Framework-5 Zn 4 O(1,4-benzenedicarboxylate) 3 , 2008 .

[63]  Craig M. Brown,et al.  Highly-selective and reversible O2 binding in Cr3(1,3,5-benzenetricarboxylate)2. , 2010, Journal of the American Chemical Society.

[64]  R. Nuzzo,et al.  The emergence of nonbulk properties in supported metal clusters: negative thermal expansion and atomic disorder in Pt nanoclusters supported on gamma-Al2O3. , 2009, Journal of the American Chemical Society.

[65]  F. Kapteijn,et al.  Amino-based metal-organic frameworks as stable, highly active basic catalysts , 2009 .

[66]  Xinwen Guo,et al.  Highly efficient epoxidation of propylene to propylene oxide over TS-1 using urea + hydrogen peroxide as oxidizing agent , 2008 .

[67]  J. Lercher,et al.  Metal organic frameworks based on Cu2+ and benzene-1,3,5-tricarboxylate as host for SO2 trapping agents , 2005 .

[68]  J. Garćıa,et al.  XANES in condensed systems , 1988 .

[69]  P. L. Hansen,et al.  A combined QEXAFS/XRD method for on-line, in situ studies of catalysts: Examples of dynamic measurements of Cu-based methanol catalysts , 1993 .

[70]  C. Roth,et al.  Ethanol Oxidation on Carbon-Supported Pt, PtRu, and PtSn Catalysts Studied by Operando X-ray Absorption Spectroscopy , 2010 .

[71]  R. P. Townsend,et al.  A new cell for the collection of combined EXAFS/XRD data in situ during solid/liquid catalytic reactions , 1997 .

[72]  B. Gates,et al.  Hexairidium Clusters Supported on γ-Al2O3: Synthesis, Structure, and Catalytic Activity for Toluene Hydrogenation , 1996 .

[73]  J. Tranquada,et al.  Extended x-ray—absorption fine-structure study of anharmonicity in CuBr , 1983 .

[74]  Qing Min Wang,et al.  Nanopore Structure and Sorption Properties of Cu-BTC Metal-Organic Framework , 2003 .

[75]  Akio Kotani,et al.  Resonant inelastic x-ray scattering spectra for electrons in solids , 2001 .

[76]  D. Koningsberger,et al.  Reactivity of Fe-binuclear complexes in over-exchanged Fe/ZSM5, studied by in situ XAFS spectroscopy - part 1: Heat treatment in He and O2. , 2003 .

[77]  M. Allendorf,et al.  Force Field Validation for Molecular Dynamics Simulations of IRMOF-1 and Other Isoreticular Zinc Carboxylate Coordination Polymers , 2008 .

[78]  J. Grunwaldt,et al.  Axial variation of the oxidation state of Pt-Rh/Al2O3 during partial methane oxidation in a fixed-bed reactor: An in situ X-ray absorption spectroscopy study , 2005 .

[79]  Ankudinov,et al.  Multiple-scattering calculations of x-ray-absorption spectra. , 1995, Physical review. B, Condensed matter.

[80]  E. Kondratenko,et al.  Mechanism and kinetics of direct N2O decomposition over Fe-MFI zeolites with different iron speciation from temporal analysis of products. , 2006, The journal of physical chemistry. B.

[81]  A. Witkowska,et al.  An XAS experimental approach to study low Pt content electrocatalysts operating in PEM fuel cells. , 2009, Physical chemistry chemical physics : PCCP.

[82]  K. Lillerud,et al.  Electronic and vibrational properties of a MOF-5 metal-organic framework: ZnO quantum dot behaviour. , 2004, Chemical communications.

[83]  A. Frenkel,et al.  Carbon-Supported IrNi Core–Shell Nanoparticles: Synthesis, Characterization, and Catalytic Activity , 2011 .

[84]  Gabor A. Somorjai,et al.  Advancing the frontiers in nanocatalysis, biointerfaces, and renewable energy conversion by innovations of surface techniques. , 2009, Journal of the American Chemical Society.

[85]  F. H. Constable The mechanism of catalytic decomposition , 1925 .

[86]  C. Catlow,et al.  STRUCTURE OF IRON-SUBSTITUTED ZSM-5 , 1995 .

[87]  Sakura Pascarelli,et al.  Turbo-XAS: dispersive XAS using sequential acquisition , 1999 .

[88]  F. Neese,et al.  Preference towards five-coordination in Ti silicalite-1 upon molecular adsorption. , 2013, Chemphyschem : a European journal of chemical physics and physical chemistry.

[89]  Frank M. F. de Groot,et al.  Multiplet effects in X-ray spectroscopy , 2005 .

[90]  R. Lobo,et al.  Identifying reaction intermediates and catalytic active sites through in situ characterization techniques. , 2010, Chemical Society reviews.

[91]  W. Hall,et al.  Stoichiometric catalytic decomposition of nitric oxide over copper-exchanged zeolite (CuZSM-5) catalysts , 1990 .

[92]  A. Dent,et al.  Application of stopped flow techniques and energy dispersive EXAFS for investigation of the reactions of transition metal complexes in solution: activation of nickel beta-diketonates to form homogeneous catalysts, electron transfer reactions involving iron(III) and oxidative addition to iridium(I). , 2003, Faraday discussions.

[93]  F. D. Groot Site-selective XAFS: a new tool for catalysis research , 2000 .

[94]  Brent M. T. Lok,et al.  Silicoaluminophosphate molecular sieves: another new class of microporous crystalline inorganic solids , 1984 .

[95]  C. Lamberti,et al.  Role of the Support in Determining the Vibrational Properties of Carbonyls Formed on Pd Supported on SiO2-Al2O3, Al2O3, and MgO , 2007 .

[96]  M. Casaletto,et al.  Metal-support and preparation influence on the structural and electronic properties of gold catalysts , 2006 .

[97]  C. Lamberti,et al.  Chromocene in porous polystyrene: an example of organometallic chemistry in confined spaces. , 2009, Physical chemistry chemical physics : PCCP.

[98]  M. Couprie,et al.  X radiation sources based on accelerators , 2008 .

[99]  F. d’Acapito,et al.  Local structure of [Cu(I)(CO)2]+ adducts hosted inside ZSM-5 zeolite probed by EXAFS, XANES and IR spectroscopies. , 2005, Physical chemistry chemical physics : PCCP.

[100]  G. Pantaleo,et al.  Metal-support interaction and redox behavior of Pt(1 wt %)/Ce0.6Zr0.4O2. , 2006, The journal of physical chemistry. B.

[101]  C. Catlow,et al.  A new furnace design for use in combined X-ray absorption and diffraction of catalysis and ceramics studies: formation from carbonate precursors of Cu, Co, Mn spinels for the oxidation of CO and the formation of PLZT, a piezoelectric ceramic , 1995 .

[102]  Alexey A. Sokol,et al.  QM/MM modelling of the TS-1 catalyst using HPCx , 2006 .

[103]  K. Lillerud,et al.  Ti-STT: a new zeotype shape selective oxidation catalyst. , 2011, Chemical Communications.

[104]  D. Ramaker,et al.  Nature of the metal-support interaction in supported Pt catalysts : Shift in Pt valence orbital energy and charge rearrangement , 2001 .

[105]  J. Barker,et al.  What is "liquid"? Understanding the states of matter , 1976 .

[106]  S. Kitagawa,et al.  Three‐Dimensional Framework with Channeling Cavities for Small Molecules: {[M2(4, 4′‐bpy)3(NO3)4]·xH2O}n (M Co, Ni, Zn) , 1997 .

[107]  W. Hall,et al.  FeZSM-5: A Durable SCR Catalyst for NOxRemoval from Combustion Streams , 1997 .

[108]  C. Christensen,et al.  Hierarchical zeolites: enhanced utilisation of microporous crystals in catalysis by advances in materials design. , 2008, Chemical Society reviews.

[109]  S. Weigel,et al.  The synthesis of molecular sieves from non-aqueous solvents , 1997 .

[110]  N. Brookes,et al.  Low energy electronic excitations in the layered cuprates studied by copper L3 resonant inelastic x-ray scattering. , 2004, Physical review letters.

[111]  J. Rehr,et al.  Parallel calculation of electron multiple scattering using Lanczos algorithms , 2002 .

[112]  C. Rovira,et al.  Coexistence of ferro- and antiferromagnetic interactions in a metal-organic radical-based (6,3)-helical network with large channels. , 2005, Chemical communications.

[113]  S. Mukerjee,et al.  Site-Specific vs Specific Adsorption of Anions on Pt and Pt-Based Alloys , 2007 .

[114]  C. Lamberti,et al.  Structural Characterization of Ti-Silicalite-1: A Synchrotron Radiation X-Ray Powder Diffraction Study , 1999 .

[115]  C. Lamberti,et al.  Determination of the Particle Size, Available Surface Area, and Nature of Exposed Sites for Silica-Alumina-Supported Pd Nanoparticles: A Multitechnical Approach , 2009 .

[116]  K. Chapman,et al.  Chasing changing nanoparticles with time-resolved pair distribution function methods. , 2012, Journal of the American Chemical Society.

[117]  Weiguo Song,et al.  The mechanism of methanol to hydrocarbon catalysis. , 2003, Accounts of chemical research.

[118]  M. Shelef Selective Catalytic Reduction of NOx with N-Free Reductants , 1995 .

[119]  Heon-Jin Choi,et al.  Magnetic and Electrical Properties of Single-Crystalline Mn-Doped Ge Nanowires , 2009 .

[120]  H. Fjellvåg,et al.  Structural changes and coordinatively unsaturated metal atoms on dehydration of honeycomb analogous microporous metal-organic frameworks. , 2008, Chemistry.

[121]  Atsushi Itadani,et al.  New insight into N2 adsorption and ion-exchange features of CuMFI with different Si/Al ratios , 2007 .

[122]  K. Wieghardt,et al.  Synthesis and Characterization of Mononuclear Octahedral Titanium(IV) Complexes Containing Ti:O, Ti(O2), and Ti(OCH3)x (x = 1-3) Structural Units , 1994 .

[123]  J. V. van Bokhoven,et al.  Three-coordinate aluminum in zeolites observed with in situ x-ray absorption near-edge spectroscopy at the Al K-edge: flexibility of aluminum coordinations in zeolites. , 2003, Journal of the American Chemical Society.

[124]  T. Yashima,et al.  Hydroxylation of Aromatics with Hydrogen Peroxide over Titanosilicates with MOR and MFI Structures: Effect of Ti Peroxo Species on the Diffusion and Hydroxylation Activity , 1998 .

[125]  A. Marcelli,et al.  Dispersive EXAFS apparatus at Frascati , 1992 .

[126]  G. Dalba,et al.  EXAFS Debye-Waller factor and thermal vibrations of crystals. , 1997, Journal of synchrotron radiation.

[127]  L. Randaccio,et al.  Cation‐site location in a natural chabazite , 1982 .

[128]  F. Lytle,et al.  Analysis of EXAFS data on bimetallic clusters , 1990 .

[129]  A. Soldatov,et al.  FitIt: New software to extract structural information on the basis of XANES fitting , 2007 .

[130]  R. Kumar,et al.  Ferrisilicate Analogs of Zeolites , 1991 .

[131]  F. Lytle,et al.  Structure of bimetallic clusters. Extended x‐ray absorption fine structure (EXAFS) studies of Pt–Ir clusters , 1982 .

[132]  C. Louis,et al.  Activation of oxygen on gold/alumina catalysts: in situ high-energy-resolution fluorescence and time-resolved X-ray spectroscopy. , 2006, Angewandte Chemie.

[133]  P. Jacobs,et al.  Factors influencing the catalytic activity of titanium silicalites in selective oxidations , 1991 .

[134]  T. Paradellis,et al.  Resonance strength measurements of the 27Al(p,γ)28Si reaction in the energy range Ep= 0.8–2.0 MeV , 1999 .

[135]  Jens K. Nørskov,et al.  A New Procedure for Particle Size Determination by EXAFS Based on Molecular Dynamics Simulations , 1993 .

[136]  M. Fanciulli,et al.  Coordination of boron and phosphorous in Borophosphosilicate glasses , 2003 .

[137]  E. Stern,et al.  Number of relevant independent points in x-ray-absorption fine-structure spectra. , 1993, Physical review. B, Condensed matter.

[138]  A. Kahn-Harari,et al.  XAS study of chromium in Li2MSiO4 (M=Mg, Zn) , 2003 .

[139]  J. Hanson,et al.  Rapid acquisition pair distribution function (RA-PDF) analysis. , 2003, cond-mat/0304638.

[140]  Jens R. Rostrup-Nielsen,et al.  Atom-Resolved Imaging of Dynamic Shape Changes in Supported Copper Nanocrystals , 2002, Science.

[141]  M. Salvalaggio,et al.  An ESR study of titanium-silicalite in presence of H2O2. , 2002, Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy.

[142]  L. Broadbelt,et al.  Elucidating steric effects on enantioselective epoxidation catalyzed by (salen)Mn in metal-organic frameworks , 2011 .

[143]  Natoli,et al.  X-ray-absorption spectroscopy and n-body distribution functions in condensed matter. I. Theory. , 1995, Physical review. B, Condensed matter.

[144]  G. Tabacchi,et al.  TS-1 from first principles. , 2009, The journal of physical chemistry. A.

[145]  T. Tatsumi,et al.  A novel titanosilicate with MWW structure: III. Highly efficient and selective production of glycidol through epoxidation of allyl alcohol with H2O2 , 2003 .

[146]  J. Grunwaldt,et al.  Continuous catalytic oxidation of solid alcohols in supercritical CO2: A parametric and spectroscopic study of the transformation of cinnamyl alcohol over Pd/Al2O3 , 2006 .

[147]  S. Bhargava,et al.  Adsorption of NO on Cu exchanged zeolites, an FTIR study: Effects of Cu levels, NO pressure, and catalyst pretreatment , 1996 .

[148]  A. Becke Density-functional thermochemistry. III. The role of exact exchange , 1993 .

[149]  D. Ramaker,et al.  Contribution of shape resonance and Pt–H EXAFS in the Pt L2,3 X-ray absorption edges of supported Pt particles: Application and consequences for catalyst characterization , 1999 .

[150]  D. Keen A comparison of various commonly used correlation functions for describing total scattering , 2001 .

[151]  M. Bauer,et al.  EXAFS as Powerful Analytical Tool for the Investigation of Organic–Inorganic Hybrid Materials , 2010 .

[152]  S. Stoupin Influence of Adsorbate-Free Atoms on Δ-XANES Signatures. , 2009, Journal of chemical theory and computation.

[153]  P. Lee,et al.  Ab initio calculations of amplitude and phase functions for extended x-ray absorption fine structure spectroscopy , 1979 .

[154]  T Mairs,et al.  Energy-dispersive absorption spectroscopy for hard-X-ray micro-XAS applications. , 2006, Journal of Synchrotron Radiation.

[155]  A. Frenkel,et al.  Anomalous lattice dynamics and thermal properties of supported size- and shape-selected Pt nanoparticles , 2010 .

[156]  L. G. Parratt ELECTRONIC BAND STRUCTURE OF SOLIDS BY X-RAY SPECTROSCOPY , 1959 .

[157]  A. Dent,et al.  Structure-performance relationships of Rh and RhPd alloy supported catalysts using combined EDE/DRIFTS/MS. , 2008, Faraday discussions.

[158]  Bo Wang,et al.  Highly efficient separation of carbon dioxide by a metal-organic framework replete with open metal sites , 2009, Proceedings of the National Academy of Sciences.

[159]  A. Frenkel,et al.  Combined in situ X-ray absorption and diffuse reflectance infrared spectroscopy: An attractive tool for catalytic investigations , 2011 .

[160]  D. Nachtigallová,et al.  Calculations of Site-Specific CO Stretching Frequencies for Copper Carbonyls with the ``Near Spectroscopic Accuracy'': CO Interaction with Cu+/MFI , 2003 .

[161]  P. M. Len,et al.  Multiple energy x-ray holography: Incident-radiation polarization effects , 1997 .

[162]  G. Pirngruber,et al.  An in situ X-ray absorption spectroscopy study of N2O decomposition over Fe-ZSM-5 prepared by chemical vapor deposition of FeCl3 , 2004 .

[163]  J. Rehr,et al.  Practical aspects of electron energy-loss spectroscopy (EELS) calculations using FEFF8. , 2007, Micron.

[164]  A. Zecchina,et al.  Spectroscopic Characterization of Silicalite and Titanium-Silicalite , 1989 .

[165]  B. Weckhuysen,et al.  Nonuniform catalytic behavior of zeolite crystals as revealed by in situ optical microspectroscopy. , 2007, Angewandte Chemie.

[166]  D. Dingwell,et al.  Effect of aluminum on Ti-coordination in silicate glasses: A XANES study , 2000 .

[167]  John J. Rehr,et al.  Limits and Advantages of X-ray Absorption Near Edge Structure for Nanometer Scale Metallic Clusters , 2003 .

[168]  G. Spoto,et al.  Silicalite characterization. 1. Structure, adsorptive capacity, and IR spectroscopy of the framework and hydroxyl modes , 1992 .

[169]  S. Oyama,et al.  Effect of composition and promoters in Au/TS-1 catalysts for direct propylene epoxidation using H2 and O2 , 2009 .

[170]  P. Panagiotopoulou,et al.  Effect of the nature of the support on the catalytic performance of noble metal catalysts for the water–gas shift reaction , 2006 .

[171]  F. Vizza,et al.  Hydrogenation of arenes over silica-supported catalysts that combine a grafted rhodium complex and palladium nanoparticles: evidence for substrate activation on Rh(single-site)-Pd(metal) moieties. , 2006, Journal of the American Chemical Society.

[172]  D. Lützenkirchen-Hecht,et al.  Piezo-QEXAFS: advances in time-resolved X-ray absorption spectroscopy. , 2001, Journal of synchrotron radiation.

[173]  V. Petkov,et al.  Element-specific structure of materials with intrinsic disorder by high-energy resonant x-ray diffraction and differential atomic pair-distribution functions: A study of PtPd nanosized catalysts , 2010 .

[174]  Armin Feldhoff,et al.  Molecular sieve membrane: supported metal-organic framework with high hydrogen selectivity. , 2010, Angewandte Chemie.

[175]  M. I. Bell,et al.  INCLUSION OF LOCAL STRUCTURE EFFECTS IN THEORETICAL X-RAY RESONANT SCATTERING AMPLITUDES USING AB INITIO X-RAY-ABSORPTION SPECTRA CALCULATIONS , 1998 .

[176]  A. Beale,et al.  Isolated Cu2+ ions: active sites for selective catalytic reduction of NO. , 2011, Chemical communications.

[177]  P. Colavita,et al.  Characterisation of heterogeneous catalysts by EXAFS , 1998 .

[178]  R. Schoonheydt UV-VIS-NIR spectroscopy and microscopy of heterogeneous catalysts. , 2010, Chemical Society reviews.

[179]  Ping Liu,et al.  Ternary Pt/Rh/SnO2 electrocatalysts for oxidizing ethanol to CO2. , 2009, Nature materials.

[180]  F. d’Acapito,et al.  CuI-Y and CuII-Y zeolites: a XANES, EXAFS and visible-NIR study , 1997 .

[181]  M. Benfatto,et al.  Geometrical fitting of experimental XANES spectra by a full multiple-scattering procedure. , 2001, Journal of synchrotron radiation.

[182]  Peter Claus,et al.  Identification of active sites in gold-catalyzed hydrogenation of acrolein. , 2003, Journal of the American Chemical Society.

[183]  T. Root,et al.  DFT Study of Solvent Coordination Effects on Titanium-Based Epoxidation Catalysts. Part Two: Reactivity of Titanium Hydroperoxo Complexes in Ethylene Epoxidation , 2003 .

[184]  P. Jacobs,et al.  Selective oxidation of methane by the bis(mu-oxo)dicopper core stabilized on ZSM-5 and mordenite zeolites. , 2005, Journal of the American Chemical Society.

[185]  C. Lamberti,et al.  Comparative IR-spectroscopic study of low-temperature H2 and CO adsorption on Na zeolites , 1994 .

[186]  M. Fernández-García,et al.  Redox behaviour of Pd-based TWCs under dynamic conditions: analysis using dispersive XAS and mass spectrometry. , 2005, Chemical communications.

[187]  K. Lillerud,et al.  Structural determination of a highly stable metal-organic framework with possible application to interim radioactive waste scavenging: Hf-UiO-66 , 2012 .

[188]  X-ray-absorption fine structure in embedded atoms. , 1994, Physical review. B, Condensed matter.

[189]  B. Weckhuysen,et al.  Bis(mu-oxo)dicopper as key intermediate in the catalytic decomposition of nitric oxide. , 2003, Chemphyschem : a European journal of chemical physics and physical chemistry.

[190]  B. Weckhuysen,et al.  Intergrowth structure of zeolite crystals and pore orientation of individual subunits revealed by electron backscatter diffraction/focused ion beam experiments. , 2008, Angewandte Chemie.

[191]  M. Fernández-García,et al.  Operando DRIFTS and XANES Study of Deactivating Effect of CO2 on a Ce0.8Cu0.2O2 CO-PROX Catalyst , 2010 .

[192]  J. Ross,et al.  Mechanistic aspects of the steam reforming of methanol over a CuO/ZnO/ZrO2/Al2O3 catalyst , 1999 .

[193]  M. Anpo,et al.  Characterization of the Local Structure of the Vanadium Silicalite (VS-2) Catalyst and Its Photocatalytic Reactivity for the Decomposition of NO into N2 and O2 , 1999 .

[194]  C. Grey,et al.  Watching nanoparticles grow: the mechanism and kinetics for the formation of TiO2-supported platinum nanoparticles. , 2007, Journal of the American Chemical Society.

[195]  L. Guczi,et al.  Soft X-ray absorption spectroscopy in heterogeneous catalysis , 2001 .

[196]  S. E. Malykhin,et al.  Catalytic Role of O•– Radicals in the Low-Temperature Isotopic Exchange in Dioxygen , 2011 .

[197]  G. Natta Stereospezifische Katalysen und isotaktische Polymere , 1956 .

[198]  G. Spoto,et al.  Well defined CuI(NO), CuI(NO)2 and CuII(NO)X (X = O− and/or NO2−) complexes in CuI-ZSMS prepared by interaction of H-ZSM5 with gaseous CuCl , 1992 .

[199]  D. Ramaker,et al.  The atomic AXAFS and Delta(mu) XANES techniques as applied to heterogeneous catalysis and electrocatalysis. , 2010, Physical chemistry chemical physics : PCCP.

[200]  Lamberti,et al.  Neutron powder diffraction study of orthorhombic and monoclinic defective silicalite , 2000, Acta crystallographica. Section B, Structural science.

[201]  C. Lamberti,et al.  Hydroxyls nests in defective silicalites and strained structures derived upon dehydroxylation: vibrational properties and theoretical modelling , 2001 .

[202]  C. Arean,et al.  Low temperature CO adsorption on Na-ZSM-5 zeolites: An FTIR investigation , 1992 .

[203]  Bert M. Weckhuysen,et al.  Determining the active site in a catalytic process: Operando spectroscopy is more than a buzzword , 2003 .

[204]  Kenji Sumida,et al.  Carbon dioxide capture in metal-organic frameworks. , 2012, Chemical reviews.

[205]  Hodgson,et al.  General multiple-scattering scheme for the computation and interpretation of x-ray-absorption fine structure in atomic clusters with applications to SF6, GeCl4, and Br2 molecules. , 1992, Physical review. B, Condensed matter.

[206]  A. Bell,et al.  The local environment of Cu+ in Cu-Y zeolite and its relationship to the synthesis of dimethyl carbonate. , 2006, The journal of physical chemistry. B.

[207]  J. Sinfelt,et al.  X-ray absorption edge studies of the electronic structure of metal catalysts , 1993 .

[208]  Nicolae Barsan,et al.  The structure and behavior of platinum in SnO2-based sensors under working conditions. , 2011, Angewandte Chemie.

[209]  C. Riekel,et al.  Structural study of poly(L-lactic acid) spherulites. , 2004, Biomacromolecules.

[210]  H. Fjellvåg,et al.  An in situ high-temperature single-crystal investigation of a dehydrated metal-organic framework compound and field-induced magnetization of one-dimensional metal-oxygen chains. , 2005, Angewandte Chemie.

[211]  A. Dent,et al.  Identification of the surface species responsible for N2O formation from the chemisorption of NO on Rh/alumina. , 2007, Physical chemistry chemical physics : PCCP.

[212]  C. Lamberti,et al.  Adsorption properties of HKUST-1 toward hydrogen and other small molecules monitored by IR. , 2007, Physical chemistry chemical physics : PCCP.

[213]  R. Frahm QEXAFS: X-ray absorption studies seconds , 1989 .

[214]  Seth M. Cohen,et al.  Systematic functionalization of a metal-organic framework via a postsynthetic modification approach. , 2008, Journal of the American Chemical Society.

[215]  Christian Bressler,et al.  Ultrafast nonadiabatic dynamics of [Fe(II)(bpy)(3)](2+) in solution. , 2007, Journal of the American Chemical Society.

[216]  F. D. de Groot,et al.  The CTM4XAS program for EELS and XAS spectral shape analysis of transition metal L edges. , 2010, Micron.

[217]  Stern,et al.  Comparison of theoretical methods for the calculation of extended x-ray-absorption fine structure. , 1994, Physical review. B, Condensed matter.

[218]  H. Padmore,et al.  A ReflEXAFS apparatus for use with soft X-rays in the sub-4-keV energy range , 1995 .

[219]  De Chen,et al.  The effect of crystal size of SAPO-34 on the selectivity and deactivation of the MTO reaction , 1999 .

[220]  F. Mauri,et al.  XANES calculation with an efficient “non muffin-tin” method: application to the angular dependence of the Al K-edge in corundum , 2005 .

[221]  J. Pérez-Pariente,et al.  Characterization of Ga-substituted zeolite Beta by X-ray absorption spectroscopy , 2000 .

[222]  B. Weckhuysen,et al.  Surface Chemistry and Spectroscopy of Chromium in Inorganic Oxides. , 1996, Chemical reviews.

[223]  L. Bonneviot,et al.  Characterization of two different framework titanium sites and quantification of extra-framework species in TS-1 silicalites , 1997 .

[224]  H. Topsøe,et al.  Developments in operando studies and in situ characterization of heterogeneous catalysts , 2003 .

[225]  Angelika Brückner,et al.  Looking on Heterogeneous Catalytic Systems from Different Perspectives: Multitechnique Approaches as a New Challenge for In Situ Studies , 2003 .

[226]  Z. Sobalík,et al.  Redox catalysis over metallo-zeolites Contribution to environmental catalysis , 2003 .

[227]  A. Dent,et al.  Bringing time resolution to EXAFS: recent developments and application to chemical systems. , 2002, Chemical Society reviews.

[228]  P. Glatzel,et al.  Investigation of the valence electronic states of Ti(IV) in Ti silicalite-1 coupling X-ray emission spectroscopy and density functional calculations. , 2011, Physical chemistry chemical physics : PCCP.

[229]  C. Lamberti,et al.  Alumina-Supported Copper Chloride: 1. Characterization of Freshly Prepared Catalyst , 2000 .

[230]  Gérard Férey,et al.  Porous metal-organic-framework nanoscale carriers as a potential platform for drug delivery and imaging. , 2010, Nature materials.

[231]  M. Anpo,et al.  Preparation and characterization of unique inorganic-organic hybrid mesoporous materials incorporating arenetricarbonyl complexes [-C6H4M(CO)3-] (M = Cr, Mo). , 2005, Journal of the American Chemical Society.

[232]  F. d’Acapito,et al.  X-ray photoelectron spectroscopy and x-ray absorption near edge structure study of copper sites hosted at the internal surface of ZSM-5 zeolite: A comparison with quantitative and energetic data on the CO and NH3 adsorption , 2000 .

[233]  W. Gates Chapter 12.3 X-ray Absorption Spectroscopy , 2006 .

[234]  W. Grünert,et al.  Selective catalytic reduction of NO by ammonia over Fe-ZSM-5 catalysts , 1999 .

[235]  W. Hall,et al.  Studies of the changes occurring on reduction and reoxidation of CuY zeolites , 1992 .

[236]  A Stein,et al.  Using compound kinoform hard-x-ray lenses to exceed the critical angle limit. , 2007, Physical review letters.

[237]  A. Nigam RESEARCH NOTES: The Origin of Fine Structures in X-Ray Absorption Spectra of Ionic Solutions , 1955 .

[238]  Yanfeng Yue,et al.  Luminescent functional metal-organic frameworks. , 2012, Chemical Reviews.

[239]  Multi-Technique In Situ Approach Towards the Study of Catalytic Solids at Work Using Synchrotron Radiation , 2009 .

[240]  Omar M Yaghi,et al.  The pervasive chemistry of metal-organic frameworks. , 2009, Chemical Society reviews.

[241]  James E Marsch,et al.  Diffraction anomalous fine structure: a new technique for probing local atomic environment , 1993 .

[242]  F. Lytle,et al.  Developments in Extended X-Ray Absorption Fine Structure Applied to Chemical Systems , 1979 .

[243]  F. Kapteijn,et al.  Visualizing the crystal structure and locating the catalytic activity of micro- and mesoporous ZSM-5 zeolite crystals by using in situ optical and fluorescence microscopy. , 2008, Chemistry.

[244]  Gang Yang,et al.  In situ magnetic resonance investigation of styrene oxidation over TS-1 zeolites. , 2004, Angewandte Chemie.

[245]  D. Koningsberger,et al.  EXAFS analysis of an Ir/γ-Al2O3 catalyst at elevated temperatures: evidence for a Gaussian pair distribution function , 2003 .

[246]  B. Weckhuysen,et al.  Operando surface spectroscopy--placing catalytic solids at work under the spotlight. , 2012, Physical chemistry chemical physics : PCCP.

[247]  L. Kiwi-Minsker,et al.  Monodispersed Pd Nanoparticles for Acetylene Selective Hydrogenation: Particle Size and Support Effects , 2008 .

[248]  J. Grunwaldt,et al.  Gold supported on Cu–Mg–Al and Cu–Ce mixed oxides: An in situ XANES study on the state of Au during aerobic alcohol oxidation , 2007 .

[249]  A. Beale,et al.  Confirmation of Isolated Cu2+ Ions in SSZ-13 Zeolite as Active Sites in NH3-Selective Catalytic Reduction , 2012 .

[250]  J. Liu Advanced Electron Microscopy of Metal–Support Interactions in Supported Metal Catalysts , 2011 .

[251]  G. Ouvrard,et al.  Ti and O K edges for titanium oxides by multiple scattering calculations: Comparison to XAS and EELS spectra , 1997 .

[252]  C. Lamberti,et al.  Doped-CuCl2/Al2O3 catalysts for ethylene oxychlorination: Influence of additives on the nature of active phase and reducibility , 2012 .

[253]  C. Lamberti,et al.  Alumina-Supported Copper Chloride 2. Effect of Aging and Thermal Treatments , 2000 .

[254]  P. Frank Medium-dependence of vanadium K-edge X-ray absorption spectra with application to blood cells from phlebobranch tunicates , 2003 .

[255]  G. van Koten,et al.  AXAFS as a probe of charge redistribution within organometallic complexes. , 2004, Journal of the American Chemical Society.

[256]  P. Gambardella,et al.  Magnetism of individual atoms adsorbed on surfaces , 2009 .

[257]  László Hegedu˝s,et al.  Hydrogenation of pyrrole derivatives I. Hydrogenations over palladium , 1996 .

[258]  R. T. Yang,et al.  Significantly enhanced hydrogen storage in metal-organic frameworks via spillover. , 2006, Journal of the American Chemical Society.

[259]  E. D. Crozier,et al.  A review of the current status of XAFS spectroscopy , 1997 .

[260]  J. Nagy,et al.  Isomorphously substituted Fe-ZSM-5 zeolites as catalysts , 2003 .

[261]  J. Gardea-Torresdey,et al.  ENVIRONMENTAL AND BIOLOGICAL APPLICATIONS OF EXTENDED X-RAY ABSORPTION FINE STRUCTURE (EXAFS) AND X-RAY ABSORPTION NEAR EDGE STRUCTURE (XANES) SPECTROSCOPIES , 2002 .

[262]  A. Frenkel,et al.  In situ diffuse reflectance IR spectroscopy and X-ray absorption spectroscopy for fast catalytic processes. , 2011, Journal of synchrotron radiation.

[263]  D. Ferri,et al.  Improvement of Catalytic Activity of LaFe0.95Pd0.05O3 for Methane Oxidation under Transient Conditions , 2011 .

[264]  Di-Jia Liu,et al.  In situ XANES characterization of the Cu oxidation state in Cu-ZSM-5 during NO decomposition catalysis , 1993 .

[265]  C. Urbina,et al.  Spectroscopic characterization of coordination complexes based on dichlorocopper(II) and poly(4-vinylpyridine): Application in catalysis , 2005 .

[266]  C. Lamberti,et al.  EXAFS Study of Ti, Fe and Ga Substituted Silicalites , 1999 .

[267]  Christian Bressler,et al.  Molecular structural dynamics probed by ultrafast X-ray absorption spectroscopy. , 2010, Annual review of physical chemistry (Print).

[268]  Marc R. Knecht,et al.  Periodicity and Atomic Ordering in Nanosized Particles of Crystals , 2008 .

[269]  G. Ozin Nanochemistry: Synthesis in diminishing dimensions , 1992 .

[270]  S. Strauss Copper(I) and silver(I) carbonyls. To be or not to be nonclassical , 2000 .

[271]  E. Davidson,et al.  Extended x-ray-absorption fine-structure amplitudes—Wave-function relaxation and chemical effects , 1978 .

[272]  J. Niemantsverdriet,et al.  Bonding of supported chromium during thermal activation of the CrOx/SiO2 (Phillips) ethylene polymerization catalyst , 2001 .

[273]  A. Ankudinov,et al.  New developments in the theory of X-ray absorption and core photoemission , 2001 .

[274]  J. Misewich,et al.  Investigating the structure of boron nitride nanotubes by near-edge X-ray absorption fine structure (NEXAFS) spectroscopy. , 2005, Physical chemistry chemical physics : PCCP.

[275]  I. Moiseev,et al.  Giant palladium clusters: synthesis and characterization , 1991 .

[276]  M. Chergui,et al.  Ultrafast X-ray absorption spectroscopy. , 2004, Chemical reviews.

[277]  Shyam Biswas,et al.  Synthesis of metal-organic frameworks (MOFs): routes to various MOF topologies, morphologies, and composites. , 2012, Chemical reviews.

[278]  T. Tyson,et al.  “Ab-initio” modelling of x-ray absorption spectra , 1991 .

[279]  J. Grunwaldt,et al.  In situ spectroscopic investigation of heterogeneous catalysts and reaction media at high pressure. , 2005, Physical chemistry chemical physics : PCCP.

[280]  D. Friedman,et al.  Application of a novel multiple scattering approach to photoelectron diffraction and Auger electron diffraction , 1991 .

[281]  C. Lamberti,et al.  The structure of active centers and the ethylene polymerization mechanism on the Cr/SiO2 catalyst: a frontier for the characterization methods. , 2005, Chemical reviews.

[282]  Avelino Corma,et al.  State of the art and future challenges of zeolites as catalysts , 2003 .

[283]  G. Panov,et al.  Mechanisms of Iron Activation on Fe-Containing Zeolites and the Charge of α-Oxygen , 2003 .

[284]  T. Yokoyama,et al.  SPIN-CROSSOVER PHASE TRANSITION OF A CHAIN FE(II) COMPLEX STUDIED BY X-RAY-ABSORPTION FINE-STRUCTURE SPECTROSCOPY , 1998 .

[285]  J. Grunwaldt,et al.  The nature of the active site in the Fe-ZSM-5/N2O system studied by (resonant) inelastic X-ray scattering , 2007 .

[286]  El-Mekki El-Malki,et al.  Isothermal oscillations during N2O decomposition over Fe/ZSM-5: effect of H2O vapor☆ , 2000 .

[287]  J. Valyon,et al.  Effects of reduction and reoxidation on the infrared spectra from Cu-Y and Cu-ZSM-5 zeolites , 1993 .

[288]  Gérard Férey,et al.  Microporous Solids: From Organically Templated Inorganic Skeletons to Hybrid Frameworks...Ecumenism in Chemistry , 2001 .

[289]  Aaron Yevick,et al.  Effects of surface disorder on EXAFS modeling of metallic clusters , 2010 .

[290]  Y. Ono,et al.  Transformation of propane into aromatic hydrocarbons over ZSM-5 zeolites , 1986 .

[291]  Seth M Cohen,et al.  Isoreticular synthesis and modification of frameworks with the UiO-66 topology. , 2010, Chemical communications.

[292]  K. Lillerud,et al.  Spectroscopic evidence for a persistent benzenium cation in zeolite H-beta. , 2003, Journal of the American Chemical Society.

[293]  R. Nuzzo,et al.  Dynamic structure in supported Pt nanoclusters: Real-time density functional theory and x-ray spectroscopy simulations , 2008 .

[294]  U. Bergmann,et al.  Structure and Orientation of the Mn4Ca Cluster in Plant Photosystem II Membranes Studied by Polarized Range-extended X-ray Absorption Spectroscopy*♦ , 2007, Journal of Biological Chemistry.

[295]  H. Freund,et al.  Free-Electron Lasers: Status and Applications , 2001, Science.

[296]  C. Lamberti,et al.  Heterogeneous Nonclassical Carbonyls Stabilized in Cu(I)− and Ag(I)−ZSM-5 Zeolites: Thermodynamic and Spectroscopic Features , 2004 .

[297]  V. Briois,et al.  Combining two structural techniques on the micrometer scale: micro-XAS and micro-Raman spectroscopy. , 2007, Journal of synchrotron radiation.

[298]  Gérard Férey,et al.  Metal-organic frameworks in biomedicine. , 2012, Chemical reviews.

[299]  R. Prins,et al.  An in situ and operando X-ray absorption spectroscopy setup for measuring sub-monolayer model and powder catalysts. , 2005, Journal of synchrotron radiation.

[300]  C. Lamberti,et al.  Infrared study of carbon monoxide adsorption at 77 K on faujasites and ZSM-5 zeolites , 1993 .

[301]  R. Xiong,et al.  Ferroelectric metal-organic frameworks. , 2012, Chemical reviews.

[302]  S. Mukerjee,et al.  Contrast in Metal-Ligand Effects on PtnM Electrocatalysts with M Equal Ru vs Mo and Sn As Exhibited by in Situ XANES and EXAFS Measurements in Methanol , 2010 .

[303]  Alfons Baiker,et al.  2D-mapping of the catalyst structure inside a catalytic microreactor at work: partial oxidation of methane over Rh/Al2O3. , 2006, The journal of physical chemistry. B.

[304]  U. Bentrup Combining in situ characterization methods in one set-up: looking with more eyes into the intricate chemistry of the synthesis and working of heterogeneous catalysts. , 2010, Chemical Society reviews.

[305]  A. Kuzmin,et al.  EDA: EXAFS data analysis software package , 1995 .

[306]  Simon J L Billinge,et al.  The Problem with Determining Atomic Structure at the Nanoscale , 2007, Science.

[307]  J. Arnold,et al.  Titanium(II), -(III), and -(IV) Complexes Supported by Benzamidinate Ligands , 1998 .

[308]  H. Wende,et al.  Atomic EXAFS: evidence for photoelectron backscattering by interstitial charge densities , 1999 .

[309]  M. Janousch,et al.  In situ XAS and XRPD parametric rietveld refinement to understand dealumination of Y zeolite catalyst. , 2010, Journal of the American Chemical Society.

[310]  C. Lamberti,et al.  Structure and reactivity of framework and extraframework iron in Fe-silicalite as investigated by spectroscopic and physicochemical methods , 1996 .

[311]  C. Natoli,et al.  X-ray absorption spectroscopy: state-of-the-art analysis. , 2003, Journal of synchrotron radiation.

[312]  K. Doll,et al.  Ti-chabazite as a model system of Ti(IV) in Ti-zeolites: A periodic approach , 2003 .

[313]  F. Farges Fivefold-coordinated Ti4+ in metamict zirconolite and titanite: A new occurrence shown by Ti K-edge XANES spectroscopy , 1997 .

[314]  J. Bokhoven,et al.  Influence of Steam Activation on Pore Structure and Acidity of Zeolite Beta: An Al K Edge XANES Study of Aluminum Coordination , 2002 .

[315]  F. Lytle,et al.  Extended x‐ray absorption fine structure (EXAFS) of highly dispersed rhodium catalysts , 1983 .

[316]  C. Lamberti,et al.  Calorimetric and spectroscopic study of the coordinative unsaturation of copper(I) and silver(I) cations in ZSM-5 zeolite - Room temperature adsorption of NH3 , 2001 .

[317]  J. Sinfelt Role of surface science in catalysis , 2002 .

[318]  A. Frenkel,et al.  Electronic and magnetic properties of ultrathin Au/Pt nanowires. , 2009, Nano letters.

[319]  F. Meunier The design and testing of kinetically-appropriate operando spectroscopic cells for investigating heterogeneous catalytic reactions. , 2010, Chemical Society reviews.

[320]  C. Booth,et al.  Improved self-absorption correction for extended x-ray absorption fine-structure measurements , 2003 .

[321]  J. Niemantsverdriet,et al.  Pt-CO/SiO2 bimetallic planar model catalysts for selective hydrogenation of crotonaldehyde , 2004 .

[322]  A new cell for the study of in situ chemical reactions using X-ray absorption spectroscopy. , 2005, Journal of synchrotron radiation.

[323]  G. A. Lindsay,et al.  Fine Structure in the X-Ray Absorption Spectra of the K Series of the Elements Calcium to Gallium , 1930 .

[324]  Adriano Zecchina,et al.  Role of exposed metal sites in hydrogen storage in MOFs. , 2008, Journal of the American Chemical Society.

[325]  C. Lamberti,et al.  Reactivity of Ti(IV) sites in Ti-zeolites: An embedded cluster approach , 2002 .

[326]  Kimoon Kim,et al.  Homochiral metal-organic frameworks for asymmetric heterogeneous catalysis. , 2012, Chemical reviews.

[327]  M. Peruzzini,et al.  Synthesis, characterization and CO2 uptake of a chiral Co(II) Metal-Organic Framework containing a thiazolidine-based spacer , 2012 .

[328]  M. Chergui,et al.  Electronic and molecular structure of photoexcited [Ru(II)(bpy)3]2+ probed by picosecond X-ray absorption spectroscopy. , 2006, Journal of the American Chemical Society.

[329]  N. Jaeger,et al.  A XANES and EXAFS investigation of titanium silicalite , 1991 .

[330]  B. Sels,et al.  A [Cu2O]2+ core in Cu-ZSM-5, the active site in the oxidation of methane to methanol , 2009, Proceedings of the National Academy of Sciences.

[331]  D. Ramaker,et al.  The metal–support interaction in Pt/Y zeolite: evidence for a shift in energy of metal d-valence orbitals by Pt–H shape resonance and atomic XAFS spectroscopy , 2000 .

[332]  M. Fernández-García,et al.  XANES-TPR Study of Cu-Pd Bimetallic Catalysts: Application of Factor Analysis , 1995 .

[333]  K. Lillerud,et al.  Post-synthetic modification of the metal–organic framework compound UiO-66 , 2010 .

[334]  P. Ratnasamy,et al.  Reactive oxygen species in epoxidation reactions over titanosilicate molecular sieves , 2003 .

[335]  C. Lamberti,et al.  Modeling CO and N2 adsorption at Cr surface species of Phillips catalyst by hybrid density functionals: effect of Hartree-Fock exchange percentage. , 2009, The journal of physical chemistry. A.

[336]  Mircea Dincă,et al.  Hydrogen storage in metal-organic frameworks. , 2009, Chemical Society reviews.

[337]  G. Tabacchi,et al.  Electronic spectra of Ti(IV) in zeolites: an ab initio approach. , 2005, Chemphyschem : a European journal of chemical physics and physical chemistry.

[338]  Bartolomeo Civalleri,et al.  Hartree–Fock geometry optimisation of periodic systems with the Crystal code , 2001 .

[339]  E. Weckert,et al.  Review of third and next generation synchrotron light sources , 2005 .

[340]  W. Lukens,et al.  Perhydrocarbyl ReVII complexes: comparison of molecular and surface complexes. , 2003, Journal of the American Chemical Society.

[341]  J. K. Park,et al.  Design and feasibility of quick EXAFS scans for a 'broomstick' double-crystal monochromator at PLS beamline. , 1998, Journal of synchrotron radiation.

[342]  V. G. Yarzhemsky,et al.  EXAFS in total reflection (reflEXAFS) for the study of organometallic Pd(II) thiol complexes based self-assembled monolayers on gold , 2011, CP 2011.

[343]  C. Catlow,et al.  X-ray absorption spectroscopic study of Bronsted, Lewis, and redox centers in cobalt-substituted aluminum phosphate catalysts , 1996 .

[344]  R. Prins,et al.  Determination of metal particle size of highly dispersed Rh, Ir, and Pt catalysts by hydrogen chemisorption and EXAFS , 1986 .

[345]  H. Hou,et al.  Catalytic applications of CuII-containing MOFs based on N-heterocyclic ligand in the oxidative coupling of 2,6-dimethylphenol , 2007 .

[346]  M. Beauchemin,et al.  Principal Component Analysis Approach for Modeling Sulfur K-XANES Spectra of Humic Acids , 2002 .

[347]  F. Ribeiro,et al.  Low absorption vitreous carbon reactors for operando XAS: a case study on Cu/Zeolites for selective catalytic reduction of NO(x) by NH3. , 2012, Physical chemistry chemical physics : PCCP.

[348]  S. Kaliaguine,et al.  Novel titanium sites in silicalites , 1992 .

[349]  Uwe Bergmann,et al.  X-ray emission spectroscopy to study ligand valence orbitals in Mn coordination complexes. , 2009, Journal of the American Chemical Society.

[350]  H. Renevier,et al.  Pre-edge structure analysis of Ti K-edge polarized X-ray absorption spectra in TiO2 by full-potential XANES calculations. , 1999, Journal of synchrotron radiation.

[351]  W. Mross Alkali Doping in Heterogeneous Catalysis , 1983 .

[352]  M. L. Connolly Solvent-accessible surfaces of proteins and nucleic acids. , 1983, Science.

[353]  Y. Iwasawa,et al.  Photoinduced reversible structural transformation and selective oxidation catalysis of unsaturated ruthenium complexes supported on SiO2. , 2008, Angewandte Chemie.

[354]  O. Swang,et al.  Detailed reaction paths for zeolite dealumination and desilication from density functional calculations. , 2012, Angewandte Chemie.

[355]  T. Tatsumi,et al.  Extremely high trans selectivity of Ti-MWW in epoxidation of alkenes with hydrogen peroxide , 2001 .

[356]  L. Fonda Multiple-scattering theory of x-ray absorption : a review , 1992 .

[357]  B. Weckhuysen,et al.  Diffuse Reflectance Spectroscopy of Supported Chromium Oxide Catalysts: A Self-Modeling Mixture Analysis , 1997 .

[358]  J. Tarascon,et al.  Mixed-valence li/fe-based metal-organic frameworks with both reversible redox and sorption properties. , 2007, Angewandte Chemie.

[359]  F. Kapteijn,et al.  Active site structure sensitivity in N2O conversion over FeMFI zeolites , 2003 .

[360]  C. Arean,et al.  Computational and Experimental Studies on the Adsorption of CO, N2, and CO2 on Mg-MOF-74 , 2010 .

[361]  Y. Ono,et al.  Transformation of butanes over ZSM-5 zeolites. Part 2.—Formation of aromatic hydrocarbons over Zn-ZSM-5 and Ga-ZSM-5 , 1991 .

[362]  C. Lamberti,et al.  Polycarbonylic and polynitrosylic species in CuI-exchanged ZSM-5, β, mordenite and Y zeolites: comparison with homogeneous complexes , 2000 .

[363]  C. Lamberti,et al.  Local structure of CPO-27-Ni metallorganic framework upon dehydration and coordination of NO , 2008 .

[364]  Christian J. Doonan,et al.  Multiple Functional Groups of Varying Ratios in Metal-Organic Frameworks , 2010, Science.

[365]  Takashi Tatsumi,et al.  Synthesis and catalytic performance of Ti-MCM-68 for effective oxidation reactions. , 2008, Chemical communications.

[366]  A. MacDowell,et al.  Soft x‐ray beam line for surface EXAFS studies in the energy range 60≤hν≤11 100 eV at the Daresbury SRS , 1986 .

[367]  J. Rehr,et al.  Extended x-ray absorption fine structure Debye-Waller factors. I. Monatomic crystals , 1979 .

[368]  F. Matthias Bickelhaupt,et al.  Chemistry with ADF , 2001, J. Comput. Chem..

[369]  Booth,et al.  Reply to "Comment on 'x-ray-absorption fine structure in embedded atoms' " , 1996, Physical Review B (Condensed Matter).

[370]  Avelino Corma,et al.  Synthesis of an ultralarge pore titanium silicate isomorphous to MCM-41 and its application as a catalyst for selective oxidation of hydrocarbons , 1994 .

[371]  A. Sanson,et al.  Extended x-ray-absorption fine-structure measurements of copper: Local dynamics, anharmonicity, and thermal expansion , 2004 .

[372]  W. Hall,et al.  Catalytic decomposition of nitric oxide over Cu-zeolites , 1991 .

[373]  K. Klementev Package “VIPER (visual processing in EXAFS researches) for windows”☆ , 2000 .

[374]  C. Kepert,et al.  Elucidating Negative Thermal Expansion in MOF-5 , 2010 .

[375]  J. Bozek,et al.  Non-linear processes in the interaction of atoms and molecules with intense EUV and X-ray fields from SASE free electron lasers (FELs) , 2010 .

[376]  C. Prestipino,et al.  Quick-EXAFS implementation on the general purpose EXAFS beamline at ESRF , 2011, Journal of synchrotron radiation.

[377]  B. Wichterlová,et al.  Identification of Cu Sites in ZSM-5 Active in NO Decomposition , 1995 .

[378]  B. Weckhuysen,et al.  Atomic XAFS as a tool to probe the electronic properties of supported noble metal nanoclusters. , 2005, Journal of the American Chemical Society.

[379]  F. d’Acapito,et al.  Probing the initial stages of solid-state reactions by total reflection EXAFS (reflEXAFS) , 2003 .

[380]  R. W. Joyner,et al.  Preparation, Characterization, and Performance of Fe−ZSM-5 Catalysts , 1999 .

[381]  F. d’Acapito,et al.  Temperature modification of the Nb oxidation at the Nb/Al interface studied by reflEXAFS , 2000 .

[382]  K. Theopold Homogeneous Chromium Catalysts for Olefin Polymerization , 1998 .

[383]  A. Fitch,et al.  Selective catalytic reduction of NOx over microporous CuAPO-5: structural characterisation by XAS and XRD , 2005 .

[384]  D. P. Woodruff,et al.  Normal-incidence standing X-ray wavefield absorption and SEXAFS studies of adsorption structures on Cu and Ni surfaces , 1990 .

[385]  John J. Rehr,et al.  Theoretical X-ray Absorption Fine Structure Standards , 1991 .

[386]  F. Lytle X-Ray Absorption Fine-Structure Investigations at Cryogenic Temperatures , 1963 .

[387]  M. Allendorf,et al.  Luminescent metal-organic frameworks. , 2009, Chemical Society reviews.

[388]  H. Wan,et al.  Supported Au catalysts prepared from Au phosphine complexes and As-precipitated metal hydroxides: Characterization and low-temperature CO oxidation , 1997 .

[389]  J. Grunwaldt,et al.  A versatile in situ spectroscopic cell for fluorescence/transmission EXAFS and X-ray diffraction of heterogeneous catalysts in gas and liquid phase. , 2007, Journal of synchrotron radiation.

[390]  F. Lytle The EXAFS family tree: a personal history of the development of extended X-ray absorption fine structure. , 1999, Journal of synchrotron radiation.

[391]  M. Gibbs,et al.  Measurement of femtometre-scale atomic displacements by X-ray absorption spectroscopy , 2005, Nature.

[392]  Peng Wu,et al.  CHARACTERIZATION OF TITANIUM SPECIES INCORPORATED INTO DEALUMINATED MORDENITES BY MEANS OF IR SPECTROSCOPY AND 18O-EXCHANGE TECHNIQUE , 1996 .

[393]  W. O'grady,et al.  'Atomic' X-ray absorption fine structure : a new tool for examining electrochemical interfaces , 1998 .

[394]  R. Greegor,et al.  Effect of chemical environment on magnitude of x‐ray absorption resonance at LIII edges. Studies on metallic elements, compounds, and catalysts , 1979 .

[395]  Stuart L James,et al.  Metal-organic frameworks. , 2003, Chemical Society reviews.

[396]  C. Lamberti,et al.  Preparation of Pd/C catalysts: from the Pd-precursor solution to the final systems , 2006 .

[397]  B. Sels,et al.  Cu-ZSM-5: A biomimetic inorganic model for methane oxidation. , 2011, Journal of catalysis.

[398]  V. A. Safonov,et al.  Cr local environment by valence-to-core X-ray emission spectroscopy , 2009 .

[399]  H. Fjellvåg,et al.  Adsorption properties and structure of CO2 adsorbed on open coordination sites of metal-organic framework Ni2(dhtp) from gas adsorption, IR spectroscopy and X-ray diffraction. , 2008, Chemical communications.

[400]  D. Ramaker,et al.  Separation of Geometric and Electronic Effects of the Support on the CO and H2 Chemisorption Properties of Supported Pt Particles: The Effect of Ionicity in Modified Alumina Supports , 2007 .

[401]  C. Lamberti,et al.  Behavior of extraframework Fe sites in MFI and MCM-22 zeolites upon interaction with N2O and NO. , 2005, The journal of physical chemistry. B.

[402]  A. Kentgens,et al.  The removal of gallium from the lattice of MF1-gallosilicates as studied by 71Ga M.A.S-N.M.R spectroscopy , 1989 .

[403]  S. Schroeder Towards a 'universal curve' for total electron-yield XAS , 1996 .

[404]  V. López‐Flores,et al.  Optimized end station and operating protocols for reflection extended x-ray absorption fine structure (ReflEXAFS) investigations of surface structure at the European Synchrotron Radiation Facility beamline BM29. , 2007, The Review of scientific instruments.

[405]  A. Frenkel Applications of extended X-ray absorption fine-structure spectroscopy to studies of bimetallic nanoparticle catalysts. , 2012, Chemical Society reviews.

[406]  F. Geobaldo,et al.  Characterization of Gallosilicate MFI-Type Zeolites by IR spectroscopy of Adsorbed Probe molecules. , 1996 .

[407]  E. Borfecchia,et al.  Iron oxidation state in garnet from a subduction setting: a micro-XANES and electron microprobe (“flank method”) comparative study , 2012 .

[408]  E. Stern Theory of the extended x-ray-absorption fine structure , 1974 .

[409]  A. Dent,et al.  In situ energy dispersive EXAFS (EDE) of low loaded Pt(acac)2/HI SiO2 catalyst precursors on a timescale of seconds and below , 1999 .

[410]  M. Skoglundh,et al.  In Situ Spectroscopic Investigation of Low-Temperature Oxidation of Methane over Alumina-Supported Platinum during Periodic Operation† , 2011 .

[411]  C. Serre,et al.  Porous Chromium Terephthalate MIL‐101 with Coordinatively Unsaturated Sites: Surface Functionalization, Encapsulation, Sorption and Catalysis , 2009 .

[412]  Avelino Corma,et al.  Water stable Zr-benzenedicarboxylate metal-organic frameworks as photocatalysts for hydrogen generation. , 2010, Chemistry.

[413]  G. Spoto,et al.  IR Spectra of CO Adsorbed at Low Temperature (77 K) On Titaniumsilicalite, H-ZSM5 and Silicalite , 1991 .

[414]  J. Niemantsverdriet,et al.  A surface science model for the Phillips ethylene polymerization catalyst : thermal activation and polymerization activity , 2004 .

[415]  A. Ankudinov,et al.  REAL-SPACE MULTIPLE-SCATTERING CALCULATION AND INTERPRETATION OF X-RAY-ABSORPTION NEAR-EDGE STRUCTURE , 1998 .

[416]  A. Beale,et al.  Comparing CuAPO-5 with Cu:ZSM-5 in the selective catalytic reduction of NOx : An in situ study , 2007 .

[417]  H. Renevier,et al.  DIFFRACTION-ANOMALOUS-FINE-STRUCTURE SPECTROSCOPY APPLIED TO THE STUDY OF III-V STRAINED SEMICONDUCTORS , 1999 .

[418]  A. Yagishita,et al.  Formation and oxidation mechanisms of Pd-Zn nanoparticles on a ZnO supported Pd catalyst studied by in situ time-resolved QXAFS and DXAFS. , 2012, Physical chemistry chemical physics : PCCP.

[419]  K. Lillerud,et al.  Assessing the acidity of high silica chabazite H-SSZ-13 by FTIR using CO as molecular probe: Comparison with H-SAPO-34. , 2005, The journal of physical chemistry. B.

[420]  A. Yaresko,et al.  Electronic structure and x-ray magnetic circular dichroism in uranium compounds. III. Heavy-fermion compounds , 2003 .

[421]  D. Ferri,et al.  Combined liquid-phase ATR-IR and XAS study of the Bi-promotion in the aerobic oxidation of benzyl alcohol over Pd/Al2O3 , 2007 .

[422]  C. Catlow,et al.  The architecture of catalytically active centers in titanosilicate (TS-1) and related selective-oxidation catalysts , 2000 .

[423]  R. Greegor,et al.  Determination of thermal amplitude of surface atoms in a supported Pt catalyst by EXAFS spectroscopy , 1982 .

[424]  Y. Joly Interaction of Polarized Light with Matter , 2010 .

[425]  C. Lamberti,et al.  Anchoring Fe ions to amorphous and crystalline oxides: a means to tune the degree of Fe coordination. , 2003, Chemphyschem : a European journal of chemical physics and physical chemistry.

[426]  E. Hensen,et al.  Direct NO and N2O decomposition and NO-assisted N2O decomposition over Cu-zeolites : elucidating the influence of the Cu-Cu distance on the oxygen migration , 2007 .

[427]  T. Nakai,et al.  State of titanium in Ti-containing silica and silicalite catalysts in relation to their oxidation activity , 1994 .

[428]  R. Sheldon,et al.  AMMOXIMATION OF CYCLOHEXANONE AND HYDROXYAROMATIC KETONES OVER TITANIUM MOLECULAR SIEVES , 1996 .

[429]  G. Spoto,et al.  Cu(I)-ZSM-5 zeolites prepared by reaction of H-ZSM-5 with gaseous CuCl: Spectroscopic characterization and reactivity towards carbon monoxide and nitric oxide☆ , 1994 .

[430]  H. Mao,et al.  In Situ Studies of Iron under Pressure: New Windows on the Earth's Core , 2001 .

[431]  Gérard Férey,et al.  Hybrid porous solids: past, present, future. , 2008, Chemical Society reviews.

[432]  C. Lamberti,et al.  Preparation of supported Pd catalysts: from the Pd precursor solution to the deposited Pd2+ phase. , 2010, Langmuir : the ACS journal of surfaces and colloids.

[433]  A. Frenkel,et al.  Phase speciation by extended x-ray absorption fine structure spectroscopy , 2002 .

[434]  C. Serre,et al.  Synthesis, characterisation and luminescent properties of a new three-dimensional lanthanide trimesate: M((C6H3)–(CO2)3)(M = Y, Ln) or MIL-78 , 2004 .

[435]  P. Ellis,et al.  XFIT - an Interactive EXAFSAnalysis Program. , 1995, Journal of synchrotron radiation.

[436]  C. Lamberti,et al.  On the Structure of the Active Site of Ti-Silicalite in Reactions with Hydrogen Peroxide: A Vibrational and Computational Study , 1998 .

[437]  A. Bell,et al.  X-ray absorption fine structure analysis of the local environment of Fe in Fe/Al-MFI , 2004 .

[438]  Filipponi,et al.  Comment on "X-ray-absorption fine structure in embedded atoms" , 1996, Physical review. B, Condensed matter.

[439]  A. Urakawa,et al.  Copper metal–organic framework: Structure and activity in the allylic oxidation of cyclohexene with molecular oxygen , 2010 .

[440]  Z. Gabelica,et al.  Synthesis of MFI metallosilicate zeolites using metallic amino complexes as mineralizing agents: an overview , 1999 .

[441]  D. Bazin,et al.  In Situ XAFS Measurement of Catalysts , 1996 .

[442]  A. Corma,et al.  Synthesis of titanoaluminosilicates isomorphous to zeolite Beta, active as oxidation catalysts , 1993 .

[443]  G. Spinolo,et al.  Micro-XANES mapping of buried interfaces: pushing microbeam techniques to the nanoscale. , 2010, Physical chemistry chemical physics : PCCP.

[444]  C. Pak,et al.  Reversible coordination change of chromium in Cr-MCM-41 and Cr-MCM-48 studied by X-ray absorption near edge structure , 2001 .

[445]  A. Carati,et al.  Preparation and characterisation of mesoporous silica–alumina and silica–titania with a narrow pore size distribution , 2003 .

[446]  D. Ferri,et al.  First steps in combining modulation excitation spectroscopy with synchronous dispersive EXAFS/DRIFTS/mass spectrometry for in situ time resolved study of heterogeneous catalysts. , 2010, Physical chemistry chemical physics : PCCP.

[447]  Krista S. Walton,et al.  Exceptional negative thermal expansion in isoreticular metal-organic frameworks. , 2007, Angewandte Chemie.

[448]  J. F. Creemer,et al.  Nanoscale chemical imaging of the reduction behavior of a single catalyst particle. , 2009, Angewandte Chemie.

[449]  U. Bergmann,et al.  Site-selective EXAFS in mixed-valence compounds using high-resolution fluorescence detection: a study of iron in Prussian Blue. , 2002, Inorganic chemistry.

[450]  G. Bond,et al.  Compensation Phenomena in Heterogeneous Catalysis: General Principles and a Possible Explanation , 2000 .

[451]  A. Beale,et al.  Chemical imaging of catalytic solids with synchrotron radiation. , 2010, Chemical Society reviews.

[452]  C. Prestipino,et al.  Novel high-temperature reactors for in situ studies of three-way catalysts using turbo-XAS. , 2009, Journal of synchrotron radiation.

[453]  E. Borfecchia,et al.  Insights into Adsorption of NH3 on HKUST-1 Metal–Organic Framework: A Multitechnique Approach , 2012 .

[454]  J. A. Ryder,et al.  X-ray Absorption Fine Structure Characterization of the Local Structure of Fe in Fe−ZSM-5 , 2003 .

[455]  K. Góra-Marek,et al.  Nitrogen Monoxide Interaction with Cu(I) Sites in Zeolites X and Y : Quantum Chemical Calculations and IR Studies , 2008 .

[456]  A. Dent,et al.  Combining diffuse reflectance infrared spectroscopy (DRIFTS), dispersive EXAFS, and mass spectrometry with high time resolution: Potential, limitations, and application to the study of NO interaction with supported Rh catalysts , 2007 .

[457]  K. Houthoofd,et al.  Reversible NOx storage over Ru/Na–Y zeolite , 2010 .

[458]  J. Hanawalt The Dependence of X-ray Absorption Spectra upon Chemical and Physical State , 1931 .

[459]  Marc R. Knecht,et al.  Structural Rearrangement of Bimetallic Alloy PdAu Nanoparticles within Dendrimer Templates to Yield Core/Shell Configurations† , 2008 .

[460]  A. Beale,et al.  A combined in situ time-resolved UV–Vis, Raman and high-energy resolution X-ray absorption spectroscopy study on the deactivation behavior of Pt and Pt-Sn propane dehydrogenation catalysts under industrial reaction conditions , 2010 .

[461]  M. Makkee,et al.  Selective Catalytic Reduction of NO with NH3 over Fe-ZSM-5 Catalysts Prepared by Sublimation of FeCl3 at Different Temperatures , 2003 .

[462]  Jamie A. Gould,et al.  Nitric oxide chemisorption in a postsynthetically modified metal-organic framework. , 2009, Inorganic chemistry.

[463]  G. Bellussi,et al.  Structural characterization of as-synthesized B- and Ti-containing MFI-type molecular sieves , 2000 .

[464]  K. Asakura Analysis of EXAFS , 1996 .

[465]  H. Wende,et al.  Recent advances in x-ray absorption spectroscopy , 2004 .

[466]  G. Ghiotti,et al.  On the chemistry of silica-supported Cr ions. Part II. One ligand complexes. Adsorption of carbon monoxide, carbon dioxide and pyridine , 1975 .

[467]  B. Weckhuysen,et al.  Revealing shape selectivity and catalytic activity trends within the pores of H-ZSM-5 crystals by time- and space-resolved optical and fluorescence microspectroscopy. , 2007, Chemistry.

[468]  D. Ferri,et al.  Modulation Excitation X-Ray Absorption Spectroscopy to Probe Surface Species on Heterogeneous Catalysts , 2011 .

[469]  A. Regazzoni,et al.  The interaction of metal oxide surfaces with complexing agents dissolved in water , 2000 .

[470]  P. Magusin,et al.  Effect of aluminum on the nature of the iron species in Fe-SBA-15. , 2006, The journal of physical chemistry. B.

[471]  Thole,et al.  X-ray circular dichroism as a probe of orbital magnetization. , 1992, Physical review letters.

[472]  F. Ribeiro,et al.  Integrated operando X-ray absorption and DFT characterization of Cu–SSZ-13 exchange sites during the selective catalytic reduction of NOx with NH3 , 2012 .

[473]  Yan Liu,et al.  Engineering Homochiral Metal‐Organic Frameworks for Heterogeneous Asymmetric Catalysis and Enantioselective Separation , 2010, Advanced materials.

[474]  J. Rabalais CHEMICAL REACTION INDUCED MASS TRANSPORT AT SURFACES , 1994 .

[475]  D. Root,et al.  Spectroscopic studies of side-on peroxide-bridged binuclear copper(II) model complexes of relevance to oxyhemocyanin and oxytyrosinase , 1992 .

[476]  Christian G. Schroer,et al.  Hard and soft X-ray microscopy and tomography in catalysis: bridging the different time and length scales. , 2010, Chemical Society reviews.

[477]  M. Britton Magnetic resonance imaging of chemistry. , 2010, Chemical Society reviews.

[478]  M. Chergui,et al.  Picosecond time-resolved x-ray absorption spectroscopy of solvated organometallic complexes , 2005 .

[479]  F. Lytle,et al.  Structure of bimetallic clusters. Extended x‐ray absorption fine structure (EXAFS) studies of Rh–Cu clusters , 1983 .

[480]  R. Lobo,et al.  Copper Coordination in Cu-SSZ-13 and Cu-SSZ-16 Investigated by Variable-Temperature XRD , 2010 .

[481]  R. Albers Electronic band-structure methods for XAS , 1989 .

[482]  H. Maeda,et al.  SPECIFIC FEATURE OF COPPER ION-EXCHANGED MORDENITE FOR DINITROGEN ADSORPTION AT ROOM TEMPERATURE , 1995 .

[483]  Hiroaki Yamanaka,et al.  Surface nano-architecture of a metal-organic framework. , 2010, Nature materials.

[484]  Progress and challenges in the theory and interpretation of X-ray spectra. , 2001 .

[485]  R. Nuzzo,et al.  A view from the inside: Complexity in the atomic scale ordering of supported metal nanoparticles , 2001 .

[486]  A. Corma,et al.  Uniform catalytic site in Sn-beta-zeolite determined using X-ray absorption fine structure. , 2005, Journal of the American Chemical Society.

[487]  P. Glatzel,et al.  In situ characterization of the 5d density of states of Pt nanoparticles upon adsorption of CO. , 2010, Journal of the American Chemical Society.

[488]  B. Weckhuysen,et al.  In situ synchrotron-based IR microspectroscopy to study catalytic reactions in zeolite crystals. , 2008, Angewandte Chemie.

[489]  F. Fontanelli,et al.  Detection of environmental fine structure in the low-energy β-decay spectrum of 187Re , 1999, Nature.

[490]  Y. Joly,et al.  X-ray absorption near-edge structure calculations beyond the muffin-tin approximation , 2001 .

[491]  D. Cockayne The Study of Nanovolumes of Amorphous Materials Using Electron Scattering , 2007 .

[492]  R. Linford EXAFS studies of polymer electrolytes , 1995 .

[493]  Liang Wang,et al.  Designed synthesis of TS-1 crystals with controllable b-oriented length. , 2011, Chemical communications.

[494]  C. Lamberti,et al.  Pd-supported catalysts: evolution of support porous texture along Pd deposition and alkali-metal doping. , 2009, Langmuir : the ACS journal of surfaces and colloids.

[495]  J. Evans Tilden lecture: shining light on metal catalysts , 1997 .

[496]  M. Newton Beam-size-related phenomena and effective normalization in energy-dispersive EXAFS for the study of heterogeneous catalysts, powder materials and the processes they mediate: observations and (some) solutions. , 2007, Journal of synchrotron radiation.

[497]  A. J. O'leary Interaction of X-rays with Bound Electrons , 1931 .

[498]  C. Lamberti,et al.  XANES, EXAFS and FTIR characterization of copper-exchanged mordenite , 1998 .

[499]  M. J. Ellis,et al.  Atomic resolution crystallography and XAFS , 2005 .

[500]  H. Ebert,et al.  Spin—Orbit-Influenced Spectroscopies of Magnetic Solids , 1996 .

[501]  W. Hölderich,et al.  Modified Beta zeolites as catalysts for the Beckmann rearrangement of cyclohexanone oxime , 1999 .

[502]  E. A. Quadrelli,et al.  Well-defined surface imido amido tantalum(v) species from ammonia and silica-supported tantalum hydrides. , 2007, Journal of the American Chemical Society.

[503]  M. Fernández-García,et al.  Selective CO oxidation in excess H2 over copper-ceria catalysts: identification of active entities/species. , 2007, Journal of the American Chemical Society.

[504]  Anatoly Snigirev,et al.  Nanotomography based on hard x-ray microscopy with refractive lenses , 2002 .

[505]  J. Derrien,et al.  Evidence of extended fine structures in the Auger spectra: A new approach for surface structural studies , 1986 .

[506]  J. Hormes,et al.  An X-ray absorption near edge spectroscopy (XANES) study on organochromium complexes at the Cr K-edge , 1998 .

[507]  A. Suzuki,et al.  Time scale and elementary steps of CO-induced disintegration of surface rhodium clusters. , 2003, Angewandte Chemie.

[508]  G. M. Zhidomirov,et al.  Cluster Model DFT Study of the Intermediates of Benzene to Phenol Oxidation by N2O on FeZSM-5 Zeolites , 2003 .

[509]  Graham N. Newton,et al.  Following the self assembly of supramolecular MOFs using X-ray crystallography and cryospray mass spectrometry , 2010 .

[510]  S. Kitagawa,et al.  Temperature responsive channel uniformity impacts on highly guest-selective adsorption in a porous coordination polymer , 2010 .

[511]  C. Lamberti,et al.  Infrared studies of the interaction of carbon monoxide and dinitrogen with ferrisilicate MFI-type zeolites , 1996 .

[512]  R. Schlögl,et al.  In-situ soft X-ray absorption of over-exchanged Fe/ZSM5 , 2003 .

[513]  Frenkel,et al.  Thermal expansion and x-ray-absorption fine-structure cumulants. , 1993, Physical review. B, Condensed matter.

[514]  F. K. Richtmyer,et al.  The Relative Intensities of CertainL-Series X-Ray Satellites in Cathode-Ray and in Fluorescence Excitation , 1933 .

[515]  M. Jansen,et al.  Extended X-ray absorption fine-structure (EXAFS) of a complex oxide structure: A full multiple scattering analysis of the Au L3-edge EXAFS of Au2O3 , 2003 .

[516]  K. Chapman,et al.  Elucidating the structure of surface acid sites on γ-Al2O3. , 2011, Journal of the American Chemical Society.

[517]  G. Hertz über die Absorptionsgrenzen in derL-Serie , 1920 .

[518]  A. Witkowska,et al.  Local ordering of nanostructured Pt probed by multiple-scattering XAFS , 2007 .

[519]  J. Marangos Introduction to the new science with X-ray free electron lasers , 2011 .

[520]  C. Serre,et al.  An EXAFS study of the formation of a nanoporous metal-organic framework: evidence for the retention of secondary building units during synthesis. , 2006, Chemical communications.

[521]  Y. Kvashnin,et al.  Ligand identification in titanium complexes using X-ray valence-to-core emission spectroscopy. , 2010, Inorganic chemistry.

[522]  P. S. Prasad,et al.  Low temperature ethylene chemisorption (L.T.E.C.): a novel technique for the characterisation of CuCl2–KCl/γ-Al2O3 oxychlorination catalysts , 1987 .

[523]  K. Chao,et al.  Characterization of metal-incorporated molecular sieves , 1999 .

[524]  J. Arthur,et al.  X-ray free-electron lasers , 2005 .

[525]  F. Cavani,et al.  Sustainability in catalytic oxidation: an alternative approach or a structural evolution? , 2009, ChemSusChem.

[526]  C. Grey,et al.  Application of high-energy X-rays and Pair-Distribution-Function analysis to nano-scale structural studies in catalysis , 2009 .

[527]  Bernd G. Pfrommer,et al.  Relaxation of Crystals with the Quasi-Newton Method , 1997 .

[528]  Hong-Cai Zhou,et al.  Metal-organic frameworks for separations. , 2012, Chemical reviews.

[529]  C. Lamberti,et al.  Structural characterization of Ti centres in Ti-silicalite and reaction mechanisms in cyclohexanone ammoximation , 1996 .

[530]  A. V. D. Eerden,et al.  Flexible aluminium coordination of zeolites as function of temperature and water content, an in-situ method to determine aluminium coordinations , 2002 .

[531]  Xinsheng Liu,et al.  Gallozeolite catalysts: preparation, characterization and performance , 1986 .

[532]  Cheng Wang,et al.  Isoreticular chiral metal-organic frameworks for asymmetric alkene epoxidation: tuning catalytic activity by controlling framework catenation and varying open channel sizes. , 2010, Journal of the American Chemical Society.

[533]  S. Bordiga,et al.  Selective Oxidation of Ammonia to Hydroxylamine with Hydrogen Peroxide on Titanium Based Catalysts , 1994 .

[534]  T. Saito,et al.  In situ XAFS analysis system for high-pressure catalytic reactions and its application to CO2 hydrogenation over a Rh/Y-zeolite catalyst. , 2001, Journal of synchrotron radiation.

[535]  L. Liotta,et al.  Structure and the Metal Support Interaction of the Au/Mn Oxide Catalysts , 2010 .

[536]  M. Fernández-García,et al.  Multitechnique analysis of supported Pd particles upon dynamic, cycling CO/NO conditions: Size-dependence of the structure–activity relationship , 2010 .

[537]  R. Rye,et al.  Flash desorption and equilibration of H2 and D2 on single crystal surfaces of platinum , 1974 .

[538]  J. Bokhoven,et al.  In situ X-ray absorption spectroscopy as a unique tool for obtaining information on hydrogen binding sites and electronic structure of supported Pt catalysts: towards an understanding of the compensation relation in alkane hydrogenolysis , 2003 .

[539]  Ivar M. Dahl,et al.  On the Reaction Mechanism for Hydrocarbon Formation from Methanol over SAPO-34 2. Isotopic Labeling Studies of the Co-reaction of Propene and Methanol , 1994 .

[540]  F. Boscherini Chapter 7 – X-Ray Absorption Fine Structure in the Study of Semiconductor Heterostructures and Nanostructures , 2013 .

[541]  J. Hazemann,et al.  Quantitative Analysis of X-Ray Absorption Near Edge Structure Data by a Full Multiple Scattering Procedure , 2001 .

[542]  Jianlin Shi,et al.  Hierarchical mesoporous TS-1 zeolite: a highly active and extraordinarily stable catalyst for the selective oxidation of 2,3,6-trimethylphenol. , 2010, Chemical communications.

[543]  F. Lytle Determination of Interatomic Distances from X-Ray Absorption Fine Structure , 1965 .

[544]  F. d’Acapito,et al.  Reactivity of Cr Species Grafted on SiO2/Si(100) Surface: A Reflection Extended X-ray Absorption Fine Structure Study down to the Submonolayer Regime , 2007 .

[545]  T. Ishikawa,et al.  Single-nanometer focusing of hard x-rays by Kirkpatrick–Baez mirrors , 2011, Journal of physics. Condensed matter : an Institute of Physics journal.

[546]  C. Lamberti The use of synchrotron radiation techniques in the characterization of strained semiconductor heterostructures and thin films , 2004 .

[547]  J. Grunwaldt,et al.  Combining XRD and EXAFS with on-Line Catalytic Studies for in situ Characterization of Catalysts , 2002 .

[548]  Y. Nishino,et al.  Photon interference x-ray absorption fine structure , 2001 .

[549]  G. Thornton,et al.  Low-coverage condensation of K on TiO2(110) 1 × 1 , 2005 .

[550]  Ian D. Williams,et al.  Tetravalent titanium, zirconium, and cerium oxo and peroxo complexes containing an imidodiphosphinate ligand. , 2012, Inorganic chemistry.

[551]  G. Bellussi,et al.  Framework composition of titanium silicalite-1 , 1992 .

[552]  W. Liu,et al.  Subnanometric Pd Particles Stabilized Inside Highly Cross-Linked Polymeric Supports , 2010 .

[553]  W. Schaich Comment on the Theory of Extended X-Ray-Absorption Fine Structure , 1973 .

[554]  T. Ressler,et al.  Redox Behavior of Copper Oxide /Zinc Oxide Catalysts in the Steam Reforming of Methanol studied by in situ X-ray Diffraction and Absorption Spectroscopy , 2001 .

[555]  G. Ghiotti,et al.  IR investigation of polymerization centres of the Phillips Catalyst. , 1988 .

[556]  A. Corma,et al.  Bridging homogeneous and heterogeneous catalysis with MOFs: “Click” reactions with Cu-MOF catalysts , 2010 .

[557]  J. Fierro,et al.  Hydrogenation of aromatics over Au-Pd/SiO2-Al2O3 catalysts; support acidity effect , 2004 .

[558]  V. Serin,et al.  EXELFS as a structural tool for studies of low Z-elements , 1992 .

[559]  R. Revel,et al.  A new X-ray absorption experimental set-up dedicated to DeNOx catalysis , 1999 .

[560]  Crystallography: past and present , 2007 .

[561]  B. Weckhuysen,et al.  Snapshots of a working catalyst: possibilities and limitations of in situ spectroscopy in the field of heterogeneous catalysis. , 2002, Chemical communications.

[562]  Axel E. Lindh Zur Kenntnis desK-Röntgenabsorptionsspektrums der Elemente Ni, Cu und Zn , 1930 .

[563]  Qinghong Zhang,et al.  Characterizations and catalytic properties of Cr-MCM-41 prepared by direct hydrothermal synthesis and template-ion exchange , 2003 .

[564]  Josef Hormes,et al.  A grazing incidence surface X-ray absorption fine structure (GIXAFS) study of alkanethiols adsorbed on Au, Ag, and Cu , 2000 .

[565]  Christian Spielmann,et al.  Femtosecond x-ray science , 2006 .

[566]  S. George,et al.  X-ray magnetic circular dichroism—a high energy probe of magnetic properties , 2005 .

[567]  B. Dobson,et al.  COMBINED QUEXAFS-XRD - A NEW TECHNIQUE IN HIGH-TEMPERATURE MATERIALS CHEMISTRY - AN ILLUSTRATIVE IN-SITU STUDY OF THE ZINC OXIDE-ENHANCED SOLID-STATE PRODUCTION OF CORDIERITE FROM A PRECURSOR ZEOLITE , 1993 .

[568]  Marc R. Knecht,et al.  Synthesis and Characterization of Pt Dendrimer-Encapsulated Nanoparticles: Effect of the Template on Nanoparticle Formation , 2008 .

[569]  M. Fernández-García,et al.  "Oxidationless" promotion of rapid palladium redispersion by oxygen during redox CO/(NO+O2) cycling. , 2007, Angewandte Chemie.

[570]  R. W. Joyner,et al.  The local structure of aluminium sites in zeolites , 2004 .

[571]  J. Grunwaldt,et al.  Visualizing a Catalyst at Work during the Ignition of the Catalytic Partial Oxidation of Methane , 2009 .

[572]  Randall Q. Snurr,et al.  Ultrahigh Porosity in Metal-Organic Frameworks , 2010, Science.

[573]  J. Long,et al.  Introduction to metal-organic frameworks. , 2012, Chemical reviews.

[574]  M. Nachtegaal,et al.  Dynamic Structure Changes of a Heterogeneous Catalyst within a Reactor: Oscillations in CO Oxidation over a Supported Platinum Catalyst , 2010 .

[575]  J. Haase Surface structure determinations using X-ray absorption spectroscopy , 1996 .

[576]  N. Takagi,et al.  In situ observation of platinum sintering on ceria-based oxide for autoexhaust catalysts using Turbo-XAS , 2011 .

[577]  C. Lamberti,et al.  Alumina-supported copper chloride: 3. Effect of exposure to ethylene , 2001 .

[578]  Ian D. Williams,et al.  A chemically functionalizable nanoporous material (Cu3(TMA)2(H2O)3)n , 1999 .

[579]  A. Cheetham,et al.  Adsorption of molecular hydrogen on coordinatively unsaturated Ni(II) sites in a nanoporous hybrid material. , 2006, Journal of the American Chemical Society.

[580]  John Meurig Thomas,et al.  Combined EXAFS and XRD for the in situ structural elucidation of solid catalysts under operating conditions , 1993 .

[581]  Grant Bunker Introduction to XAFS: Index , 2010 .

[582]  G. Bond Source of the activation energy in heterogeneously catalysed reactions , 1993 .

[583]  R. Greegor,et al.  Structure of bimetallic clusters. Extended x‐ray absorption fine structure (EXAFS) studies of Os–Cu clusters , 1981 .

[584]  C. Lamberti,et al.  Co-ordination and oxidation changes undergone by iron species in Fe-silicalite upon template removal, activation and interaction with N2O: an in situ X-ray absorption study , 2002 .

[585]  F. Heinrich,et al.  Fe–ZSM-5 Catalysts for the Selective Reduction of NO by Isobutane—The Problem of the Active Sites , 2002 .

[586]  F. Bonino,et al.  AM-6: a microporous one-dimensional ferromagnet. , 2009, Dalton transactions.

[587]  T. Shimada,et al.  Irreversible Change in the NO Adsorption State on Pt(111) under High Pressure Studied by AP-XPS, NEXAFS, and STM† , 2010 .

[588]  I. Ivanova,et al.  Ni-, Co-, Fe- and Zn-containing silicalites-1 in propane conversion , 2010 .

[589]  C. David,et al.  A von Hamos x-ray spectrometer based on a segmented-type diffraction crystal for single-shot x-ray emission spectroscopy and time-resolved resonant inelastic x-ray scattering studies. , 2012, The Review of scientific instruments.

[590]  G. Busca,et al.  Production of hydrogen from oxidative steam reforming of methanol: I. Preparation and characterization of Cu/ZnO/Al2O3 catalysts from a hydrotalcite-like LDH precursor , 2004 .

[591]  Chick C. Wilson,et al.  Structural investigation of TS-1: determination of the true nonrandom titanium framework substitution and silicon vacancy distribution from powder neutron diffraction studies using isotopes , 2001 .

[592]  R. Bal,et al.  Redox and catalytic chemistry of Ti in titanosilicate molecular sieves: an EPR investigation , 2000 .

[593]  C. Lamberti,et al.  On the fraction of CrII sites involved in the C2H4 polymerization on the Cr/SiO2 Phillips catalyst: a quantification by FTIR spectroscopy. , 2006, Physical chemistry chemical physics : PCCP.

[594]  A. Ankudinov,et al.  New developments in NEXAFS/EXAFS theory , 1998 .

[595]  B. Weckhuysen,et al.  Promotion effects in the oxidation of CO over zeolite-supported Pt nanoparticles. , 2005, The journal of physical chemistry. B.

[596]  C. Lamberti,et al.  Advanced X-ray absorption and emission spectroscopy: in situ catalytic studies. , 2010, Chemical Society reviews.

[597]  J. Smith,et al.  Silicalite, a new hydrophobic crystalline silica molecular sieve , 1978, Nature.

[598]  T. Shibata,et al.  Applying very high resolution microfocus X–ray CT and 3–D reconstruction to the human auditory apparatus , 1996, Nature Medicine.

[599]  A. Dent,et al.  Simultaneous Determination of Structural and Kinetic Parameters Characterizing the Interconversion of Highly Dispersed Species: the Interaction of NO with RhI(CO)2/γ-Al2O3 , 2001 .

[600]  R. Kronig Zur Theorie der Feinstruktur in den Röntgenabsorptionsspektren. III , 1932 .

[601]  A. Beale,et al.  Closing the operando gap: the application of high energy photons for studying catalytic solids at work , 2011 .

[602]  O. Shekhah,et al.  MOF thin films: existing and future applications. , 2011, Chemical Society reviews.

[603]  T. Ressler,et al.  Curved Crystal Transmission Optics for Energy-Dispersive X-ray Absorption Spectroscopy. , 1995, Journal of synchrotron radiation.

[604]  C. Lamberti,et al.  Quantum-size effects in the titanosilicate molecular sieve , 1997 .

[605]  J. Bokhoven,et al.  The interaction of aromatic molecules with the acid site in zeolite H-Beta as observed through a newly discovered Fano resonance at the Al K edge , 2001 .

[606]  C. Lamberti,et al.  Calorimetric and IR spectroscopic study of the interaction of NH3 with variously prepared defective silicalites: Comparison with ab initio computational data , 2002 .

[607]  A. Corma,et al.  Infrared spectroscopic investigation of titanium in zeolites. A new assignment of the 960 cm–1 band , 1993 .

[608]  R. Prins,et al.  Fe/ZSM-5 Prepared by Sublimation of FeCl3: The Structure of the Fe Species as Determined by IR, 27Al MAS NMR, and EXAFS Spectroscopy , 2000 .

[609]  Bartolomeo Civalleri,et al.  Disclosing the Complex Structure of UiO-66 Metal Organic Framework: A Synergic Combination of Experiment and Theory , 2011 .

[610]  D. Olson,et al.  Separation of hydrocarbons with a microporous metal-organic framework. , 2006, Angewandte Chemie.

[611]  K. Tsutsumi,et al.  Fine Structures of X-ray Absorption Spectra Of Cobalt in the Face Centered Cubic Lattice and Close-packed Hexagonal Lattice , 1957 .

[612]  B. Weckhuysen,et al.  Intergrowth structure of zeolite crystals as determined by optical and fluorescence microscopy of the template-removal process. , 2007, Angewandte Chemie.

[613]  M. Kurmoo Magnetic metal-organic frameworks. , 2009, Chemical Society reviews.

[614]  A. Dent Development of Time-Resolved XAFS Instrumentation for Quick EXAFS and Energy-Dispersive EXAFS Measurements on Catalyst Systems , 2002 .

[615]  B. Weckhuysen,et al.  New frontiers in X-ray spectroscopy in heterogeneous catalysis: Using Fe/ZSM-5 as test-system , 2005 .

[616]  A. Dent,et al.  Synchronous, time resolved, diffuse reflectance FT-IR, energy dispersive EXAFS (EDE) and mass spectrometric investigation of the behaviour of Rh catalysts during NO reduction by CO. , 2004, Chemical Communications.

[617]  Keiji Nakagawa,et al.  Rapid preparation of flexible porous coordination polymer nanocrystals with accelerated guest adsorption kinetics. , 2010, Nature chemistry.

[618]  P. Rangsunvigit,et al.  Phenol hydroxylation using Ti- and Sn-containing silicalitesElectronic supplementary information (ESI) available: XRD pattern of Ti?Sn?S-1s. See http://www.rsc.org/suppdata/cc/b3/b303455k/ , 2003 .

[619]  Ejm Emiel Hensen,et al.  Chemistry of N2O decomposition on active sites with different nature : Effect of high-temperature treatment of Fe/ZSM-5 , 2006 .

[620]  Bert M. Weckhuysen,et al.  Kβ-detected XANES of framework-substituted FeZSM-5 zeolites , 2004 .

[621]  C. Lamberti,et al.  Direct IR observation of vibrational properties of carbonyl species formed on Pd nano-particles supported on amorphous carbon: comparison with Pd/SiO2-Al2O3. , 2006, Physical chemistry chemical physics : PCCP.

[622]  E. Guillon,et al.  Co‐Adsorption of Copper(II) and 3‐Amino‐1,2,4‐triazole at a Water–Natural Macromolecular Compound Interface: Molecular Structure from Adsorption Isotherms Combined with X‐ray Absorption Measurements , 2005 .

[623]  R. Boehler High‐pressure experiments and the phase diagram of lower mantle and core materials , 2000 .

[624]  Koen Janssens,et al.  Synchrotron-based X-ray absorption spectroscopy for art conservation: looking back and looking forward. , 2010, Accounts of chemical research.

[625]  J. Hanson,et al.  Nanostructured oxides in chemistry: characterization and properties. , 2004, Chemical reviews.

[626]  G. Comelli,et al.  Adsorption and temperature-dependent decomposition of SO2 on Ni(110): an XPS and XAFS study , 1998 .

[627]  T. Stemmler,et al.  XAFS OF DINUCLEAR METAL SITES IN PROTEINS AND MODEL COMPOUNDS , 1995 .

[628]  W. O'grady,et al.  Understanding atomic x-ray absorption fine structure in x-ray absorption spectra , 1998 .

[629]  Craig M. Brown,et al.  Hydrogen storage and carbon dioxide capture in an iron-based sodalite-type metal–organic framework (Fe-BTT) discovered via high-throughput methods , 2010 .

[630]  P. Ratnasamy,et al.  Reactive Oxygen Species in Titanosilicates TS-1 and TiMCM-41: An In Situ EPR Spectroscopic Study , 2001 .

[631]  B. Weckhuysen,et al.  A three-site Langmuir adsorption model to elucidate the temperature, pressure, and support dependence of the hydrogen coverage on supported Pt particles , 2007 .

[632]  G. Lindsay Über die Feinstruktur in derK-Absorptionskante von Kalium , 1931 .

[633]  M. Newton Dynamic adsorbate/reaction induced structural change of supported metal nanoparticles: heterogeneous catalysis and beyond. , 2008, Chemical Society reviews.

[634]  J. Grunwaldt,et al.  X-ray absorption spectroscopy under reaction conditions: suitability of different reaction cells for combined catalyst characterization and time-resolved studies , 2004 .

[635]  J. Hazemann,et al.  Quantitative analysis of x-ray absorption near edge structure data by a full multiple scattering procedure: the Fe-CO geometry in photolyzed carbonmonoxy-myoglobin single crystal. , 2001, Physical review letters.

[636]  M. Bowker,et al.  The adsorption and decomposition of formic acid on Cu {110} , 1996 .

[637]  T. I. Morrison,et al.  Re-investigation of titanium silicalite by X-ray absorption spectroscopy: Are the novel titanium sites real? , 1993 .

[638]  F. Lytle,et al.  Structure of bimetallic clusters. Extended x-ray absorption fine structure (EXAFS) studies of Ru--Cu clusters , 1980 .

[639]  R. Sheldon,et al.  Oxidative Transformations of Organic Compounds Mediated by Redox Molecular Sieves , 1997 .

[640]  Paul T. Barger,et al.  The characteristics of SAPO-34 which influence the conversion of methanol to light olefins , 1999 .

[641]  J. Duraud,et al.  The initial stages of the growth of copper on a (1 × 1) and a (√31 × √31)R ± 9° α-Al2O3(0001) surface , 1996 .

[642]  Matthias Bauer,et al.  X-Ray absorption in homogeneous catalysis research: the iron-catalyzed Michael addition reaction by XAS, RIXS and multi-dimensional spectroscopy. , 2010, Physical chemistry chemical physics : PCCP.

[643]  M Newville,et al.  ATHENA, ARTEMIS, HEPHAESTUS: data analysis for X-ray absorption spectroscopy using IFEFFIT. , 2005, Journal of synchrotron radiation.

[644]  S J L Billinge,et al.  PDFfit2 and PDFgui: computer programs for studying nanostructure in crystals , 2007, Journal of physics. Condensed matter : an Institute of Physics journal.

[645]  B. Gates,et al.  GAMMA -AL2O3-SUPPORTED RE-PT CLUSTER CATALYST PREPARED FROM RE2PT(CO)12: CHARACTERIZATION BY EXTENDED X-RAY ABSORPTION FINE STRUCTURE SPECTROSCOPY AND CATALYSIS OF METHYLCYCLOHEXANE DEHYDROGENATION , 1997 .

[646]  D. Sayers,et al.  Dispersive XAS studies of the reduction kinetics of a highly dispersed supported catalyst , 1989 .

[647]  H. Fricke The K-Characteristic Absorption Frequencies for the Chemical Elements Magnesium to Chromium , 1920 .

[648]  Michael O'Keeffe,et al.  Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage , 2002, Science.

[649]  S. Chambers,et al.  Elastic scattering and interference of backscattered primary, Auger and X-ray photoelectrons at high kinetic energy: principles and applications , 1992 .

[650]  R. Schlögl,et al.  Characterisation of active phases of a copper catalyst for methanol oxidation under reaction conditions: an in situ X-ray absorption spectroscopy study in the soft energy range , 2001 .

[651]  Donald H. Bilderback,et al.  Review of capillary x-ray optics from the 2nd International Capillary Optics Meeting , 2003 .

[652]  P. Mantica,et al.  β-decay studies of neutron-rich nuclei , 2005 .

[653]  C. Lamberti,et al.  Effect of Ti insertion in the silicalite framework on the vibrational modes of the structure: an ab initio, and vibrational study , 2001 .

[654]  C. Arean,et al.  Vibrational and optical spectroscopic studies on copper-exchanged ferrierite , 2002 .

[655]  A. Corma,et al.  New Aluminosilicate and Titanosilicate Delaminated Materials Active for Acid Catalysis, and Oxidation Reactions Using H2O2 , 2000 .

[656]  V. Prasad,et al.  Correlating particle size and shape of supported Ru/gamma-Al2O3 catalysts with NH3 decomposition activity. , 2009, Journal of the American Chemical Society.

[657]  A. Jess,et al.  Pt@MOF-177: synthesis, room-temperature hydrogen storage and oxidation catalysis. , 2008, Chemistry.

[658]  C. Lamberti,et al.  Direct Evidence of Highly Dispersed Iron in Fe–silicalite: A Raman Spectroscopic Study , 2011 .

[659]  D. P. Woodruff,et al.  Adsorbate structure determination on surfaces using photoelectron diffraction , 1994 .

[660]  G. Bellussi,et al.  Synthesis of propylene oxide from propylene and hydrogen peroxide catalyzed by titanium silicalite , 1991 .

[661]  B. Rieger,et al.  Composition optimization of silica-supported copper (II) chloride substance for phosgene production , 2009 .

[662]  R. Morris,et al.  Induction of chiral porous solids containing only achiral building blocks. , 2010, Nature chemistry.

[663]  B. Weckhuysen,et al.  The siting of Cu(II) in mordenite: a theoretical spectroscopic study , 2002 .

[664]  M. Harada,et al.  Atomic XAFS for a bromide ion bound on anion-exchange resin in water. , 2001, Analytical sciences : the international journal of the Japan Society for Analytical Chemistry.

[665]  H. Ebert Magneto-optical effects in transition metal systems , 1996 .

[666]  T. Schedel-Niedrig,et al.  High-pressure soft X-ray absorption spectroscopy: application of a new in situ spectroscopic method in catalysis research , 1999 .

[667]  A. Ankudinov,et al.  Pt L-edge XANES as a probe of Pt clusters. , 2001, Journal of synchrotron radiation.

[668]  C. Lamberti Electron-hole reduced effective mass in monoatomic ...-O-Ti-O-Ti-O-... quantum wires embedded in the siliceous crystalline matrix of ETS-10 , 1999 .

[669]  H. Petersen Zur Theorie der Röntgenabsorption molekularer Gase , 1932 .

[670]  D. P. Woodruff,et al.  A structural study of the interaction of SO2 with Cu(111) , 2000 .

[671]  M. Hay,et al.  X-ray absorption spectroscopy of aqueous aluminum-organic complexes. , 2010, The journal of physical chemistry. A.

[672]  D. Doren,et al.  Photocatalytic Activity of Vanadium-Substituted ETS-10 , 2007 .

[673]  A. Soldatov,et al.  Quantitative local structure refinement from XANES: multi-dimensional interpolation approach. , 2006, Journal of synchrotron radiation.

[674]  A. Bell,et al.  An in situ Al K-edge XAS investigation of the local environment of H+- and Cu+-exchanged USY and ZSM-5 zeolites. , 2006, The journal of physical chemistry. B.

[675]  R. Prins,et al.  X-ray absorption investigations on Ti-containing zeolites , 1992 .

[676]  R. Benfield Mean coordination numbers and the non-metal–metal transition in clusters , 1992 .

[677]  B. Weckhuysen,et al.  Infrared and Raman imaging of heterogeneous catalysts. , 2010, Chemical Society reviews.

[678]  G. Thornton,et al.  Structure of Atomic and Molecular Adsorbates on Low-Miller-Index ZnO Surfaces Using X-ray Absorption Spectroscopy , 2002 .

[679]  John B. Pendry,et al.  Theory of the extended x-ray absorption fine structure , 1975 .

[680]  C. Lamberti,et al.  Local structure of Pr3+ in fluorozirconate glasses , 1999 .

[681]  Unni Olsbye,et al.  Space- and time-resolved in-situ spectroscopy on the coke formation in molecular sieves: methanol-to-olefin conversion over H-ZSM-5 and H-SAPO-34. , 2008, Chemistry.

[682]  G. Mickelson,et al.  Simple flow through reaction cells for in situ transmission and fluorescence x-ray-absorption spectroscopy of heterogeneous catalysts , 2006 .

[683]  X. D. Wang,et al.  Synthesis of b‐Oriented TS‐1 Films on Chitosan‐Modified α‐Al2O3 Substrates , 2006 .

[684]  Seda Keskin,et al.  Can metal-organic framework materials play a useful role in large-scale carbon dioxide separations? , 2010, ChemSusChem.

[685]  R. Kumar,et al.  Catalytic properties of crystalline titanium silicalites. II, Hydroxylation of phenol with hydrogen peroxide over TS-1 zeolites , 1991 .

[686]  V. Aksenov,et al.  Development of methods of EXAFS spectroscopy on synchrotron radiation beams: Review , 2006 .

[687]  Richard Blom,et al.  Application of metal–organic frameworks with coordinatively unsaturated metal sites in storage and separation of methane and carbon dioxide , 2009 .

[688]  R. Bagatin,et al.  Selective oxidations with hydrogen peroxide and titanium silicalite catalyst , 1999 .

[689]  Mehl,et al.  Angular momentum branching ratios for electron-induced ionization: Atomic and model calculations. , 1987, Physical review. B, Condensed matter.

[690]  A. Proctor,et al.  Quantitative analysis of mixed oxidation states in supported catalysts , 1994 .

[691]  P. Battle,et al.  Study of the Iron-phosphorus-oxygen System by Mössbauer Effect, Neutron Diffraction, Magnetic Susceptibility, and Analytical Electron Microscopy: Some Pitfalls and Solutions in the Analysis of a Complex Mixture , 1983 .

[692]  V. Parmon,et al.  In situ MRI of the structure and function of multiphase catalytic reactors , 2005 .

[693]  Adriano Zecchina,et al.  Probing the surfaces of heterogeneous catalysts by in situ IR spectroscopy. , 2010, Chemical Society reviews.

[694]  H. Hayashi SIM‐RIXS: a program to simulate resonant inelastic X‐ray scattering , 2011 .

[695]  F. Geobaldo,et al.  DRS UV-Vis and EPR spectroscopy of hydroperoxo and superoxo complexes in titanium silicalite , 1992 .

[696]  D. E. Keller,et al.  Combining operando techniques in one spectroscopic-reaction cell: New opportunities for elucidating the active site and related reaction mechanism in catalysis , 2006 .

[697]  V. Parmon,et al.  Iron complexes in zeolites as a new model of methane monooxygenase , 1997 .

[698]  R. Theissmann,et al.  X-ray absorption studies on alloy formation in different carbon-supported Pt–Ru electrocatalysts , 2004 .

[699]  B. Weckhuysen,et al.  In Situ X-ray Absorption of Co/Mn/TiO2 Catalysts for Fischer−Tropsch Synthesis , 2004 .

[700]  W. O'grady,et al.  Determination of H Adsorption Sites on Pt/C Electrodes in HClO4 from Pt L23 X-ray Absorption Spectroscopy , 2004 .

[701]  D. Nachtigallová,et al.  Nature of the Cu+-NO bond in the gas phase and at different types of Cu+ sites in zeolite catalysts , 2004 .

[702]  Jean-François Méhaut,et al.  High Performance Computing / Le Calcul Intensif Daubechies wavelets for high performance electronic structure calculations: The BigDFT project , 2011 .

[703]  M. Chergui,et al.  Structural analysis of ultrafast extended x-ray absorption fine structure with subpicometer spatial resolution: application to spin crossover complexes. , 2009, The Journal of chemical physics.

[704]  J. Bokhoven,et al.  Evolution of Fe species during the synthesis of over-exchanged Fe/ZSM5 obtained by chemical vapor deposition of FeCl3 , 2003 .

[705]  B. Dobson,et al.  Quick Fluorescence XAFS: A Technique for Recording Fluorescence X-ray Absorption Spectra during Chemical/Biochemical Reactions , 1993 .

[706]  Gordon E. Brown,et al.  Coordination chemistry of Ti(IV) in silicate glasses and melts: I. XAFS study of titanium coordination in oxide model compounds , 1996 .

[707]  Mathieu Taillefumier,et al.  X-ray absorption near-edge structure calculations with the pseudopotentials: Application to the K edge in diamond and α-quartz , 2002 .

[708]  K. Klementev Extraction of the fine structure from x-ray absorption spectra , 2001 .

[709]  C. Jacobsen,et al.  Catalytic epoxidation of alkenes with hydrogen peroxide over first mesoporous titanium-containing zeolite , 2000 .

[710]  R. Kumar,et al.  Reactive oxo-titanium species in titanosilicate molecular sieves: EPR investigations and structure–activity correlations , 2003 .

[711]  A. Corma,et al.  MOFs as catalysts: Activity, reusability and shape-selectivity of a Pd-containing MOF , 2007 .

[712]  J. Bokhoven,et al.  Nature of ≡SiOCrO2Cl and (≡SiO)2CrO2 Sites Prepared by Grafting CrO2Cl2 onto Silica , 2008 .

[713]  T. Schildhauer,et al.  Quantitative Analysis of Modulated Excitation X-ray Absorption Spectra: Enhanced Precision of EXAFS Fitting , 2012 .

[714]  A. Corma,et al.  Cu and Au metal-organic frameworks bridge the gap between homogeneous and heterogeneous catalysts for alkene cyclopropanation reactions. , 2010, Chemistry.

[715]  G. Vayssilov Structural and Physicochemical Features of Titanium Silicalites , 1997 .

[716]  T. Yokoyama,et al.  Temperature dependence of EXAFS spectra of supported small metal particles , 1991 .

[717]  R. Sanz,et al.  Turning TS-1 zeolite into a highly active catalyst for olefin epoxidation with organic hydroperoxides. , 2009, Chemical communications.

[718]  F. d’Acapito,et al.  Do we have a probe for the initial stages of solid state reactions , 2003 .

[719]  C. Lamberti,et al.  Vibrational properties of Cr(II) centers on reduced Phillips catalysts highlighted by resonant Raman spectroscopy. , 2006, Chemphyschem : a European journal of chemical physics and physical chemistry.

[720]  R. Vedrinskii,et al.  Multiple Scattering Approach to the XANES Theory of Alkali Halide Crystals , 1986, March 1.

[721]  B. Dobson,et al.  Quick Fluorescence-EXAFS: an Improved Method for Collection of Conventional XAFS Data, an Improved Method for Collection of Conventional XAFS Data and for Studying Reaction Intermediates in Dilute Systems. , 1995, Journal of synchrotron radiation.

[722]  G. Mul,et al.  Characterization of Fe sites in Fe-zeolites by FTIR spectroscopy of adsorbed NO: are the spectra obtained in static vacuum and dynamic flow set-ups comparable? , 2010, Physical chemistry chemical physics : PCCP.

[723]  Bruce Ravel,et al.  The UWXAFS analysis package : philosophy and details , 1995 .

[724]  Omar K Farha,et al.  Rational design, synthesis, purification, and activation of metal-organic framework materials. , 2010, Accounts of chemical research.

[725]  A. Bell,et al.  An Infrared Study of NO Decomposition over Cu-ZSM-5 , 1995 .

[726]  John Meurig Thomas,et al.  In situ combined X‐ray absorption spectroscopic and X‐ray diffractometric studies of solid catalysts , 1999 .

[727]  C. Lamberti,et al.  Effect of reduction in liquid phase on the properties and the catalytic activity of Pd/Al2O3 catalysts , 2012 .

[728]  J. Lunsford,et al.  Silica-supported chromium catalysts for ethylene polymerization , 1985 .

[729]  C. Lamberti,et al.  Ti-Peroxo Species in the TS-1/H2O2/H2O System , 2004 .

[730]  Jinghua Guo,et al.  Electronic structure of phospho-olivines Li(x)FePO4 (x = 0, 1) from soft-x-ray-absorption and -emission spectroscopies. , 2005, The Journal of chemical physics.

[731]  Guy Jennings,et al.  Determining Quantitative Kinetics and the Structural Mechanism for Particle Growth in Porous Templates , 2011 .

[732]  K. Xie,et al.  Studies of the interaction between CuCl and HY zeolite for preparing heterogeneous CuI catalyst , 2001 .

[733]  C. Lamberti,et al.  The role of Al in the structure and reactivity of iron centers in Fe-ZSM-5-based catalysts: a statistically based infrared study , 2003 .

[734]  Lothar Mussmann,et al.  Influence of NO2 on the selective catalytic reduction of NO with ammonia over Fe-ZSM5 , 2006 .

[735]  G. Ricchiardi,et al.  The effect of hydration on structure and location of Ti-sites in Ti-silicalite catalysts. A computational study , 2000 .

[736]  Xiaoyi Zhang,et al.  X-ray snapshots for metalloporphyrin axial ligation , 2010 .

[737]  C. Lamberti,et al.  Influence of additives in defining the active phase of the ethylene oxychlorination catalyst. , 2010, Physical chemistry chemical physics : PCCP.

[738]  Anatoly I. Frenkel,et al.  Combining X-ray Absorption and X-ray Diffraction Techniques for in Situ Studies of Chemical Transformations in Heterogeneous Catalysis: Advantages and Limitations , 2011 .

[739]  M. Hirscher,et al.  Hydrogen adsorption in a nickel based coordination polymer with open metal sites in the cylindrical cavities of the desolvated framework. , 2006, Chemical communications.

[740]  A. Corma,et al.  Characterization and Catalytic Activity of MCM-22 and MCM-56 Compared with ITQ-2 , 2000 .

[741]  S. Oyama,et al.  Mechanistic study of propane selective oxidation with H2 and O2 on Au/TS-1 , 2008 .

[742]  G. Spoto,et al.  Silicalite characterization. 2. IR spectroscopy of the interaction of carbon monoxide with internal and external hydroxyl groups , 1992 .

[743]  Irina Snigireva,et al.  Imaging by parabolic refractive lenses in the hard X-ray range , 1999 .

[744]  F. D. Groot,et al.  High-Resolution X-ray Emission and X-ray Absorption Spectroscopy , 2001 .

[745]  C. Lamberti,et al.  Structure and redox activity of copper sites isolated in a nanoporous P4VP polymeric matrix. , 2008, Angewandte Chemie.

[746]  O. Terasaki,et al.  Delamination of Ti-MWW and High Efficiency in Epoxidation of Alkenes with Various Molecular Sizes , 2004 .

[747]  C. Pinel,et al.  Solvent free base catalysis and transesterification over basic functionalised Metal-Organic Frameworks , 2009 .

[748]  J. Moulijn,et al.  Comparison of the Performance of Activated Carbon-Supported Noble Metal Catalysts in the Hydrogenolysis of CCl2F2☆ , 1998 .

[749]  Pio Forzatti,et al.  Higher Alcohol Synthesis , 1991 .

[750]  C. Lamberti,et al.  Mono-, Di-, and Tricarbonylic Species in Copper(I)-Exchanged Zeolite ZSM-5: Comparison with Homogeneous Copper(I) Carbonylic Structures , 1999 .

[751]  A. Marcelli,et al.  Three particle correlation function of metal ions in tetrahedral coordination determined by XANES , 1986 .

[752]  G Giuli,et al.  Sulfur-metal orbital hybridization in sulfur-bearing compounds studied by X-ray emission spectroscopy. , 2010, Inorganic chemistry.

[753]  P. Sadler,et al.  X-ray transient absorption structural characterization of the 3MLCT triplet excited state of cis-[Ru(bpy)2(py)2]2+. , 2013, Dalton transactions.

[754]  R. D. Shannon,et al.  Properties of boron-substituted ZSM-5 and ZSM-11 zeolites , 1987 .

[755]  B. Gates,et al.  EXAFS characterization of supported metal-complex and metal-cluster catalysts made from organometallic precursors , 2000 .

[756]  K. Wilson,et al.  Evidence for the surface-catalyzed Suzuki-Miyaura reaction over palladium nanoparticles: an operando XAS study. , 2010, Angewandte Chemie.

[757]  M Newville,et al.  EXAFS analysis using FEFF and FEFFIT. , 2001, Journal of synchrotron radiation.

[758]  Chen,et al.  Soft-x-ray magnetic circular dichroism at the L2,3 edges of nickel. , 1990, Physical review. B, Condensed matter.

[759]  B. Weckhuysen,et al.  Diffuse reflectance spectroscopy study of the thermal genesis and molecular structure of chromium-supported catalysts , 1994 .

[760]  C. Catlow,et al.  The Three-Dimensional Structure of the Titanium-Centered Active Site during Steady-State Catalytic Epoxidation of Alkenes , 2001 .

[761]  Bedzyk,et al.  Electrical Double-Layer Structure at the Rutile-Water Interface as Observed in Situ with Small-Period X-Ray Standing Waves. , 2000, Journal of colloid and interface science.

[762]  K. Tsutsumi,et al.  Fine Structures of X-ray K Absorption Spectra of Copper in Various Copper Compounds , 1957 .

[763]  J. Rehr,et al.  Theoretical approaches to x-ray absorption fine structure , 2000 .

[764]  B. Weckhuysen,et al.  COMBINED DRS-RS-EXAFS-XANES-TPR STUDY OF SUPPORTED CHROMIUM CATALYSTS , 1995 .

[765]  Freek Kapteijn,et al.  Cobalt particle size effects in the Fischer-Tropsch reaction studied with carbon nanofiber supported catalysts. , 2006, Journal of the American Chemical Society.

[766]  K. Wilson,et al.  Reaction-driven surface restructuring and selectivity control in allylic alcohol catalytic aerobic oxidation over Pd. , 2011, Journal of the American Chemical Society.

[767]  R. Prins,et al.  Preparation of Overexchanged Fe–ZSM-5 Zeolites Using the Ferrous Oxalate Method: Why Does It Fail? , 2000 .

[768]  C. Lamberti,et al.  Coordination and oxidation changes undergone by iron species in Fe-MCM-22 upon template removal, activation and red–ox treatments: an in situ IR, EXAFS and XANES study , 2005 .

[769]  G. E. van Dorssen,et al.  An atomic X-ray absorption fine structure study of the influence of hydrogen chemisorption and support on the electronic structure of supported Pt particles , 2000 .

[770]  J. V. van Bokhoven,et al.  Design and construction on an in situ cell for catalytic studies on elements with 12 < Z < 20. , 1999, Journal of synchrotron radiation.

[771]  C. Lamberti,et al.  LOW-TEMPERATURE FOURIER TRANSFORM INFRARED STUDY OF THE INTERACTION OF CO WITH CATIONS IN ALKALI-METAL EXCHANGED ZSM-5 ZEOLITES , 1994 .

[772]  M. Sierka,et al.  Coordination and siting of Cu+ ions in ZSM-5: A combined quantum mechanics/interatomic potential function study , 1999 .

[773]  D. Norman REVIEW ARTICLE: X-ray absorption spectroscopy (EXAFS and XANES) at surfaces , 1986 .

[774]  A. Yaresko,et al.  Band-structure theory of dichroism , 2006 .

[775]  D. Hartree,et al.  A theoretical calculation of the fine structure for the K-absorption band of Ge in GeCl4 , 1934 .

[776]  David Fischer,et al.  Stereospecific Olefin Polymerization with Chiral Metallocene Catalysts , 1995 .

[777]  J. Rehr,et al.  High-order multiple-scattering calculations of x-ray-absorption fine structure. , 1992, Physical review letters.

[778]  J. Tarascon,et al.  In situ Fe XAFS of reversible lithium insertion in a flexible metal organic framework material , 2009 .

[779]  Guy Jennings,et al.  MLCT state structure and dynamics of a copper(I) diimine complex characterized by pump-probe X-ray and laser spectroscopies and DFT calculations. , 2003, Journal of the American Chemical Society.

[780]  S. Bourgeois,et al.  A surface EXAFS study of thin nickel deposits on (110) TiO2 surfaces , 1997 .

[781]  O. Kitao,et al.  Characterization of the VS-1 catalyst using various spectroscopic techniques and its unique photocatalytic reactivity for the decomposition of NO in the absence and presence of C3H8 , 2001 .

[782]  Collins,et al.  Top-site adsorption for K on Cu(111) and Ni(111) surfaces. , 1993, Physical review. B, Condensed matter.

[783]  R. Crooks,et al.  X-ray Absorption Study of PdCu Bimetallic Alloy Nanoparticles Containing an Average of ∼64 Atoms , 2009 .

[784]  C. Lamberti,et al.  Influence of K-doping on a Pd/SiO2-Al2O3 catalyst , 2009 .

[785]  Pascal Granger,et al.  Catalytic NO(x) abatement systems for mobile sources: from three-way to lean burn after-treatment technologies. , 2011, Chemical reviews.

[786]  B. Weckhuysen,et al.  The Catalytic Conversion of Thiophenes over Large H‐ZSM‐5 Crystals: An X‐Ray, UV/Vis, and Fluorescence Microspectroscopic Study , 2010 .

[787]  M. Anpo,et al.  Effect of the addition of propane and distortion of tetrahedral vanadium(V) species in VSiβ zeolites on the photodecomposition of NO , 2003 .

[788]  R. Prins,et al.  On determining the nuclearity of iron sites in Fe-ZSM-5--a critical evaluation. , 2006, Physical chemistry chemical physics : PCCP.

[789]  M. White,et al.  A synthetically useful, self-assembling MMO mimic system for catalytic alkene epoxidation with aqueous H2O2. , 2001, Journal of the American Chemical Society.

[790]  D. Murzin,et al.  Isomerization of linoleic acid over supported metal catalysts , 2003 .

[791]  In situ characterization of supported metal catalysts and model surfaces by time-resolved and three-dimensional XAFS techniques , 2003 .

[792]  D. P. Woodruff,et al.  Structural aspects of the interaction of methyl thiol and dimethyldisulphide with Ni(111) , 1995 .

[793]  A. Kotani Resonant inelastic X-ray scattering in d and f electron systems , 2005 .

[794]  R. Dovesi,et al.  Titanium-Containing Zeolites. A Periodic ab Initio Hartree−Fock Characterization , 1998 .

[795]  R. Nuzzo,et al.  Structural Characterization of Carbon-Supported Platinum−Ruthenium Nanoparticles from the Molecular Cluster Precursor PtRu5C(CO)16 , 1997 .

[796]  Natoli,et al.  Use of general potentials in multiple-scattering theory. , 1986, Physical review. A, General physics.

[797]  Q. Zhu,et al.  Effect of high-temperature treatment on Fe/ZSM-5 prepared by chemical vapor deposition of FeCl3: I. Physicochemical characterization , 2004 .

[798]  C. Serre,et al.  Why hybrid porous solids capture greenhouse gases? , 2011, Chemical Society reviews.

[799]  Wenbin Lin,et al.  Chiral porous coordination networks: rational design and applications in enantioselective processes , 2003 .

[800]  K. K. Hii,et al.  In situ investigation of the oxidative addition in homogeneous Pd catalysts by synchronised time resolved UV-Vis/EXAFS. , 2006, Chemical communications.

[801]  A. Cheetham,et al.  On the Nature of Nonframework Cations in a Zeolitic deNOx Catalyst: Cu-Mordenite , 1997 .

[802]  Anthony K. Cheetham,et al.  Hybrid Inorganic–Organic Solids: An Emerging Class of Nanoporous Catalysts , 2003 .

[803]  J. Lercher,et al.  Adsorption of SO2 on Ba impregnated metal organic framework materials , 2005 .

[804]  J. Spivey,et al.  Heterogeneous catalytic synthesis of ethanol from biomass-derived syngas. , 2007, Chemical Society reviews.

[805]  Anatoly I. Frenkel,et al.  Solving the 3D structure of metal nanoparticles , 2007 .

[806]  N. Mott,et al.  CXVI. The interpretation of X-ray absorption spectra of solids , 1949 .

[807]  C. D. Collier,et al.  Metal-organic framework from an anthracene derivative containing nanoscopic cages exhibiting high methane uptake. , 2008, Journal of the American Chemical Society.

[808]  M. Chergui,et al.  Exploiting EXAFS and XANES for time-resolved molecular structures in liquids , 2008 .

[809]  Arturo Martínez-Arias,et al.  Dynamic in situ observation of rapid size and shape change of supported Pd nanoparticles during CO/NO cycling. , 2007, Nature materials.

[810]  S. Tolbert,et al.  High-pressure structural transformations in semiconductor nanocrystals. , 1995, Annual review of physical chemistry.

[811]  A. Lamberti,et al.  Interaction of CD3CN and pyridine with the Ti(IV) centers of TS-1 catalysts: a spectroscopic and computational study , 2003 .

[812]  Abraham M. Shultz,et al.  A catalytically active, permanently microporous MOF with metalloporphyrin struts. , 2009, Journal of the American Chemical Society.

[813]  Structural Characterization of Multi‐Quantum Wells in Electroabsorption‐Modulated Lasers by using Synchrotron Radiation Micrometer‐Beams , 2010, Advanced materials.

[814]  C. Natoli,et al.  The MXAN procedure: a new method for analysing the XANES spectra of metalloproteins to obtain structural quantitative information. , 2003, Journal of synchrotron radiation.

[815]  Adriano Filipponi,et al.  The radial distribution function probed by X-ray absorption spectroscopy , 1994 .

[816]  J. Robert,et al.  Titanium valence and coordination in synthetic richterite -Ti-richterite amphiboles. A synchrotron-radiation XAS study , 1993 .

[817]  G. Bellussi,et al.  Amorphous mesoporous silica-alumina with controlled pore size as acid catalysts , 1994 .

[818]  G. Deo,et al.  Characterization of titania silicalites , 1993 .

[819]  R. A. Santen,et al.  On the role of aluminum in the selective oxidation of benzene to phenol by nitrous oxide over iron-containing MFI zeolites: an in situ Fe XANES study , 2004 .

[820]  T. Nenoff,et al.  Radioactive iodine capture in silver-containing mordenites through nanoscale silver iodide formation. , 2010, Journal of the American Chemical Society.

[821]  P. Mériaudeau,et al.  The role of Ga2O3 and proton acidity on the dehydrogenating activity of Ga2O3-HZSM-5 catalysts: evidence of a bifunctional mechanism , 1990 .

[822]  D. Coster Über die Absorptionsspektren im Röntgengebiet , 1924 .

[823]  G. Calzaferri,et al.  The electronic structure of Cu+, Ag+, and Au+ zeolites. , 2003, Chemical Society reviews.

[824]  B. Gates,et al.  Low‐cost, heated, and/or cooled flow‐through cell for transmission x‐ray absorption spectroscopy , 1996 .

[825]  Y. Nishino,et al.  Holographies and EXAFS in quantum electrodynamics , 1999 .

[826]  G. Bellussi,et al.  Stability of Ti in MFI and Beta structures: a comparative study , 1999 .

[827]  K. Hungerbühler,et al.  HERFD XAS/ATR-FTIR batch reactor cell. , 2012, Physical chemistry chemical physics : PCCP.

[828]  Brian H. Toby,et al.  Crystal Structure of Dehydrated CsZSM-5 (5.8Al): Evidence for Nonrandom Aluminum Distribution† , 2000 .

[829]  Glenn J. Sunley,et al.  Detailed structural investigation of the grafting of [Ta(=CHtBu)(CH2tBu)3] and [Cp*TaMe4] on silica partially dehydroxylated at 700 degrees C and the activity of the grafted complexes toward alkane metathesis. , 2004, Journal of the American Chemical Society.

[830]  F. d’Acapito,et al.  Structure of Homoleptic CuI(CO)3 Cations in CuI-Exchanged ZSM-5 Zeolite: An X-ray Absorption Study , 2000 .

[831]  P. Chupas,et al.  3-D Structure of Nanosized Catalysts by High-Energy X-ray Diffraction and Reverse Monte Carlo Simulations: Study of Ru , 2007 .

[832]  B. Wichterlová,et al.  Siting and Redox Behavior of Cu Ions in CuH-ZSM-5 Zeolites. Cu+ Photoluminescence Study , 1994 .

[833]  A. Ankudinov,et al.  New developments in the theory and interpretation of X-ray spectra based on fast parallel calculations. , 2003, Journal of synchrotron radiation.

[834]  S. Dahl,et al.  The role of monomeric iron during the selective catalytic reduction of NOx by NH3 over Fe-BEA zeolite catalysts , 2009 .

[835]  J. Nørskov,et al.  Asymmetric pair distribution functions in catalysts , 2000 .

[836]  Craig M. Brown,et al.  Neutron powder diffraction study of D2 sorption in Cu3(1,3,5-benzenetricarboxylate)2. , 2006, Journal of the American Chemical Society.

[837]  C. H. Shaw Secondary Structure in the K Absorption Limit of Germanium Tetrachloride , 1946 .

[838]  F. Rey,et al.  Heterogeneous catalysts obtained by grafting metallocene complexes onto mesoporous silica , 1995, Nature.

[839]  Bert M. Weckhuysen,et al.  Local Environment and Nature of Cu Active Sites in Zeolite-Based Catalysts for the Selective Catalytic Reduction of NOx , 2013 .

[840]  E. Stern,et al.  Development of the EXELFS technique for high accuracy structural information , 1995 .

[841]  W. Stenström Experimentelle Untersuchungen der Röntgenspektra. M‐Reihe , 1918 .

[842]  S. Davis,et al.  The effect of surface oxygen on hydrocarbon reactions catalyzed by platinum crystal surfaces with variable kink concentrations , 1980 .

[843]  E. Stern,et al.  Analysis of multiple-scattering XAFS data using theoretical standards , 1995 .

[844]  B. D. Ray Mehrfachabsorption und sekundäreK-Absorptionsgrenze im Röntgengebiet , 1929 .

[845]  K. Tsutsumi,et al.  On the Fine Structures of X-ray Absorption Spectra of Amorphous Substances The Amorphous State of the Binary System of Nickel-Sulfur. II. , 1955 .

[846]  K. Tamaki,et al.  Size-selective Lewis acid catalysis in a microporous metal-organic framework with exposed Mn2+ coordination sites. , 2008, Journal of the American Chemical Society.

[847]  C. Lamberti,et al.  Resonance Raman effects in TS-1: the structure of Ti(IV) species and reactivity towards H2O, NH3 and H2O2: an in situ study , 2003 .

[848]  C. Ramsauer,et al.  Über den Wirkungsquerschnitt der Gasmoleküle gegenüber langsamen Elektronen , 1921 .

[849]  M. Kumar,et al.  Reduction of N2O with CO over FeMFI zeolites: influence of the preparation method on the iron species and catalytic behavior , 2004 .

[850]  A. Bell,et al.  Investigations of the State of Fe in H–ZSM-5 , 1999 .

[851]  A. Stein Advances in Microporous and Mesoporous Solids—Highlights of Recent Progress , 2003 .

[852]  Olivier Mathon,et al.  Advances in high brilliance energy dispersive X-ray absorption spectroscopy. , 2010, Physical chemistry chemical physics : PCCP.

[853]  M. Di Michiel,et al.  Nanoparticulate Pd supported catalysts: size-dependent formation of Pd(I)/Pd(0) and their role in CO elimination. , 2011, Journal of the American Chemical Society.

[854]  J. Hanson,et al.  Quick extended x-ray absorption fine structure instrument with millisecond time scale, optimized for in situ applications. , 2010, The Review of scientific instruments.

[855]  H. Dalton,et al.  Steady-state kinetic analysis of soluble methane mono-oxygenase from Methylococcus capsulatus (Bath). , 1986, The Biochemical journal.

[856]  S. Oyama,et al.  Enhanced reactivity of direct propylene epoxidation with H2 and O2 over Ge-modified Au/TS-1 catalysts , 2009 .

[857]  N. Toshima,et al.  Preparation of Pd−Pt Bimetallic Colloids with Controllable Core/Shell Structures , 1997 .

[858]  M. Balasubramanian,et al.  Efficient simultaneous reverse Monte Carlo modeling of pair-distribution functions and extended x-ray-absorption fine structure spectra of crystalline disordered materials. , 2012, The Journal of chemical physics.

[859]  C. Lamberti,et al.  Reactivity of Ti(IV) species hosted in TS-1 towards H2O2-H2O solutions investigated by ab initio cluster and periodic approaches combined with experimental XANES and EXAFS data: a review and new highlights. , 2007, Physical chemistry chemical physics : PCCP.

[860]  R. Prins,et al.  Origin of the cluster-size effect in the hydrogenation of cinnamaldehyde over supported Au catalysts , 2007 .

[861]  F. d’Acapito,et al.  Determination of the oxidation and coordination state of copper on different Cu-based catalysts by XANES spectroscopy in situ or in operando conditionsPresented at the International Congress on Operando Spectroscopy, Lunteren, The Netherlands, March 2?6, 2003. , 2003 .

[862]  A. Beale,et al.  A Combined Multi-Technique In Situ Approach Used to Probe the Stability of Iron Molybdate Catalysts During Redox Cycling , 2009 .

[863]  Stefan Goedecker,et al.  ABINIT: First-principles approach to material and nanosystem properties , 2009, Comput. Phys. Commun..

[864]  C. Lamberti,et al.  Response of CPO-27-Ni towards CO, N2 and C2H4. , 2009, Physical chemistry chemical physics : PCCP.

[865]  G. Spoto,et al.  Low-temperature Fourier-transform infrared investigation of the interaction of CO with nanosized ZSM5 and silicalite , 1992 .

[866]  Carlo Lamberti,et al.  0.5 wt.% Pd/C catalyst for purification of terephthalic acid: Irreversible deactivation in industrial plants , 2011 .

[867]  A. Kentgens,et al.  Determination of gallium in H(Ga)ZSM5 zeolites by 71Ga MAS NMR spectroscopy , 1992 .

[868]  F. Cavani,et al.  A rationale of the Baeyer-Villiger oxidation of cyclohexanone to ε-caprolactone with hydrogen peroxide: unprecedented evidence for a radical mechanism controlling reactivity. , 2010, Chemistry.

[869]  G. Benedek,et al.  Measurement of the p to s wave branching ratio of 187Re beta decay from beta environmental fine structure. , 2006, Physical review letters.

[870]  M. Anpo,et al.  The interaction of NO with copper ions in ZSM5 : an EPR and IR investigation , 1992 .

[871]  M. Denecke Actinide speciation using X-ray absorption fine structure spectroscopy , 2006 .

[872]  C. Lamberti,et al.  On the first stages of the ethylene polymerization on Cr2+/SiO2 Phillips catalyst: time and temperature resolved IR studies , 2003 .

[873]  C. Catlow,et al.  Computational and EXAFS Study of the Nature of the Ti(IV) Active Sites in Mesoporous Titanosilicate Catalysts , 1997 .

[874]  A. Fletcher,et al.  High-capacity hydrogen and nitric oxide adsorption and storage in a metal-organic framework. , 2007, Journal of the American Chemical Society.

[875]  C. Lamberti,et al.  An in situ temperature dependent IR, EPR and high resolution XANES study on the No/Cu+-ZSM-5 interaction , 2002 .

[876]  Alfonso San-Miguel A program for fast classic or dispersive XAS data analysis in a PC , 1995 .

[877]  M. Clerici The role of the solvent in TS-1 chemistry: active or passive? An early study revisited , 2001 .

[878]  Alexis T. Bell,et al.  Density Functional Theory Study of Nitrous Oxide Decomposition over Fe- and Co-ZSM-5 , 2002 .

[879]  A. Chakraborty,et al.  Density Functional Theory Investigations of the Direct Oxidation of Methane on an Fe-Exchanged Zeolite , 2004 .

[880]  L. Glasser,et al.  Crystal structures with a chabazite framework. II. Hydrated Ca-chabazite at room temperature , 1963 .

[881]  Hyunuk Kim,et al.  Metathesis in single crystal: complete and reversible exchange of metal ions constituting the frameworks of metal-organic frameworks. , 2009, Journal of the American Chemical Society.

[882]  J. Rehr Recent Developments in Multiple-Scattering Calculations of XAFS and XANES , 1993 .

[883]  C. Lamberti,et al.  The chemistry of the oxychlorination catalyst: an in situ, time-resolved XANES study. , 2002, Angewandte Chemie.

[884]  D. Coster,et al.  Über die Feinstruktur der Röntgenabsorptionskanten , 1932 .

[885]  P. Citrin AN OVERVIEW OF SEXAFS DURING THE PAST DECADE , 1986 .

[886]  F. d’Acapito,et al.  The ReflEXAFS station at the GILDA beamline (BM08) of ESRF. , 2003, Journal of synchrotron radiation.

[887]  C. Lamberti,et al.  Band resolution techniques and Fourier transform infrared spectra of adsorbed species , 1993 .

[888]  E. Arenholz,et al.  Enhanced Magnetism of Fe3O4 Nanoparticles with Ga Doping , 2011 .

[889]  Lothar Mussmann,et al.  Investigation of the selective catalytic reduction of NO by NH3 on Fe-ZSM5 monolith catalysts , 2006 .

[890]  R. S. V. Bordwehr A History of X-ray absorption fine structure , 1989 .

[891]  F. Farges Chromium speciation in oxide-type compounds: application to minerals, gems, aqueous solutions and silicate glasses , 2009 .

[892]  F. Lytle,et al.  Extended x‐ray absorption fine structure (EXAFS) of supported platinum catalysts , 1978 .

[893]  B. Weckhuysen,et al.  Noninvasive in situ visualization of supported catalyst preparations using multinuclear magnetic resonance imaging. , 2005, Journal of the American Chemical Society.

[894]  R. Feidenhans'l,et al.  In situ cell for combined XRD and on-line catalysis tests : studies of Cu-based water gas shift and methanol catalysts , 1991 .

[895]  Tadashi Matsushita,et al.  An Energy-Dispersive Spectrometer for the Rapid Measurement of X-ray Absorption Spectra Using Synchrotron Radiation , 1983 .

[896]  J. Ziegelbauer,et al.  Fundamental Investigation of Oxygen Reduction Reaction on Rhodium Sulfide-Based Chalcogenides , 2009 .

[897]  U. Bergmann,et al.  High-resolution Mn EXAFS of the oxygen-evolving complex in photosystem II: structural implications for the Mn4Ca cluster. , 2005, Journal of the American Chemical Society.

[898]  C. Lamberti,et al.  XAFS, IR, and UV−Vis Study of the CuI Environment in CuI-ZSM-5 , 1997 .

[899]  A. Fontaine,et al.  High-focusing Bragg-Crystal polychromator design for energy-dispersive X-ray absorption spectroscopy. , 1998, Journal of synchrotron radiation.

[900]  E. Giamello,et al.  EPR Investigation of the Electronic Structure of Mononuclear Copper(I) Nitric Oxide Adduct Formed upon Low-Pressure Adsorption of NO onto Cu/ZSM-5 Zeolite , 1997 .

[901]  D. Nachtigallová,et al.  Characterization of the Cu+ sites in high-silica zeolites interacting with the CO molecule: Combined computational and experimental study , 2003 .

[902]  J. D. Hanawalt Der Einfluß der Temperatur auf dieK-Absorption des Eisens , 1931 .

[903]  D. Saldin,et al.  Application of the layer Korringa-Kohn-Rostoker method to the calculation of near-edge structure in x-ray-absorption and electron-energy-loss spectroscopy , 1998 .

[904]  G. M. Bommarito,et al.  X-ray Standing Waves and Surface EXAFS Studies of Electrochemical Interfaces , 1995 .

[905]  J. Niemantsverdriet,et al.  WORKING SURFACE SCIENCE MODEL FOR THE PHILLIPS ETHYLENE POLYMERIZATION CATALYST : PREPARATION AND TESTING , 1997 .

[906]  J. Lunsford,et al.  Silica-supported chromium catalysts for ethylene polymerization: The active oxidation states of chromium , 1986 .

[907]  F. d’Acapito,et al.  Equilibria between peroxo and hydroperoxo species in the titanosilicates: an in situ high-resolution XANES investigation. , 2004, Chemphyschem : a European journal of chemical physics and physical chemistry.

[908]  Brian H. Toby,et al.  Accuracy of pair distribution function analysis applied to crystalline and non-crystalline materials , 1992 .

[909]  S. Mukerjee,et al.  CO Coverage/Oxidation Correlated with PtRu Electrocatalyst Particle Morphology in 0.3 M Methanol by In Situ XAS , 2007 .

[910]  W. Sachtler,et al.  Redox Chemistry of Cu/ZSM-5 , 1996 .

[911]  A. Delabie,et al.  A reinterpretation of the EPR spectra of Cu(II) in zeolites A, Y and ZK4, based on ab initio cluster model calculations , 2001 .

[912]  Lin X. Chen Taking snapshots of photoexcited molecules in disordered media by using pulsed synchrotron X-rays. , 2004, Angewandte Chemie.

[913]  Stern,et al.  Analysis of experimental extended x-ray-absorption fine-structure (EXAFS) data using calculated curved-wave, multiple-scattering EXAFS spectra. , 1990, Physical review. B, Condensed matter.

[914]  C. Roth,et al.  Determination of O[H] and CO coverage and adsorption sites on PtRu electrodes in an operating PEM fuel cell. , 2005, Journal of the American Chemical Society.

[915]  Katrin F. Domke,et al.  Host-guest geometry in pores of zeolite ZSM-5 spatially resolved with multiplex CARS spectromicroscopy. , 2012, Angewandte Chemie.

[916]  V. Caps,et al.  Synthesis and catalytic properties of TS-1 with mesoporous/microporous hierarchical structures obtained in the presence of amphiphilic organosilanes , 2010 .

[917]  C. Lamberti,et al.  Direct evidence of adsorption induced Cr(II) mobility on the SiO(2) surface upon complexation by CO. , 2010, Chemical communications.

[918]  Xiao‐Yu Yang,et al.  Highly Stable and Reusable Multimodal Zeolite TS‐1 Based Catalysts with Hierarchically Interconnected Three‐Level Micro–Meso–Macroporous Structure , 2011 .

[919]  C. Lamberti,et al.  EXAFS studies on MFI‐type gallosilicate molecular sieves , 1999 .

[920]  D. Sayers,et al.  Hydrogen Chemisorption on Silica-Supported Pt Clusters: In Situ X-ray Absorption Spectroscopy , 1997 .

[921]  Seth M Cohen,et al.  Postsynthetic methods for the functionalization of metal-organic frameworks. , 2012, Chemical reviews.

[922]  Cheetham,et al.  Open-Framework Inorganic Materials. , 1999, Angewandte Chemie.

[923]  C. Lamberti,et al.  Heterogeneity of Framework Ti(IV) in Ti-Silicalite as Revealed by the Adsorption of NH3. Combined Calorimetric and Spectroscopic Study † , 1999 .

[924]  Ulrich Müller,et al.  Industrial applications of metal-organic frameworks. , 2009, Chemical Society reviews.

[925]  K. Lillerud,et al.  Characterization of a New Porous Pt-Containing Metal-Organic Framework Containing Potentially Catalytically Active Sites: Local Electronic Structure at the Metal Centers , 2007 .

[926]  K. Lillerud,et al.  Functionalization of UiO-66 Metal−Organic Framework and Highly Cross-Linked Polystyrene with Cr(CO)3: In Situ Formation, Stability, and Photoreactivity , 2010 .

[927]  C. Lamberti,et al.  Alumina-supported copper chloride: 4. Effect of exposure to O2 and HCl , 2000 .

[928]  S. Heald EXAFS at grazing incidence: Data collection and analysis , 1992 .

[929]  R. Bell,et al.  Determination of the structure of distorted TiO6 units in the titanosilicate ETS-10 by a combination of X-ray absorption spectroscopy and computer modeling , 1996 .

[930]  F. d’Acapito,et al.  Description of a flexible cell for in situ X-ray and far-IR characterization of the surface of powdered materials , 2003 .

[931]  E. Stern Musings about the development of XAFS. , 2001, Journal of synchrotron radiation.

[932]  C. Lamberti,et al.  XRD, XAS, and IR Characterization of Copper-Exchanged Y Zeolite , 2000 .

[933]  Claude R. Henry,et al.  Surface studies of supported model catalysts , 1998 .

[934]  Boping Liu,et al.  Spectroscopic and structural characterization of Cr(II)/SiO2 active site precursors in model Phillips polymerization catalysts , 2012 .

[935]  H. Maeda,et al.  The state of excessively lon-exchanged copper in mordenite: formation of tetragonal hydroxy-bridged copper ion , 1992 .

[936]  James E. Penner-Hahn,et al.  Characterization of “spectroscopically quiet” metals in biology , 2005 .

[937]  Chen,et al.  Experimental confirmation of the X-ray magnetic circular dichroism sum rules for iron and cobalt. , 1995, Physical review letters.

[938]  C. Lamberti,et al.  Evolution of Extraframework Iron Species in Fe Silicalite: 2. Effect of Steaming , 2002 .

[939]  C. Catlow,et al.  Quantum Chemical Study of the Mechanism of Partial Oxidation Reactivity in Titanosilicate Catalysts: Active Site Formation, Oxygen Transfer, and Catalyst Deactivation , 1999 .

[940]  V. Krishnan,et al.  Structural studies on ruthenium(II) complexes used in interphase catalysis for the hydrogenation of ketones , 2007 .

[941]  A. Delabie,et al.  Identification of Cu(II) coordination structures in Cu-ZSM-5, based on a DFT/ab initio assignment of the EPR spectra , 2003 .

[942]  P. Sadler,et al.  Resonant X-ray emission spectroscopy reveals d-d ligand-field states involved in the self-assembly of a square-planar platinum complex. , 2012, Physical chemistry chemical physics : PCCP.

[943]  D. Siddons,et al.  Hard real-time quick EXAFS data acquisition with all open source software on a commodity personal computer , 2007 .

[944]  P. Gütlich,et al.  Thermal- and light-induced spin crossover in novel 2D Fe(II) metalorganic frameworks {Fe(4-PhPy)(2)[M(II)(CN)(x)](y)}.sH(2)O: spectroscopic, structural, and magnetic studies. , 2009, Inorganic chemistry.

[945]  K. Asakura,et al.  X-ray magnetic circular dichroism at rare-earth L23 absorption edges in various compounds and alloys , 2006 .

[946]  S. Kaskel,et al.  Improved synthesis, thermal stability and catalytic properties of the metal-organic framework compound Cu3(BTC)2 , 2004 .

[947]  Bartolomeo Civalleri,et al.  CRYSTAL: a computational tool for the ab initio study of the electronic properties of crystals , 2005 .

[948]  T. Fujikawa Theory of Deep Core Excitation EELS , 1991 .

[949]  J. V. van Bokhoven,et al.  Catalysis by metal-organic frameworks: fundamentals and opportunities. , 2011, Physical chemistry chemical physics : PCCP.

[950]  F. d’Acapito,et al.  A new procedure for the quantitative analysis of extended x-ray absorption fine structure data in total reflection geometry. , 2008, The Review of scientific instruments.

[951]  K. Lillerud,et al.  Liquid hydrogen in protonic chabazite. , 2005, Journal of the American Chemical Society.

[952]  H. Si,et al.  Location of Si vacancies and [Ti(OSi)4] and [Ti(OSi)3OH] sites in the MFI framework: a large cluster and full ab initio study. , 2011, The journal of physical chemistry. A.

[953]  M. Bauer,et al.  Adsorption of oxygen on copper in Cu/HZSM5 zeolites. , 2010, Physical chemistry chemical physics : PCCP.

[954]  G. Kramer,et al.  Reactivity Theory of Zeolitic Broensted Acidic Sites , 1995 .

[955]  R. Nuzzo,et al.  Core Shell Inversion during Nucleation and Growth of Bimetallic Pt/Ru Nanoparticles , 1998 .

[956]  A. Beale,et al.  New Insights into the Active Surface Species of Silver Alumina Catalysts in the Selective Catalytic Reduction of NO , 2011 .

[957]  L. G. Parratt Surface Studies of Solids by Total Reflection of X-Rays , 1954 .

[958]  P. Soukiassian,et al.  Structure of Prototypical Semiconductor Surfaces and Interfaces Investigated by Photoemission Extended X-Ray Absorption Fine Structure (PEXAFS) , 1998 .

[959]  C. Catlow,et al.  On the structure and coordination of the oxygen-donating species in Ti↑MCM-41/TBHP oxidation catalysts: a density functional theory and EXAFS study , 2002 .

[960]  H. Petersen Zur Theorie der Röntgenabsorption molekularer Gase. III , 1936 .

[961]  W. Hölderich,et al.  Vapour-phase beckmann rearrangement using B-MFI zeolites , 1996 .

[962]  A. Frenkel,et al.  Evolution of the structure and chemical state of Pd nanoparticles during the in situ catalytic reduction of NO with H2. , 2011, Journal of the American Chemical Society.

[963]  W. Delgass,et al.  Evidence of defect-promoted reactivity for epoxidation of propylene in titanosilicate (TS-1) catalysts: a DFT study. , 2004, Journal of the American Chemical Society.

[964]  J. Niemantsverdriet,et al.  In situ, Cr K-edge XAS study on the Phillips catalyst: activation and ethylene polymerization , 2005 .

[965]  W. O'grady,et al.  'ATOMIC' X-RAY ABSORPTION FINE STRUCTURE : A NEW TOOL FOR EXAMINING ELECTRONIC AND IONIC POLARIZATION EFFECTS , 1999 .

[966]  V. Sobolev,et al.  Ferrisilicate analogs of ZSM-5 zeolite as catalysts for one- step oxidation of benzene to phenol , 1993 .

[967]  R. G. Tailleur,et al.  Cu/P(4-PVP) stereochemistry in tetralin liquid-phase oxidation I. Effect of the CuCl2/P(4-PVP) on selectivity , 2007 .

[968]  Michael O'Keeffe,et al.  Secondary building units, nets and bonding in the chemistry of metal-organic frameworks. , 2009, Chemical Society reviews.

[969]  A. Frenkel,et al.  Structure, chemical composition, and reactivity correlations during the in situ oxidation of 2-propanol. , 2011, Journal of the American Chemical Society.

[970]  Naoki Toshima,et al.  Bimetallic nanoparticles—novel materials for chemical and physical applications , 1998 .

[971]  Zhigang Xie,et al.  Porous phosphorescent coordination polymers for oxygen sensing. , 2010, Journal of the American Chemical Society.

[972]  S. Strauss,et al.  [Cu(CO)(n)()](+) Complex Ions in the Solid State (n = 1, 2, 3). , 1996, Inorganic chemistry.

[973]  C. Lamberti,et al.  A calorimetric, IR, XANES and EXAFS study of the adsorption of NH3 on Ti-silicalite as a function of the sample pre-treatment , 1999 .

[974]  Olivier Mathon,et al.  Invited article: the fast readout low noise camera as a versatile x-ray detector for time resolved dispersive extended x-ray absorption fine structure and diffraction studies of dynamic problems in materials science, chemistry, and catalysis. , 2007, The Review of scientific instruments.

[975]  Pengyan Wu,et al.  Homochiral metal-organic frameworks for heterogeneous asymmetric catalysis. , 2010, Journal of the American Chemical Society.

[976]  J. Grunwaldt,et al.  Oxidic or metallic palladium: which is the active phase in pd-catalyzed aerobic alcohol oxidation? , 2006, The journal of physical chemistry. B.

[977]  R. Millini,et al.  Ti coordination in titanium silicalite-1. , 2006, Journal of the American Chemical Society.

[978]  Russell G. Tonkyn,et al.  Excellent activity and selectivity of Cu-SSZ-13 in the selective catalytic reduction of NOx with NH3 , 2010 .

[979]  D. Murzin,et al.  The influence of acidity of carbon nanofibre-supported palladium catalysts in the hydrogenolysis of hydroxymatairesinol , 2007 .

[980]  S. Conradson,et al.  A four‐point crystal bender for dispersive X‐ray absorption spectroscopy , 1993 .

[981]  M. Di Michiel,et al.  Observing oxygen storage and release at work during cycling redox conditions: synergies between noble metal and oxide promoter. , 2012, Angewandte Chemie.

[982]  Raul F. Lobo,et al.  The ammonia selective catalytic reduction activity of copper-exchanged small-pore zeolites , 2011 .

[983]  B. Weckhuysen,et al.  An operando optical fiber UV–vis spectroscopic study of the catalytic decomposition of NO and N2O over Cu-ZSM-5 , 2003 .

[984]  E. A. Lewis,et al.  Embedded cluster Δ-XANES modeling of adsorption processes on Pt , 2009 .

[985]  Raul F. Lobo,et al.  Zeolite and molecular sieve synthesis , 1992 .

[986]  A. V. D. Eerden,et al.  Apparatus for in situ x-ray absorption fine structure studies on catalytic systems in the energy range 1000 eV , 2000 .

[987]  C. Prestipino,et al.  EXAFS and XANES investigation of the ETS-10 microporous titanosilicate. , 2005, The journal of physical chemistry. B.

[988]  Helmut Bertagnolli,et al.  X‐Ray Absorption Spectroscopy of Amorphous Solids, Liquids, and Catalytic and Biochemical Systems—Capabilities and Limitations , 1994 .

[989]  Y. Souma,et al.  A new type of support 'bipyridine containing aromatic polyamide' to CuCl2 for synthesis of dimethyl carbonate (DMC) by oxidative carbonylation of methanol , 2000 .

[990]  J. Long,et al.  Matrix isolation chemistry in a porous metal-organic framework: photochemical substitutions of N2 and H2 in Zn4O[(eta6-1,4-benzenedicarboxylate)Cr(CO)3]3. , 2008, Journal of the American Chemical Society.

[991]  D. Ramaker,et al.  XAFS spectroscopy in catalysis research: AXAFS and shape resonances. , 1999, Journal of synchrotron radiation.

[992]  Anna Bergamaschi,et al.  Five-element Johann-type x-ray emission spectrometer with a single-photon-counting pixel detector. , 2011, The Review of scientific instruments.

[993]  G. Ghiotti,et al.  Cr2+ ions grafted to silica and silicalite surfaces: FTIR characterization and ethylene polymerization activity , 1994 .

[994]  W. M. Meier,et al.  Structure of synthetic zeolite ZSM-5 , 1978, Nature.

[995]  Teppei Yamada,et al.  Protection and deprotection approach for the introduction of functional groups into metal-organic frameworks. , 2009, Journal of the American Chemical Society.

[996]  S. Kitagawa,et al.  Selective sorption of oxygen and nitric oxide by an electron-donating flexible porous coordination polymer , 2010, Nature Chemistry.

[997]  Uwe Bergmann,et al.  High resolution 1s core hole X-ray spectroscopy in 3d transition metal complexes—electronic and structural information , 2005 .

[998]  Rob Ameloot,et al.  An amino-modified Zr-terephthalate metal-organic framework as an acid-base catalyst for cross-aldol condensation. , 2011, Chemical communications.

[999]  D. Nachtigallová,et al.  Coordination of Cu+ and Cu2+ ions in ZSM-5 in the vicinity of two framework Al atoms , 2001 .

[1000]  T. Akita,et al.  Propane reacts with O2 and H2 on gold supported TS-1 to form oxygenates with high selectivity. , 2008, Chemical communications.

[1001]  D. Koningsberger,et al.  Reactivity of binuclear Fe complexes in over-exchanged Fe/ZSM5, studied by in situ XAFS spectroscopy 2. Selective catalytic reduction of NO with isobutane , 2003 .

[1002]  W. Xu,et al.  Time Resolved IR and X-Ray Simultaneous Spectroscopy: New Opportunities for the Analysis of Fast Chemical-Physical Phenomena in Materials Science , 2009 .

[1003]  R. Socha,et al.  Selective catalytic reduction of NO by ethanol: Speciation of iron and "structure-properties" relationship in FeSiBEA zeolite , 2009 .

[1004]  A. Corma,et al.  INTERACTION OF TI-ZEOLITES WITH WATER. A PERIODIC AB INITIO STUDY , 1999 .

[1005]  M. Clerici Oxidation of saturated hydrocarbons with hydrogen peroxide, catalysed by titanium silicalite , 1991 .

[1006]  W. Haag,et al.  Catalytic conversion of propane to aromatics: Effects of adding Ga and/or Pt to HZSM-5 , 1994 .

[1007]  J. Grunwaldt,et al.  Structural changes of noble metal catalysts during ignition and extinction of the partial oxidation of methane studied by advanced QEXAFS techniques. , 2009, Physical chemistry chemical physics : PCCP.

[1008]  D. Ramaker,et al.  Three-site model for hydrogen adsorption on supported platinum particles: influence of support ionicity and particle size on the hydrogen coverage. , 2005, Journal of the American Chemical Society.

[1009]  K. Hadjiivanov,et al.  FTIR Study of Low-Temperature CO Adsorption on Cu-ZSM-5: Evidence of the Formation of Cu2+(CO)2 Species , 2000 .

[1010]  G. Bellussi,et al.  Titanium-Silicalite: a Novel Derivative in the Pentasil Family , 1986 .

[1011]  Filipponi,et al.  X-ray-absorption spectroscopy and n-body distribution functions in condensed matter. II. Data analysis and applications. , 1995, Physical review. B, Condensed matter.

[1012]  K. Lillerud,et al.  Conversion of methanol to hydrocarbons: how zeolite cavity and pore size controls product selectivity. , 2012, Angewandte Chemie.

[1013]  A. Frenkel Solving the structure of nanoparticles by multiple-scattering EXAFS analysis. , 1999, Journal of synchrotron radiation.

[1014]  A. Piazzalunga,et al.  Collective magnetic excitations in the spin ladder Sr14Cu24O41 measured using high-resolution resonant inelastic x-ray scattering. , 2009, Physical review letters.

[1015]  Ettore Fois,et al.  Competition between Water and Hydrogen Peroxide at Ti Center in Titanium Zeolites. An ab Initio Study , 2004 .

[1016]  M. Lyubovsky,et al.  SYNTHESIS AND CHARACTERIZATION OF VANADIUM-SUBSTITUTED MESOPOROUS MOLECULAR SIEVES , 1999 .

[1017]  M. Balasubramanian,et al.  When is a nanoparticle a cluster? An operando EXAFS study of amine borane dehydrocoupling by Rh(4-6) clusters. , 2007, Journal of the American Chemical Society.

[1018]  P. Glatzel,et al.  Resonant X-ray spectroscopy to study K absorption pre-edges in 3d transition metal compounds , 2009 .

[1019]  G. Pirngruber The surface chemistry of N2O decomposition on iron containing zeolites (I) , 2003 .

[1020]  Z. Liu,et al.  X-ray absorption spectroscopy of Ti-containing molecular sieves ETS-10, aluminum-free Ti-β, and TS-1 , 1995 .

[1021]  Dorina F. Sava,et al.  Trapping guests within a nanoporous metal-organic framework through pressure-induced amorphization. , 2011, Journal of the American Chemical Society.

[1022]  M. Siegbahn LVIII. Precision-measurements in the X-ray spectra , 1919 .

[1023]  M. Tromp,et al.  Interaction of small gas phase molecules with alumina supported rhodium nanoparticles: an in situ spectroscopic study , 2008 .

[1024]  K. Hodgson,et al.  Multiple-Edge XAS Studies of Synthetic Iron-Copper Bridged Molecular Assemblies Relevant to Cytochrome c Oxidase. Structure Determination Using Multiple-Scattering Analysis with Statistical Evaluation of Errors. , 1996, Inorganic chemistry.

[1025]  J. Sauer,et al.  Coordination, Structure, and Vibrational Spectra of Titanium in Silicates and Zeolites in Comparison with Related Molecules. An ab Initio Study , 1996 .

[1026]  D. Olson,et al.  Commensurate adsorption of hydrocarbons and alcohols in microporous metal organic frameworks. , 2012, Chemical reviews.

[1027]  C. Lamberti,et al.  IR spectroscopy of adsorbed NO as a useful tool for the characterisation of low concentrated Fe-silicalite catalysts , 2002 .

[1028]  D. Lützenkirchen-Hecht,et al.  Recent advances and new applications of time-resolved x-ray absorption spectroscopy , 2005 .

[1029]  F. Lytle,et al.  Extended x‐ray absorption fine structure (EXAFS) of dispersed metal catalysts , 1979 .

[1030]  C. Lamberti,et al.  Time-resolved in situ studies of oxygen intercalation into SrCoO2.5, performed by neutron diffraction and X-ray absorption spectroscopy. , 2006, Journal of the American Chemical Society.

[1031]  V. Romannikov,et al.  Oxidation of benzene to phenol by nitrous oxide over Fe-ZSM-5 zeolites , 1992 .

[1032]  J. Bokhoven,et al.  Al K-edge near-edge X-ray absorption fine structure (NEXAFS) study on the coordination structure of aluminum in minerals and Y zeolites , 1999 .

[1033]  R. Nuzzo,et al.  Structural characterization of bimetallic nanomaterials with overlapping x-ray absorption edges , 2009 .

[1034]  C. Lamberti,et al.  Cu+(H2) and Na+(H2) adducts in exchanged ZSM-5 zeolites. , 2004, Chemical communications.

[1035]  Takashi Yamamoto Assignment of pre‐edge peaks in K‐edge x‐ray absorption spectra of 3d transition metal compounds: electric dipole or quadrupole? , 2008 .

[1036]  S. Hong,et al.  Influence of framework silicon to aluminium ratio on aluminium coordination and distribution in zeolite Beta investigated by 27Al MAS and 27Al MQ MAS NMR , 2004 .

[1037]  K. Lillerud,et al.  H2 storage in isostructural UiO-67 and UiO-66 MOFs. , 2012, Physical chemistry chemical physics : PCCP.

[1038]  P. Agrawal,et al.  Gallosilicate molecular sieves: the role of framework and nonframework gallium on catalytic cracking activity , 1987 .

[1039]  C. Meneghini,et al.  ESTRA-FitEXA: A software package for EXAFS data analysis , 2012 .

[1040]  S. Qiu,et al.  Molecular engineering for synthesizing novel structures of metal–organic frameworks with multifunctional properties , 2009 .

[1041]  B. Weckhuysen,et al.  Pore curvature and support composition effects on the electronic properties of supported Pt catalysts: An infrared spectroscopy study with CO as probe molecule , 2008 .

[1042]  M. Kumar,et al.  Selective reduction of NO with Fe-ZSM-5 catalysts of low Fe content: I. Relations between active site structure and catalytic performance , 2005 .

[1043]  T. Tatsumi,et al.  Unique trans-Selectivity of Ti-MWW in Epoxidation of cis/trans-Alkenes with Hydrogen Peroxide , 2002 .

[1044]  A. Beale,et al.  Spatiotemporal Multitechnique Imaging of a Catalytic Solid in Action: Phase Variation and Volatilization During Molybdenum Oxide Reduction , 2009 .

[1045]  P. Smirniotis,et al.  N2O decomposition over iron-containing zeolites prepared by different methods: a comparison of the reaction mechanism , 2004 .

[1046]  Kenji Sumida,et al.  Hydrogen storage properties and neutron scattering studies of Mg2(dobdc)--a metal-organic framework with open Mg2+ adsorption sites. , 2011, Chemical communications.

[1047]  Qing Min Wang,et al.  Metallo-organic molecular sieve for gas separation and purification , 2002 .

[1048]  R. Nuzzo,et al.  Unusual non-bulk properties in nanoscale materials: thermal metal-metal bond contraction of gamma-alumina-supported Pt catalysts. , 2006, Journal of the American Chemical Society.

[1049]  C. Lamberti,et al.  The structure of the peroxo species in the TS-1 catalyst as investigated by resonant Raman spectroscopy. , 2002, Angewandte Chemie.

[1050]  C. Lamberti,et al.  Effect of Interaction with H2O and NH3 on the Vibrational, Electronic, and Energetic Peculiarities of Ti(IV) Centers TS-1 Catalysts: A Spectroscopic and Computational Study , 2002 .

[1051]  M. Rosseinsky,et al.  Framework functionalisation triggers metal complex binding. , 2008, Chemical communications.

[1052]  C. Lamberti,et al.  XAFS Study of Ti-Silicalite - Structure of Framework Ti(IV) in the Presence and Absence of Reactive Molecules (H2O, NH3) and Comparison with Ultraviolet-Visible and Ir Results , 1994 .

[1053]  B. Weckhuysen,et al.  Promotion effects in the oxidation of CO over zeolite-supported Pt nanoparticles. , 2005, The journal of physical chemistry. B.

[1054]  C. Lamberti,et al.  Functionalization of zeolitic cavities: grafting NH2 groups in framework T sites of B-SSZ-13--a way to obtain basic solids catalysts? , 2007, Journal of the American Chemical Society.

[1055]  Simon J. L. Billinge,et al.  PDFgetX2: a GUI-driven program to obtain the pair distribution function from X-ray powder diffraction data , 2004 .

[1056]  J. Hormes,et al.  The influence of coordination geometry and valency on the K-edge absorption near edge spectra of selected chromium compounds , 2004 .

[1057]  K. Lillerud,et al.  Design, synthesis and characterization of a Pt-Gd metal-organic framework containing potentially catalytically active sites. , 2008, Dalton transactions.

[1058]  A. Corma,et al.  Engineering metal organic frameworks for heterogeneous catalysis. , 2010, Chemical reviews.

[1059]  C. Lamberti,et al.  Characterization of isolated Ag cations in homoionic Ag-Y zeolites: A combined anomalous XRPD and EXAFS study , 2003 .

[1060]  J. Bünzli,et al.  Lanthanide-containing molecular and supramolecular polymetallic functional assemblies. , 2002, Chemical reviews.

[1061]  J. Rehr,et al.  TI K-EDGE XANES STUDIES OF TI COORDINATION AND DISORDER IN OXIDE COMPOUNDS: COMPARISON BETWEEN THEORY AND EXPERIMENT , 1997 .

[1062]  Carlo Lamberti,et al.  The inconsistency in adsorption properties and powder XRD data of MOF-5 is rationalized by framework interpenetration and the presence of organic and inorganic species in the nanocavities. , 2007, Journal of the American Chemical Society.

[1063]  Cheng Wang,et al.  Rational synthesis of noncentrosymmetric metal-organic frameworks for second-order nonlinear optics. , 2012, Chemical reviews.

[1064]  H. García,et al.  Metal Organic Frameworks as Solid Acid Catalysts for Acetalization of Aldehydes with Methanol , 2010 .

[1065]  C. Lamberti,et al.  Vibrational structure of titanium silicate catalysts. A spectroscopic and theoretical study. , 2001, Journal of the American Chemical Society.

[1066]  W. Sachtler,et al.  Effect of Ga/Proton Balance in Ga/HZSM-5 Catalysts on C3 Conversion to Aromatics , 1994 .

[1067]  M. Eddaoudi,et al.  Rod packings and metal-organic frameworks constructed from rod-shaped secondary building units. , 2005, Journal of the American Chemical Society.

[1068]  P. Luches,et al.  O K-edge x-ray absorption study of ultrathin NiO epilayers deposited in situ on Ag(001) , 2004 .

[1069]  Can Li,et al.  UV Raman spectroscopic studies on active sites and synthesis mechanisms of transition metal-containing microporous and mesoporous materials. , 2010, Accounts of chemical research.

[1070]  Simon J. L. Billinge,et al.  PDFFIT, a program for full profile structural refinement of the atomic pair distribution function , 1999 .

[1071]  A. Rosenzweig The metal centres of particulate methane mono-oxygenase. , 2008, Biochemical Society transactions.

[1072]  U. Mueller,et al.  Metal–organic frameworks—prospective industrial applications , 2006 .

[1073]  T. Ressler,et al.  In Situ X-ray Absorption Spectroscopy Studies on Chemical Oscillations in the CO/O2 System on Supported Pd Catalysts , 1997 .

[1074]  B. Weckhuysen,et al.  Bis(μ-oxo)dicopper in Cu-ZSM-5 and Its Role in the Decomposition of NO: A Combined in Situ XAFS, UV−Vis−Near-IR, and Kinetic Study , 2003 .

[1075]  B. Gates,et al.  A flow-through x-ray absorption spectroscopy cell for characterization of powder catalysts in the working state , 2001 .

[1076]  W. O'grady,et al.  Determination of O and OH adsorption sites and coverage in situ on Pt electrodes from Pt L(2,3) X-ray absorption spectroscopy. , 2005, The journal of physical chemistry. B.

[1077]  K. Burgess,et al.  Metal-catalyzed epoxidations of alkenes with hydrogen peroxide. , 2003, Chemical reviews.

[1078]  H. Gies,et al.  Alkene epoxidation with mesoporous materials assembled from TS-1 seeds - Is there a hierarchical pore system? , 2010 .

[1079]  C. Lamberti,et al.  CO Adsorption on CPO-27-Ni Coordination Polymer: Spectroscopic Features and Interaction Energy , 2009 .

[1080]  John J. Rehr,et al.  Sensitivity of Pt x-ray absorption near edge structure to the morphology of small Pt clusters , 2002 .

[1081]  D. Lützenkirchen-Hecht,et al.  Advancing Time-resolved Methods in Monitoring and Characterization of Catalysts , 2009 .

[1082]  G. Palmisano,et al.  Cubic octanuclear Ni(II) clusters in highly porous polypyrazolyl-based materials. , 2010, Journal of the American Chemical Society.

[1083]  W. O'grady,et al.  SYSTEMATIC CHEMICAL EFFECTS OBSERVED IN ATOMIC X-RAY ABSORPTION FINE STRUCTURE , 1997 .

[1084]  A. Yaresko,et al.  Electronic structure of mixed-valence semiconductors in the LSDA + U approximation. I. Sm monochalcogenides , 2002 .

[1085]  D. Koningsberger,et al.  An in situ cell for transmission EXAFS measurements on catalytic samples , 1989 .

[1086]  F. Quignard,et al.  Catalytic Cleavage of the C-H and C-C Bonds of Alkanes by Surface Organometallic Chemistry: An EXAFS and IR Characterization of a Zr-H Catalyst , 1996, Science.

[1087]  Avelino Corma,et al.  Inorganic Solid Acids and Their Use in Acid-Catalyzed Hydrocarbon Reactions , 1995 .

[1088]  J. Pendry,et al.  Atomic origin of structure in EXAFS experiments , 1978 .

[1089]  Liu,et al.  UV Resonance Raman Spectroscopic Identification of Titanium Atoms in the Framework of TS-1 Zeolite. , 1999, Angewandte Chemie.

[1090]  Kimoon Kim,et al.  A homochiral metal-organic material with permanent porosity, enantioselective sorption properties, and catalytic activity. , 2006, Angewandte Chemie.

[1091]  Grant Bunker,et al.  Application of the ratio method of EXAFS analysis to disordered systems , 1983 .

[1092]  B. Sels,et al.  Oxygen precursor to the reactive intermediate in methanol synthesis by Cu-ZSM-5. , 2010, Journal of the American Chemical Society.

[1093]  Gloria Berlier,et al.  Interaction of N2, CO and NO with Cu-exchanged ETS-10: a compared FTIR study with other Cu-zeolites and with dispersed Cu2O , 2001 .

[1094]  B. Gates,et al.  Structure and Nature of the Metal-Support Interface: Characterization of Iridium Clusters on Magnesium Oxide by Extended X-Ray Absorption Fine Structure Spectroscopy. , 1993 .

[1095]  Wenbin Lin,et al.  Enantioselective catalysis with homochiral metal-organic frameworks. , 2009, Chemical Society reviews.

[1096]  B. Weckhuysen,et al.  An integrated AFM-Raman instrument for studying heterogeneous catalytic systems: a first showcase. , 2012, Chemical communications.

[1097]  D. E. Keller,et al.  Application of AXAFS spectroscopy to transition-metal oxides: influence of the nearest and next nearest neighbour shells in vanadium oxides. , 2007, Chemistry.

[1098]  C. Lamberti,et al.  Evolution of Extraframework Iron Species in Fe Silicalite: 1. Effect of Fe Content, Activation Temperature, and Interaction with Redox Agents , 2002 .

[1099]  Fabrizio Cavani,et al.  Sustainable Industrial Chemistry , 2009 .

[1100]  L. Kiwi-Minsker,et al.  Benzene hydroxylation over FeZSM-5 catalysts: which Fe sites are active? , 2004 .

[1101]  J. Hanson,et al.  Solving the structure of reaction intermediates by time-resolved synchrotron x-ray absorption spectroscopy. , 2008, The Journal of chemical physics.

[1102]  C. Lamberti,et al.  XANES study of Ti and Fe substituted silicalites in presence and in absence of NH3 and comparison with UV-vis, IR and Raman spectra , 1995 .

[1103]  V. A. Safonov,et al.  Valence-to-core X-ray emission spectroscopy identification of carbide compounds in nanocrystalline Cr coatings deposited from Cr(III) electrolytes containing organic substances. , 2006, The journal of physical chemistry. B.

[1104]  R. Prins,et al.  Different methods for preparation of Fe-ZSM5 as catalyst for the selective catalytic reduction of nitrogen oxides , 1999 .

[1105]  Eric L. Shirley,et al.  AB INITIO INCLUSION OF ELECTRON-HOLE ATTRACTION : APPLICATION TO X-RAY ABSORPTION AND RESONANT INELASTIC X-RAY SCATTERING , 1998 .

[1106]  Julian D. Gale,et al.  GULP: A computer program for the symmetry-adapted simulation of solids , 1997 .

[1107]  Y. Hu,et al.  Hydrogen Storage in Metal–Organic Frameworks , 2010, Advanced materials.

[1108]  C. Lamberti,et al.  Single site catalyst for partial oxidation reaction: Ts-1 case study , 2005 .

[1109]  Seth M. Cohen,et al.  Postsynthetic modification of metal-organic frameworks. , 2009, Chemical Society reviews.

[1110]  Edward A. Stern,et al.  New Technique for Investigating Noncrystalline Structures: Fourier Analysis of the Extended X-Ray—Absorption Fine Structure , 1971 .

[1111]  K. Lillerud,et al.  Effect of boron substitution in chabazite framework : IR studies on the acidity properties and reactivity towards methanol , 2007 .

[1112]  C. Lamberti,et al.  Thermal Reduction of Cu2+−Mordenite and Re-oxidation upon Interaction with H2O, O2, and NO , 2003 .

[1113]  G. Wilke Fifty years of Ziegler catalysts: consequences and development of an invention. , 2003, Angewandte Chemie.

[1114]  Javier Pérez-Ramírez,et al.  Importance of the lifetime of oxygen species generated by N2O decomposition for hydrocarbon activation over Fe-silicalite , 2006 .

[1115]  Héaector D. Abruña Probing Electrochemical Interfaces with X‐Rays , 2007 .

[1116]  K. Lillerud,et al.  Synthesis of Titanium Chabazite: A New Shape Selective Oxidation Catalyst with Small Pore Openings and Application in the Production of Methyl Formate from Methanol , 2011 .

[1117]  E. D. Crozier,et al.  Angular scanning stage for glancing‐incidence surface EXAFS , 1988 .

[1118]  A. Frenkel,et al.  Time Resolved in Situ XAFS Study of the Electrochemical Oxygen Intercalation in SrFeO2.5 Brownmillerite Structure: Comparison with the Homologous SrCoO2.5 System† , 2011 .

[1119]  T. Uruga,et al.  Energy-Dispersive XAFS Studies on the Spontaneous Dispersion of PdO and the Formation of Stable Pd Clusters in Zeolites. , 2004, The journal of physical chemistry. B.

[1120]  M. O'Keeffe Design of MOFs and intellectual content in reticular chemistry: a personal view. , 2009, Chemical Society reviews.

[1121]  D. Trimm,et al.  Kinetic study of steam reforming of methanol over copper-based catalysts , 1993 .

[1122]  Peng Wu,et al.  Synthesis, crystallization mechanism, and catalytic properties of titanium-rich TS-1 free of extraframework titanium species. , 2008, Journal of the American Chemical Society.

[1123]  R. W. Joyner,et al.  Structure, Chemistry, and Activity of Cu-ZSM-5 Catalysts for the Selective Reduction of NOx in the Presence of Oxygen , 1994 .

[1124]  Lynn F. Gladden,et al.  Recent Advances in MRI Studies of Chemical Reactors: Ultrafast Imaging of Multiphase Flows , 2003 .

[1125]  G. Koten,et al.  Atomic XAFS as a probe of electron transfer within organometallic complexes: Data analysis and theoretical calculations , 2004 .

[1126]  N. Binsted,et al.  A rapid, exact, curved-wave theory for EXAFS calculations. II. The multiple-scattering contributions , 1986 .

[1127]  S. Shinkai,et al.  "Clickable" metal-organic framework. , 2008, Journal of the American Chemical Society.

[1128]  C. Louis,et al.  Nucleation and Particle Growth Processes Involved in the Preparation of Silica-Supported Nickel Materials by a Two-Step Procedure , 1995 .

[1129]  A. Dent,et al.  Combined energy dispersive EXAFS and x‐ray diffraction , 1992 .

[1130]  B. Rieger,et al.  Reaction kinetics of oxychlorination of carbon monoxide to phosgene based on copper(II) chloride , 2009 .

[1131]  H. Ebert,et al.  Calculation of X-ray absorption spectra using the full potential spin-polarized relativistic multiple scattering formalism , 1999 .

[1132]  Lin X. Chen,et al.  Probing transient molecular structures in photochemical processes using laser-initiated time-resolved X-ray absorption spectroscopy. , 2005, Annual review of physical chemistry.

[1133]  A. Frenkel,et al.  Structural and Architectural Evaluation of Bimetallic Nanoparticles: a Case Study of Pt؊ru Core؊shell and Alloy Nanoparticles Abstract a Comprehensive Structural/architectural Evaluation of the Ptru (1:1) Alloy and Ru@pt Core؊shell Nanoparticles (nps) Provides Spatially Resolved Structural Informati , 2009 .

[1134]  A. Paulikas,et al.  Improved ab initio calculations of amplitude and phase functions for extended x-ray absorption fine structure spectroscopy , 1988 .

[1135]  A. Uriarte,et al.  Oxidation of benzene to phenol by nitrous oxide: Activity of iron in zeolite matrices of various composition , 2002 .

[1136]  A. Munkholm,et al.  Capturing a Photoexcited Molecular Structure Through Time-Domain X-ray Absorption Fine Structure , 2001, Science.

[1137]  M. Kantcheva,et al.  Study of the NO2-NH3 Interaction on a Titania (ANATASE) Supported Vanadia Catalyst , 1994 .

[1138]  M. Drakopoulos,et al.  Determining the aluminium occupancy on the active T-sites in zeolites using X-ray standing waves. , 2008, Nature materials.

[1139]  B. Weckhuysen,et al.  In-situ scanning transmission X-ray microscopy of catalytic solids and related nanomaterials. , 2010, Chemphyschem : a European journal of chemical physics and physical chemistry.

[1140]  Omar K Farha,et al.  Supercritical processing as a route to high internal surface areas and permanent microporosity in metal-organic framework materials. , 2009, Journal of the American Chemical Society.

[1141]  R. Nuzzo,et al.  Carbon Support Effects on Bimetallic Pt−Ru Nanoparticles Formed from Molecular Precursors , 1999 .

[1142]  A. P. Sorini,et al.  Ab initio theory and calculations of X-ray spectra , 2009 .

[1143]  C. Lamberti,et al.  Study of epitaxial selective area growth In1−xGaxAs films by synchrotron μ-XRF mapping , 2010 .

[1144]  B. Smit,et al.  Carbon dioxide capture: prospects for new materials. , 2010, Angewandte Chemie.

[1145]  K. Lillerud,et al.  X-ray absorption spectroscopies: useful tools to understand metallorganic frameworks structure and reactivity. , 2010, Chemical Society reviews.

[1146]  K. Lillerud,et al.  A thermally stable Pt/Y-based metal-organic framework: Exploring the accessibility of the metal centers with spectroscopic methods using H2O, CH3OH, and CH3CN as probes. , 2006, The journal of physical chemistry. B.

[1147]  Chan,et al.  Practical method for full curved-wave theory analysis of experimental extended x-ray-absorption fine structure. , 1986, Physical review. B, Condensed matter.

[1148]  C. Lamberti,et al.  Oxidation States of Copper Ions in ZSM-5 Zeolites. A Multitechnique Investigation. , 2000, The journal of physical chemistry. B.

[1149]  R. T. Yang,et al.  Low-temperature selective catalytic reduction of NOx with NH3 over metal oxide and zeolite catalysts—A review , 2011 .

[1150]  A. Beale,et al.  Implementation of a combined SAXS/WAXS/QEXAFS set-up for time-resolved in situexperiments. , 2008, Journal of synchrotron radiation.

[1151]  C. Louis,et al.  The effect of gold particle size on AuAu bond length and reactivity toward oxygen in supported catalysts , 2006 .

[1152]  P. Luches,et al.  X-ray absorption study at the Mg and O K edges of ultrathin MgO epilayers on Ag(001) , 2004 .

[1153]  C. Mirodatos,et al.  Applicability and Limits of the Ensemble Model in Catalysis by Metals: The Kinetics of Ethane Hydrogenolysis over Pt/SiO2☆ , 1998 .

[1154]  B. Gates,et al.  Time-Resolved Structural Characterization of Formation and Break-up of Rhodium Clusters Supported in Highly Dealuminated Y Zeolite , 2008 .

[1155]  M. Anpo,et al.  In-Situ XAFS, Photoluminescence, and IR Investigations of Copper Ions Included within Various Kinds of Zeolites. Structure of Cu(I) Ions and Their Interaction with CO Molecules , 1996 .

[1156]  Seth M Cohen,et al.  Postsynthetic modification of metal-organic frameworks--a progress report. , 2011, Chemical Society reviews.

[1157]  A. Beale,et al.  Chemical probing within catalyst bodies by diagonal offset Raman spectroscopy. , 2012, Angewandte Chemie.

[1158]  Hidenori Yahiro,et al.  Cu-ZSM-5 zeolite as highly active catalyst for removal of nitrogen monoxide from emission of diesel engines , 1991 .

[1159]  D. Dingwell,et al.  X-ray absorption study of Ti-bearing silicate glasses , 1994 .

[1160]  G. Pirngruber,et al.  A look into the surface chemistry of N2O decomposition on iron zeolites by transient response experiments , 2005 .

[1161]  A. Polian,et al.  Dispersive XAS at third-generation sources: strengths and limitations. , 1999, Journal of synchrotron radiation.

[1162]  J. A. Ryder,et al.  Density functional theory study of benzene oxidation over Fe-ZSM-5 , 2003 .

[1163]  Cr Cees Bayense,et al.  Aromatization of propane over MFI-gallosilicates , 1991 .

[1164]  T. Tatsumi,et al.  A Novel Titanosilicate with MWW Structure: II. Catalytic Properties in the Selective Oxidation of Alkenes , 2001 .

[1165]  A. Rockett,et al.  Origin of bulklike structure and bond length disorder of Pt37 and Pt6Ru31 clusters on carbon: comparison of theory and experiment. , 2006, Journal of the American Chemical Society.

[1166]  R. Prins,et al.  The mechanism of formation of the Fe species in Fe/ZSM-5 prepared by CVD , 2001 .

[1167]  A. Russell,et al.  X-ray absorption spectroscopy of low temperature fuel cell catalysts. , 2004, Chemical Reviews.

[1168]  Zhong Ren,et al.  Time-resolved Macromolecular Crystallography Workshop at BioCARS , 2009 .

[1169]  D. Ramaker,et al.  Characterization of Ligand Effects on Water Activation in Triarylphosphine-Stabilized Pt Nanoparticle Catalysts by X-ray Absorption Spectroscopy , 2008 .

[1170]  F. Manjón,et al.  Pressure effects on the structural and electronic properties of ABX4 scintillating crystals , 2008, 0802.0160.

[1171]  C. Lamberti,et al.  Quantification of copper phases, their reducibility and dispersion in doped-CuCl2/Al2O3 catalysts for ethylene oxychlorination. , 2010, Dalton transactions.

[1172]  M. Krisch,et al.  Spectral sharpening of the Pt L edges by high-resolution x-ray emission , 2002 .

[1173]  El-Mekki El-Malki,et al.  Active Sites in Fe/MFI Catalysts for NOx Reduction and Oscillating N2O Decomposition , 2000 .

[1174]  D. Resasco,et al.  High-temperature oxychlorination catalysts: Role of LaCl3 as an inhibitor of the segregation of active species during heating/cooling cycles , 1990 .

[1175]  R. Kumar,et al.  Transition metal-silicate analogs of zeolites , 1993 .

[1176]  H. Renevier,et al.  ELECTRON POPULATION ANALYSIS BY FULL-POTENTIAL X-RAY ABSORPTION SIMULATIONS , 1999 .

[1177]  Omar K Farha,et al.  Metal-organic framework materials as catalysts. , 2009, Chemical Society reviews.

[1178]  C. Lamberti,et al.  Structure and nuclearity of active sites in Fe-zeolites: comparison with iron sites in enzymes and homogeneous catalysts. , 2007, Physical chemistry chemical physics : PCCP.

[1179]  K. Chamberlain The Fine Structure of Certain X-Ray Absorption Edges , 1925 .

[1180]  Kai Chen,et al.  Morphology and microstructure of magnetite and ilmenite inclusions in plagioclase from Adirondack anorthositic gneiss , 2011 .

[1181]  Uwe Bergmann,et al.  Chemical dependence of interatomic X-ray transition energies and intensities – a study of Mn Kβ″ and Kβ2, 5 spectra , 1999 .

[1182]  B. Gates,et al.  Structure and reactivity of a mononuclear gold-complex catalyst supported on magnesium oxide. , 2003, Angewandte Chemie.

[1183]  Christian J. Doonan,et al.  Crystals as molecules: postsynthesis covalent functionalization of zeolitic imidazolate frameworks. , 2008, Journal of the American Chemical Society.

[1184]  A. Frenkel,et al.  Shape-dependent catalytic properties of Pt nanoparticles. , 2010, Journal of the American Chemical Society.

[1185]  D. Ramaker,et al.  Separation of Double-Electron and Atomic XAFS contributions in X-ray Absorption Spectra of Pt foil and Na2Pt(OH)6 , 2002 .

[1186]  Gang Li,et al.  The Direct Synthesis of Hydrogen Peroxide from H2 and O2 over Au/TS-1 and Application in Oxidation of Thiophene in Situ , 2006 .

[1187]  A. Cheetham,et al.  A quantitative description of the active sites in the dehydrated acid catalyst HSAPO-34 for the conversion of methanol to olefins , 1996 .

[1188]  B. Ravel,et al.  ATOMS: crystallography for the X-ray absorption spectroscopist. , 2001, Journal of synchrotron radiation.

[1189]  Development of XAFS theory. , 2003, Journal of synchrotron radiation.

[1190]  Q. Zhu,et al.  Extraframework Fe-Al-O species occluded in MFI zeolite as the active species in the oxidation of benzene to phenol with nitrous oxide , 2003 .

[1191]  D. King,et al.  Sulphur adsorption on Cu{110}: a SEXAFS study , 1991 .

[1192]  Guodong Qian,et al.  Metal-organic frameworks with functional pores for recognition of small molecules. , 2010, Accounts of chemical research.

[1193]  Andreas Heyden,et al.  Nitrous oxide decomposition over Fe-ZSM-5 in the presence of nitric oxide: a comprehensive DFT study. , 2006, The journal of physical chemistry. B.

[1194]  D. Nachtigallová,et al.  Coordination Change of Cu+Sites in ZSM-5 on Excitation in the Triplet State: Understanding of the Photoluminescence Spectra , 2000 .

[1195]  G. Ghiotti,et al.  The chemistry of silica-supported Cr ions: A characterization of the reduced and oxidized forms of chromia/silica catalyst by calorimetry and ultraviolet-visible spectroscopy , 1980 .

[1196]  J. Sinfelt Catalytic Hydrogenolysis over Supported Metals , 1970 .

[1197]  A. Frenkel,et al.  Solving the structure of size-selected Pt nanocatalysts synthesized by inverse micelle encapsulation. , 2010, Journal of the American Chemical Society.

[1198]  C. Lamberti,et al.  Effect of NH3 Adsorption on the Structural and Vibrational Properties of TS-1 , 2002 .

[1199]  L. Pellerito,et al.  Organotin(IV)n+ complexes formed with biologically active ligands: equilibrium and structural studies, and some biological aspects , 2002 .

[1200]  H. Wende,et al.  Surface atomic-XAFS for nitrogen atoms on copper , 1997 .

[1201]  D. E. Keller,et al.  Atomic XAFS as a tool to probe the reactivity of metal oxide catalysts: quantifying metal oxide support effects. , 2007, Journal of the American Chemical Society.

[1202]  K. Hodgson,et al.  GNXAS, A Multiple-Scattering Approach to EXAFS Analysis: Methodology and Applications to Iron Complexes , 1995 .

[1203]  A. Cheetham,et al.  Synchrotron X‐ray and Neutron Diffraction Studies in Solid‐State Chemistry , 1992 .

[1204]  R. Szostak,et al.  Preparation of ferrisilicate ZSM-5 molecular sieves , 1986 .

[1205]  D. Huybrechts,et al.  Oxyfunctionalization of alkanes with hydrogen peroxide on titanium silicalite , 1990, Nature.

[1206]  Reflectivity studies on a synchrotron radiation mirror in the hard X-ray regime , 2001 .

[1207]  J. Smith,et al.  Crystal Structure of Chabazite, a Molecular Sieve , 1958, Nature.

[1208]  M. Newton,et al.  Oxidation/reduction kinetics of supported Rh/Rh2O3 nanoparticles in plug flow conditions using dispersive EXAFS. , 2005, Chemical communications.

[1209]  E. Fois,et al.  Ab Initio Molecular Dynamics Simulation of the Interaction between Water and Ti in Zeolitic Systems , 2004 .

[1210]  A. P. Sorini,et al.  Evidence for weak electronic correlations in Fe-Pnictides , 2009, 0905.2633.

[1211]  M. Piumetti,et al.  The control of selectivity in benzene hydroxylation catalyzed by TS-1: The solvent effect and the role of crystallite size , 2010 .

[1212]  Axel E. Lundh Über dieK-Röntgenabsorptionsspektra der Elemente Si, Ti, V, Cr, Mn und Fe , 1925 .

[1213]  F. Kapteijn,et al.  Utilizing full-exchange capacity of zeolites by alkaline leaching: Preparation of Fe-ZSM5 and application in N2O decomposition , 2006 .

[1214]  P. Magusin,et al.  N2O Decomposition over Fe/ZSM-5: Effect of High-Temperature Calcination and Steaming , 2002 .

[1215]  T. Schmitt,et al.  Observation of multiple Zhang-Rice excitations in a correlated solid: Resonant inelastic X-ray scattering study of Li2CuO2 , 2007 .

[1216]  A Primer in Synchrotron Radiation: Everything You Wanted to Know about SEX (Synchrotron Emission of X-rays) but Were Afraid to Ask. , 1995, Journal of synchrotron radiation.

[1217]  Luc Favre,et al.  Magnetic and structural properties of isolated and assembled clusters , 2005 .

[1218]  M. Fernández-García XANES analysis of catalytic systems under reaction conditions , 2002 .

[1219]  R. Boča,et al.  Spin crossover in iron(II) tris(2-(2-pyridyl)benzimidazole) complex monitored by the variable temperature EXAFS , 2000 .

[1220]  M. Bañares Operando methodology: combination of in situ spectroscopy and simultaneous activity measurements under catalytic reaction conditions , 2005 .

[1221]  Q. Shen,et al.  Hard x-ray microscopy with Fresnel zone plates reaches 40 nm Rayleigh resolution. , 2008 .

[1222]  A. Beale,et al.  Adding a third dimension to operando spectroscopy: a combined UV-Vis, Raman and XAFS setup to study heterogeneous catalysts under working conditions. , 2005, Chemical communications.

[1223]  Uwe Bergmann,et al.  1s2p resonant inelastic X-ray scattering of iron oxides. , 2005, The journal of physical chemistry. B.

[1224]  L. Hegedüs,et al.  Hydrogenation of pyrrole derivatives. II. Hydrogenations over supported noble metal catalysts , 1996 .

[1225]  G. Beni,et al.  Temperature and polarization dependence of extended x-ray absorption fine-structure spectra , 1976 .

[1226]  S. Mohapatra,et al.  Synthesis and characterization of divalent cobalt-substituted mesoporous aluminophosphate molecular sieves and their application as novel heterogeneous catalysts for the oxidation of cycloalkanes , 2005 .

[1227]  N. Binsted,et al.  EXAFS and near-edge structure in the cobalt K-edge absorption spectra of metal carbonyl complexes , 1987 .

[1228]  M. A. Vuurman,et al.  Characterization of chromium oxide supported on Al2O3, ZrO2, TiO2, and SiO2 under dehydrated conditions , 1993 .

[1229]  C. Lamberti,et al.  Structural determination of copper species on the alumina-supported copper chloride catalyst: a detailed EXAFS study , 2003 .

[1230]  B. Weckhuysen,et al.  Bis(mu-oxo)dicopper as intermediate in the catalytic decomposition of NO over Cu-ZSM-5 , 2004 .

[1231]  S. Colonna,et al.  Cell for the in situ study of heterogeneous catalysts by transmission and fluorescence XAS spectroscopy , 1999 .

[1232]  B. Weckhuysen Preface: recent advances in the in-situ characterization of heterogeneous catalysts , 2010 .

[1233]  J. Bokhoven,et al.  Particle Size Effect of Hydride Formation and Surface Hydrogen Adsorption of Nanosized Palladium Catalysts: L3 Edge vs K Edge X-ray Absorption Spectroscopy , 2009 .

[1234]  S. Staniland,et al.  Rapid magnetosome formation shown by real-time x-ray magnetic circular dichroism , 2007, Proceedings of the National Academy of Sciences.

[1235]  A. Arcoya,et al.  Optimization of copper chloride based catalysts for ethylene oxyhydrochlorination , 1982 .

[1236]  D Aberdam SEDEM, a software package for EXAFS data extraction and modelling. , 1998, Journal of synchrotron radiation.

[1237]  Y. Kuroda,et al.  New Analysis of Oxidation State and Coordination Environment of Copper Ion-Exchanged in ZSM-5 Zeolite , 1999 .

[1238]  I. Nam,et al.  N2O decomposition over wet- and solid-exchanged Fe-ZSM-5 catalysts , 2008 .

[1239]  M. Siegbahn Spektroskopie der Röntgenstrahlen , 1931 .

[1240]  L. Guczi,et al.  Bimetallic Cobalt Based Catalysts , 2010 .

[1241]  A. Bianconi,et al.  Relevant role of hydrogen atoms in the XANES of Pd hydride: Evidence of hydrogen induced unoccupied states , 1993 .

[1242]  N. Mizuno,et al.  Novel Preparation Method of Highly Copper Ion-exchanged ZSM-5 Zeolites and Their Catalytic Activities for NO Decomposition , 1990 .

[1243]  Can Li,et al.  UV Raman spectroscopic study on the synthesis mechanism and assembly of molecular sieves. , 2010, Chemical Society reviews.

[1244]  J. Grunwaldt,et al.  In situ EXAFS study on the oxidation state of Pd/Al2O3 and Bi–Pd/Al2O3 during the liquid-phase oxidation of 1-phenylethanol , 2004 .

[1245]  D. Resasco,et al.  Stabilization of the active phase by interaction with the support in CuCl2 oxychlorination catalysts , 1986 .

[1246]  Jihyun An,et al.  High and selective CO2 uptake in a cobalt adeninate metal-organic framework exhibiting pyrimidine- and amino-decorated pores. , 2010, Journal of the American Chemical Society.

[1247]  S. Hasnain,et al.  State-of-the-Art Analysis of Whole X-ray Absorption Spectra. , 1996, Journal of synchrotron radiation.

[1248]  L. Belfiore,et al.  Spectroscopic analysis of transition-metal coordination complexes based on poly(4-vinylpyridine) and dichlorotricarbonylruthenium(II) , 1999 .

[1249]  A. Corma,et al.  Ti/ITQ-2, a new material highly active and selective for the epoxidation of olefins with organic hydroperoxides , 1999 .

[1250]  V. Briois,et al.  Applications in materials science of combining Raman and X-rays at the macro- and micrometric scale , 2009 .

[1251]  P. Frediani,et al.  PREPARATION, CHARACTERIZATION, AND PERFORMANCE OF TRIPODAL POLYPHOSPHINE RHODIUM CATALYSTS IMMOBILIZED ON SILICA VIA HYDROGEN BONDING , 1999 .

[1252]  U. Bergmann,et al.  High-resolution structure of the photosynthetic Mn4Ca catalyst from X-ray spectroscopy , 2008, Philosophical Transactions of the Royal Society B: Biological Sciences.

[1253]  D. Koningsberger,et al.  XAFS characterization of the binuclear iron complex in overexchanged Fe/ZSM5 – structure and reactivity , 2000 .

[1254]  Kazunori Yagi,et al.  New light on the state of active sites in CuZSM-5 for the NO decomposition reaction and N2 adsorption , 2003 .

[1255]  Stacey I. Zones,et al.  Product selectivity in methanol to hydrocarbon conversion for isostructural compositions of AFI and CHA molecular sieves , 1994 .

[1256]  C. Lamberti,et al.  Structure and Enhanced Reactivity of Chromocene Carbonyl Confined inside Cavities of NaY Zeolite , 2009 .

[1257]  William A. Goddard,et al.  Metal−Organic Frameworks Provide Large Negative Thermal Expansion Behavior , 2007 .

[1258]  Y. Iwasawa,et al.  Alternative selective oxidation pathways for aldehyde oxidation and alkene epoxidation on a SiO2-supported Ru-monomer complex catalyst. , 2010, Journal of the American Chemical Society.

[1259]  Hao Shen,et al.  Single-molecule fluorescence imaging of nanocatalytic processes. , 2010, Chemical Society reviews.

[1260]  J. Bünzli,et al.  Lanthanide 8-hydroxyquinoline-based podates with efficient emission in the NIR range. , 2005, Chemical communications.

[1261]  D. Ramaker,et al.  Structure of ethene adsorption sites on supported metal catalysts from in situ XANES Analysis. , 2007, Journal of the American Chemical Society.

[1262]  J. F. Creemer,et al.  Nanoscale chemical imaging of a working catalyst by scanning transmission X-ray microscopy , 2008, Nature.

[1263]  A. S. Rao,et al.  The spectra of Br V, Br VI and Br VII , 1934 .

[1264]  S. Johnson,et al.  Femtosecond XANES Study of the Light-Induced Spin Crossover Dynamics in an Iron(II) Complex , 2009, Science.

[1265]  D. Ramaker,et al.  A new model describing the metal-support interaction in noble metal catalysts , 1999 .

[1266]  G. Reid,et al.  Cr K‐Edge XANES Spectroscopy: Ligand and Oxidation State Dependence — What is Oxidation State? , 2007 .

[1267]  S. Mangani,et al.  Identification of copper(II) binding sites in the aminoglycosidic antibiotic Neomycin B , 2005 .

[1268]  C. Lamberti,et al.  In Situ Characterization of Catalysts Active in Partial Oxidations: TS-1 and Fe-MFI Case Studies , 2002 .

[1269]  J. Rehr,et al.  Parameter-free calculations of X-ray spectra with FEFF9. , 2010, Physical chemistry chemical physics : PCCP.

[1270]  S. Koonin Environmental fine structure in low-energy β-particle spectra , 1991, Nature.

[1271]  Michael J Zaworotko,et al.  Design and synthesis of metal-organic frameworks using metal-organic polyhedra as supermolecular building blocks. , 2009, Chemical Society reviews.

[1272]  B. Sels,et al.  Transition-metal ions in zeolites: coordination and activation of oxygen. , 2010, Inorganic chemistry.

[1273]  H. Renevier,et al.  Grazing Incidence Diffraction Anomalous Fine Structure in the Study of Structural Properties of Nanostructures , 2013 .

[1274]  A. Matzger,et al.  Liquid phase separations by crystalline microporous coordination polymers , 2010 .

[1275]  M. Chergui,et al.  A full multiple scattering model for the analysis of time-resolved X-ray difference absorption spectra. , 2006, The journal of physical chemistry. B.

[1276]  C. Lamberti,et al.  Orthorhombic to monoclinic phase transition in high-Ti-loaded TS-1: an attempt to locate Ti in the MFI framework by low temperature XRD , 2000 .

[1277]  A. Urakawa,et al.  Size selectivity of a copper metal-organic framework and origin of catalytic activity in epoxide alcoholysis. , 2009, Chemistry.

[1278]  T. Root,et al.  DFT Study of Solvent Coordination Effects on Titanium-Based Epoxidation Catalysts. Part One: Formation of the Titanium Hydroperoxo Intermediate , 2003 .

[1279]  Omar M Yaghi,et al.  Isoreticular metalation of metal-organic frameworks. , 2009, Journal of the American Chemical Society.

[1280]  A. Scherz,et al.  A systematic study of embedded atom EXAFS: the (2 × 1)O/Cu(110) reconstruction as an ideal prototype system , 2003 .

[1281]  N. Bârsan,et al.  Operando X-ray absorption spectroscopy studies on Pd-SnO2 based sensors. , 2009, Physical chemistry chemical physics : PCCP.

[1282]  Marius Vaarkamp,et al.  Obtaining reliable structural parameters from EXAFS , 1998 .

[1283]  Craig M. Brown,et al.  Hydrogen storage in a microporous metal-organic framework with exposed Mn2+ coordination sites. , 2006, Journal of the American Chemical Society.

[1284]  S. Nguyen,et al.  A Zn-based, pillared paddlewheel MOF containing free carboxylic acids via covalent post-synthesis elaboration. , 2009, Chemical communications.

[1285]  H. Kung,et al.  Study of Supported PtCu and PdAu Bimetallic Nanoparticles Using In-Situ X-ray Tools† , 2010 .

[1286]  Edward A. Stern,et al.  Extended x-ray-absorption fine-structure technique. III. Determination of physical parameters , 1975 .

[1287]  Richard P Van Duyne,et al.  Resonance Raman and surface- and tip-enhanced Raman spectroscopy methods to study solid catalysts and heterogeneous catalytic reactions. , 2010, Chemical Society reviews.

[1288]  Joachim Sauer,et al.  Finding transition structures in extended systems: A strategy based on a combined quantum mechanics–empirical valence bond approach , 2000 .

[1289]  J. Hazemann,et al.  Structural relaxation around substitutional Cr3+ in MgAl2O4 , 2007, 0704.0878.

[1290]  V. Bailey XLIII. The mental multiplication and division of large numbers , 1921 .

[1291]  L. Kustov,et al.  Investigation of the different states of gallium in crystalline gallosilicates with pentasil structure and their role in propane aromatization , 1990 .

[1292]  S. Kitagawa,et al.  Photoactivation of a nanoporous crystal for on-demand guest trapping and conversion. , 2010, Nature materials.

[1293]  Theoretical Interpretation of XAFS and XANES in Pt Clusters , 2002 .

[1294]  G. Spoto,et al.  Spectroscopic Studies (UV-Vis and FTIR) of CO and Ethene Molecular-Complexes and of Ethene Oligomerization on Alpha-Cr2O3 Surfaces , 1994 .

[1295]  R. Schlögl,et al.  Investigation of Ammonia Oxidation over Copper with In Situ NEXAFS in the Soft X-Ray Range: Influence of Pressure on the Catalyst Performance , 2001 .

[1296]  Axel E. Lindh Zur Kenntnis des Röntgenabsorptionsspektrums von Chlor , 1921 .

[1297]  B. Weckhuysen,et al.  Redox behaviour of over-exchanged Fe/ZSM5 zeolites studied with in-situ soft X-ray absorption spectroscopy , 2003 .

[1298]  K. Schwarz,et al.  Electronic structure of solids with WIEN2k , 2010 .

[1299]  B. Batterman,et al.  Dynamical Diffraction of X Rays by Perfect Crystals , 1964 .

[1300]  H. Kitagawa,et al.  Highly proton-conductive copper coordination polymer, H2dtoaCu (H2dtoa=dithiooxamide anion) , 2003 .

[1301]  García,et al.  Multielectron excitations in the K-edge x-ray-absorption near-edge spectra of V, Cr, and Mn 3d0 compounds with tetrahedral coordination. , 1991, Physical review. B, Condensed matter.

[1302]  C. Lamberti,et al.  Hydrogen adsorption and spill-over effects on H–Y and Pd-containing Y zeolites: An experimental and theoretical investigation , 2006 .

[1303]  D. P. Woodruff Adsorbate structure determination using photoelectron diffraction: Methods and applications , 2007 .

[1304]  R. Prins,et al.  Time-resolved in situ XAS study of the preparation of supported gold clusters. , 2007, Physical chemistry chemical physics : PCCP.

[1305]  A. Miyamoto,et al.  Highly selective synthesis of light olefins from methanol on a novel Fe-silicate , 1986 .

[1306]  C. Lamberti,et al.  The role of chlorine and additives on the density and strength of Lewis and Brønsted acidic sites of γ-Al2O3 support used in oxychlorination catalysis: A FTIR study , 2011 .

[1307]  R. M. Lambert,et al.  In situ studies of catalysts under reaction conditions by total electron-yield XAS: Possibilities and limitations of a new experimental technique , 1996 .

[1308]  E. Wolf,et al.  In situ EXAFS and FTIR studies of the promotion behavior of Pt–Nb2O5/Al2O3 catalysts during the preferential oxidation of CO , 2009 .

[1309]  Hans-Dieter Martin,et al.  Das Mülheimer Normaldruck‐Polyäthylen‐Verfahren , 1955 .

[1310]  C. Lamberti,et al.  Structure–activity relationships of simple molecules adsorbed on CPO-27-Ni metal–organic framework: In situ experiments vs. theory , 2012 .

[1311]  A. A. Shteinman,et al.  Evolution of Iron States and Formation of α-Sites upon Activation of FeZSM-5 Zeolites , 2002 .

[1312]  T. Ressler WinXAS: a program for X-ray absorption spectroscopy data analysis under MS-Windows. , 1998, Journal of synchrotron radiation.

[1313]  C. Lamberti,et al.  Ti location in the MFI framework of Ti-Silicalite-1: a neutron powder diffraction study. , 2001, Journal of the American Chemical Society.

[1314]  Céline Chizallet,et al.  H2‐Induced Reconstruction of Supported Pt Clusters: Metal–Support Interaction versus Surface Hydride , 2011 .

[1315]  C. Rovira,et al.  A nanoporous molecular magnet with reversible solvent-induced mechanical and magnetic properties , 2003, Nature materials.

[1316]  Z. Sobalík,et al.  Coordination of Cu Ions in High-Silica Zeolite Matrixes. Cu+ Photoluminescence, IR of NO Adsorbed on Cu2+, and Cu2+ ESR Study , 1995 .

[1317]  P. Claus,et al.  Catalytic and Mechanistic Investigation of Polyaniline Supported PtO2Nanoparticles: A Combinedin situ/operandoEPR, DRIFTS, and EXAFS Study , 2008 .

[1318]  Mark E. Davis,et al.  Studies on the Catalytic-Oxidation of Alkanes and Alkenes by Titanium Silicates , 1994 .

[1319]  A. Corma,et al.  Ti-ferrierite and TiITQ-6: synthesis and catalytic activity for the epoxidation of olefins with H2O2 , 2000 .

[1320]  H. Padmore,et al.  The undulator beamline at the SRS Daresbury , 1992 .

[1321]  A. Frenkel,et al.  Characterization of palladium nanoparticles by using X-ray reflectivity, EXAFS, and electron microscopy. , 2006, Langmuir : the ACS journal of surfaces and colloids.

[1322]  Zhirong Huang,et al.  A review of x-ray free-electron laser theory. , 2007 .

[1324]  Manuel Sánchez Del Ruío,et al.  NPI, a Code for EXAFS Data Analysis , 1995, Comput. Chem..

[1325]  Freek Kapteijn,et al.  Building MOF bottles around phosphotungstic acid ships: One-pot synthesis of bi-functional polyoxometalate-MIL-101 catalysts , 2010 .

[1326]  Hydrogen storage in Chabazite zeolite frameworks. , 2005, Physical chemistry chemical physics : PCCP.

[1327]  E. Stern,et al.  Extended x-ray-absorption fine-structure technique. II. Experimental practice and selected results , 1975 .

[1328]  H Li,et al.  Modular chemistry: secondary building units as a basis for the design of highly porous and robust metal-organic carboxylate frameworks. , 2001, Accounts of chemical research.

[1329]  C. Lamberti,et al.  XAFS study of Ti-silicalite: structure of framework Ti(IV) in presence and in absence of reactive molecules (H2O, NH3) , 1994 .

[1330]  G. M. De Luca,et al.  Magnetic excitations and phase separation in the underdoped La2-xSrxCuO4 superconductor measured by resonant inelastic X-ray scattering. , 2010, Physical review letters.

[1331]  C. Lamberti,et al.  Characterisation of defective silicalites , 2000 .

[1332]  F. Kapteijn,et al.  NO Adsorption on Ex-Framework [Fe,X]MFI Catalysts: Novel IR Bands and Evaluation of Assignments , 2002 .

[1333]  N. Motta,et al.  EXAFS measurements on FeB metallic glasses: Asymmetry of the radial distribution function , 1981 .

[1334]  C. Natoli,et al.  Full quantitative multiple-scattering analysis of X-ray absorption spectra: application to potassium hexacyanoferrat(II) and -(III) complexes. , 2004, Journal of the American Chemical Society.

[1335]  J. Čejka,et al.  CATALYTIC ACTIVITY OF CU ION-EXCHANGED METALLOALUMINOPHOSPHATES IN NO DECOMPOSITION , 1998 .

[1336]  Andrew M. Beale,et al.  Combined time-resolved X-ray scattering and spectroscopy methods , 2012 .

[1337]  K. Baberschke,et al.  New opportunities in soft X-ray absorption to characterise the adsorbate bonding , 2000 .

[1338]  Tianxi Liu,et al.  A new method for extracting x-ray absorption fine structure and the atomic background from an x-ray absorption spectrum , 1997 .

[1339]  N. Takagi,et al.  In situ redispersion of platinum autoexhaust catalysts: an on-line approach to increasing catalyst lifetimes? , 2008, Angewandte Chemie.

[1340]  A. Beale,et al.  EXAFS as a tool to interrogate the size and shape of mono and bimetallic catalyst nanoparticles. , 2010, Physical chemistry chemical physics : PCCP.

[1341]  N. Rösch,et al.  Comparison of all sites for Ti substitution in zeolite TS-1 by an accurate embedded-cluster method. , 2005, The journal of physical chemistry. B.

[1342]  G. Tian,et al.  Ordered mesoporous titanosilicates with catalytically stable and active four-coordinated titanium sites. , 2004, Chemical communications.

[1343]  Uwe Bergmann,et al.  The electronic structure of Mn in oxides, coordination complexes, and the oxygen-evolving complex of photosystem II studied by resonant inelastic X-ray scattering. , 2004, Journal of the American Chemical Society.

[1344]  G. Spoto,et al.  Formation of CuI—N2 adducts at 298 and 77 K in CuI-ZSM-5: an FTIR investigation , 1995 .

[1345]  C. Lamberti,et al.  A Multitechnique Approach to Spin-Flips for Cp2Cr(II) Chemistry in Confined State , 2010 .

[1346]  A. Dent,et al.  In situ, time resolved, and simultaneous multi-edge determination of local order change during reduction of supported bimetallic (Pt–Ge) catalyst precursors using energy dispersive EXAFS , 2001 .

[1347]  P. Sermon,et al.  Nature of oxide-supported copper(II) ions and copper derived from copper(II) chloride , 1987 .

[1348]  W. Bras,et al.  A new experimental cell for in situ and operandoX-ray absorption measurements in heterogeneous catalysis. , 2005, Journal of synchrotron radiation.

[1349]  Jeroen van den Brink,et al.  Resonant Inelastic X-ray Scattering Studies of Elementary Excitations , 2010, 1009.3630.

[1350]  Simon J L Billinge,et al.  Beyond crystallography: the study of disorder, nanocrystallinity and crystallographically challenged materials with pair distribution functions. , 2004, Chemical communications.

[1351]  J. Smith Crystal structures with a chabazite framework. I. Dehydrated Ca-chabazite , 1962 .

[1352]  J. Eckert,et al.  The siting of Ti in TS-1 is non-random. Powder neutron diffraction studies and theoretical calculations of TS-1 and FeS-1 , 2000 .

[1353]  A. Delabie,et al.  The Coordination of CuII in Zeolites − Structure and Spectroscopic Properties , 2002 .

[1354]  S. Doniach,et al.  Theory of extended x-ray absorption edge fine structure (EXAFS) in crystalline solids , 1975 .

[1355]  V. Dufaud,et al.  Supported metallocene catalysts by surface organometallic chemistry. Synthesis, characterization, and reactivity in ethylene polymerization of oxide-supported mono- and biscyclopentadienyl zirconium alkyl complexes: establishment of structure/reactivity relationships. , 2001, Journal of the American Chemical Society.

[1356]  Christoph Rau,et al.  Microimaging and tomography with chemical speciation , 2003 .

[1357]  G. Thornton,et al.  The initial stages of Cr and Ti growth on SiO2(0001) , 1999 .

[1358]  W. A. Dench,et al.  Quantitative electron spectroscopy of surfaces: A standard data base for electron inelastic mean free paths in solids , 1979 .

[1359]  A. Urakawa,et al.  Space-Resolved Profiling Relevant in Heterogeneous Catalysis , 2009 .

[1360]  J. Lercher,et al.  Sulfate formation on SOx trapping materials studied by Cu and S K-edge XAFS. , 2005, Physical chemistry chemical physics : PCCP.

[1361]  Sang Soo Han,et al.  Recent advances on simulation and theory of hydrogen storage in metal-organic frameworks and covalent organic frameworks. , 2009, Chemical Society reviews.

[1362]  Jeffrey R. Long,et al.  Strong H2 Binding and Selective Gas Adsorption within the Microporous Coordination Solid Mg3(O2C-C10H6-CO2)3 , 2005 .

[1363]  K. Schwarz,et al.  Electronic structure calculations of solids using the WIEN2k package for material sciences , 2002 .

[1364]  Irina Snigireva,et al.  Nanofocusing parabolic refractive x-ray lenses , 2003 .

[1365]  G. Ertl,et al.  Handbook of Heterogeneous Catalysis , 1997 .

[1366]  Samuel M. Webb,et al.  SIXpack: a graphical user interface for XAS analysis using IFEFFIT , 2005 .

[1367]  J. Sinfelt,et al.  Structure of bimetallic clusters , 1987 .

[1368]  A. Bell,et al.  Characterization of Cu-ZSM-5 Prepared by Solid-State Ion Exchange of H-ZSM-5 with CuCl , 2006 .

[1369]  A. Jentys,et al.  Estimation of mean size and shape of small metal particles by EXAFS , 1999 .

[1370]  Jie Zheng,et al.  Promoted H2 generation from NH3BH3 thermal dehydrogenation catalyzed by metal-organic framework based catalysts. , 2010, Chemistry.

[1371]  M. Sierka,et al.  Coordination of Cu+ Ions to Zeolite Frameworks Strongly Enhances Their Ability To Bind NO2. An ab Initio Density Functional Study , 1998 .

[1372]  F. d’Acapito,et al.  μ-EXAFS, μ-XRF, and μ-PL characterization of a multi-quantum-well electroabsorption modulated laser realized via selective area growth. , 2011, Small.

[1373]  A. A. Shteinman,et al.  Kinetic isotope effects and mechanism of biomimetic oxidation of methane and benzene on FeZSM-5 zeolite , 1997 .

[1374]  B. Sels,et al.  Coordination chemistry and reactivity of copper in zeolites , 2013 .

[1375]  A. Frenkel,et al.  Synchrotron Studies of Catalysts: From XAFS to QEXAFS and Beyond , 2009 .

[1376]  R. Nuzzo,et al.  The atomic structural dynamics of γ-Al2O3 supported Ir-Pt nanocluster catalysts prepared from a bimetallic molecular precursor: a study using aberration-corrected electron microscopy and X-ray absorption spectroscopy. , 2011, Journal of the American Chemical Society.

[1377]  Rochus Schmid,et al.  Exploring Network Topologies of Copper Paddle Wheel Based Metal–Organic Frameworks with a First-Principles Derived Force Field , 2011 .

[1378]  Mark A. Rodriguez,et al.  Capture of volatile iodine, a gaseous fission product, by zeolitic imidazolate framework-8. , 2011, Journal of the American Chemical Society.

[1379]  A. Cheetham,et al.  A neutron diffraction and infrared spectroscopy study of the acid form of the aluminosilicate zeolite, chabazite (H- SSZ-13) , 1997 .

[1380]  J. Pérez-Pariente,et al.  The state of Ti in titanoaluminosilicates isomorphous with zeolite .beta. , 1993 .

[1381]  G. Pirngruber,et al.  The characterisation and catalytic properties of biomimetic metal-peptide complexes immobilised on mesoporous silica. , 2009, Physical chemistry chemical physics : PCCP.

[1382]  H. Ebert,et al.  Fully relativistic theory for the magnetic extended x-ray absorption fine structure , 1998 .

[1383]  K. Lillerud,et al.  Designing Heterogeneous Catalysts by Incorporating Enzyme-Like Functionalities into MOFs , 2010 .

[1384]  A. Dent,et al.  Rapid monitoring of the nature and interconversion of supported catalyst phases and of their influence upon performance: CO oxidation to CO2 by gamma-Al2O3 supported Rh catalysts. , 2006, Chemistry.

[1385]  Mark E. Davis Ordered porous materials for emerging applications , 2002, Nature.

[1386]  M. Fernández-García,et al.  Hard X-ray Photon-In Photon-Out Spectroscopy , 2009 .

[1387]  L. Dubrovinsky,et al.  Development of micro-XANES mapping in the diamond anvil cell. , 2009, Journal of synchrotron radiation.

[1388]  M. Newton,et al.  Combining synchrotron-based X-ray techniques with vibrational spectroscopies for the in situ study of heterogeneous catalysts: a view from a bridge. , 2010, Chemical Society reviews.

[1389]  A. Bell,et al.  Synthesis of dimethyl carbonate and dimethoxy methane over Cu-ZSM-5 , 2006 .

[1390]  Cross,et al.  Diffraction anomalous fine structure: A new x-ray structural technique. , 1992, Physical review letters.

[1391]  Carlo Lamberti,et al.  A new zirconium inorganic building brick forming metal organic frameworks with exceptional stability. , 2008, Journal of the American Chemical Society.

[1392]  B. Smit,et al.  Entropy effects during sorption of alkanes in zeolites. , 2002, Chemical Society reviews.

[1393]  Wu Zhou Nanostructural and Chemical Characterization of Supported Metal Oxide Catalysts by Aberration Corrected Analytical Electron Microscopy , 2012 .

[1394]  M. Niwa,et al.  High catalytic activity for synthesis of aniline from phenol and ammonia found on gallium-containing MFI , 1999 .

[1395]  M. Roeffaers,et al.  Fluorescence micro(spectro)scopy as a tool to study catalytic materials in action. , 2010, Chemical Society reviews.

[1396]  H. N. Chapman,et al.  Imaging Atomic Structure and Dynamics with Ultrafast X-ray Scattering , 2007, Science.

[1397]  C. Lamberti,et al.  Evidence of the Presence of Two Different Framework Ti(IV) Species in Ti−Silicalite-1 in Vacuo Conditions: an EXAFS and a Photoluminescence Study , 1998 .

[1398]  K. Chao,et al.  Characterization of heterogeneous catalysts by X-ray absorption spectroscopy , 2001 .

[1399]  R. Frahm,et al.  The energy dispersive X-ray absorption spectrometer DEXAFS at HASYLAB , 1989 .

[1400]  Katrin F. Domke,et al.  Label-free chemical imaging of catalytic solids by coherent anti-Stokes Raman scattering and synchrotron-based infrared microscopy. , 2009, Angewandte Chemie.

[1401]  M. Clerici,et al.  Epoxidation of Lower Olefins with Hydrogen Peroxide and Titanium Silicalite , 1993 .

[1402]  K. A. Dubkov,et al.  Selective oxidation of methane to methanol on a FeZSM-5 surface , 1995 .

[1403]  A. Corma,et al.  Titanium-Catalyzed Heterogeneous Oxidations of Silanes, Chiral Allylic Alcohols, 3-Alkylcyclohexanes, and Thianthrene 5-Oxide: A Comparison of the Reactivities and Selectivities for the Large-Pore Zeolite Ti-β, the Mesoporous Ti-MCM-41, and the Layered Alumosilicate Ti-ITQ-2 , 2000 .

[1404]  C. Roth,et al.  Kinetics of CO Poisoning in Simulated Reformate and Effect of Ru Island Morphology on PtRu Fuel Cell Catalysts As Determined by Operando X-ray Absorption Near Edge Spectroscopy , 2007 .

[1405]  J. Hazemann,et al.  FAME: a new beamline for x-ray absorption investigations of very-diluted systems of environmental, material and biological interests , 2005 .

[1406]  H Bornebusch,et al.  A new approach for QEXAFS data acquisition. , 1999, Journal of synchrotron radiation.

[1407]  M. Sawada,et al.  Fine Structures of X-ray Absorption Spectra of Crystalline and Amorphous Germanium , 1957 .

[1408]  I. Arčon,et al.  Manganese-Containing Silica-Based Microporous Molecular Sieve MnS-1: Synthesis and Characterization , 2003 .

[1409]  A. MacDowell,et al.  A soft/hard x-ray beamline for surface EXAFS studies in the energy range 0. 8--15 keV , 1989 .

[1410]  R. Frahm,et al.  Quick scanning exafs: First experiments , 1988 .

[1411]  G. Spoto,et al.  Fourier-transform infrared and Raman spectra of pure and Al-, B-, Ti- and Fe-substituted silicalites: stretching-mode region , 1993 .

[1412]  Nigel M. Allinson,et al.  PDA system for energy dispersive EXAFS , 1988 .

[1413]  Lin X. Chen,et al.  Revealing Structural Dynamics in Catalytic Reactions Using Ultrafast Transient X-ray Absorption Spectroscopy , 2009 .

[1414]  Rachel B. Getman,et al.  Review and analysis of molecular simulations of methane, hydrogen, and acetylene storage in metal-organic frameworks. , 2012, Chemical reviews.

[1415]  A. Barbier,et al.  A new UHV diffractometer for surface structure and real time molecular beam deposition studies with synchrotron radiations at ESRF , 1999 .

[1416]  H. Frei,et al.  Photochemical and FT-IR probing of the active site of hydrogen peroxide in Ti silicalite sieve. , 2002, Journal of the American Chemical Society.

[1417]  I. Robinson,et al.  Direct separation of short range order in intermixed nanocrystalline and amorphous phases. , 2002, Physical review letters.

[1418]  C. Serre,et al.  Large breathing effects in three-dimensional porous hybrid matter: facts, analyses, rules and consequences. , 2009, Chemical Society reviews.

[1419]  D. Coster,et al.  Bestimmung des Absorptionskoeffizienten für Röntgenstrahlen in der Nähe derK-Absorptionskante der Elemente Cu und Zn , 1931 .

[1420]  C. Catlow,et al.  Computer simulation of Fe-ZSM5 — comparison to EXAFS studies , 1995 .

[1421]  Y. Iwasawa,et al.  A new method for quantitative characterization of adsorbed hydrogen on Pt particles by means of Pt L-edge XANES , 1996 .

[1422]  A. Becke A New Mixing of Hartree-Fock and Local Density-Functional Theories , 1993 .

[1423]  L. Böhm The ethylene polymerization with Ziegler catalysts: fifty years after the discovery. , 2003, Angewandte Chemie.

[1424]  C. Garino,et al.  Synchrotron ultrafast techniques for photoactive transition metal complexes , 2013, Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences.

[1425]  A. Corma,et al.  AlITQ-6 and TiITQ-6: Synthesis, Characterization, and Catalytic Activity We thank the Spanish CICYT for financial support (project MAT97-1016-C02-01 and project MAT97-1207-C03-01). U.D. and M.E.D. thank the M.E.C. and M.E.A., respectively, for funding their doctoral fellowships. , 2000, Angewandte Chemie.

[1426]  M. Schoonen,et al.  The Structure of Ferrihydrite, a Nanocrystalline Material , 2007, Science.

[1427]  G. Panov,et al.  Room-Temperature Oxidation of Methane by α-Oxygen and Extraction of Products from the FeZSM-5 Surface , 2011 .

[1428]  J. Fierro,et al.  The usefulness of time-dependent density functional theory to describe the electronic spectra of ti-containing catalysts. , 2003, Angewandte Chemie.

[1429]  J. Grunwaldt,et al.  Catalysts at work: From integral to spatially resolved X-ray absorption spectroscopy , 2009 .

[1430]  D. Siddons,et al.  Elimination of the inner-shell lifetime broadening in x-ray-absorption spectroscopy. , 1991, Physical review letters.

[1431]  G. Sankar,et al.  The role of synchrotron-based studies in the elucidation and design of active sites in titanium-silica epoxidation catalysts. , 2001, Accounts of chemical research.

[1432]  Z. Tang,et al.  Metal−Organic Framework Supported Gold Nanoparticles as a Highly Active Heterogeneous Catalyst for Aerobic Oxidation of Alcohols , 2010 .

[1433]  G. Mickelson,et al.  Design and operation of a high pressure reaction cell for in situ X-ray absorption spectroscopy , 2007 .

[1434]  R. Schmid,et al.  Metal@MOF: loading of highly porous coordination polymers host lattices by metal organic chemical vapor deposition. , 2005, Angewandte Chemie.

[1435]  D. Koningsberger,et al.  A new method for parameterization of phase shift and backscattering amplitude , 1995 .

[1436]  M. Stockenhuber,et al.  An Hermite expansion method for EXAFS data treatment and its application to Fe K-edge spectra , 2000 .

[1437]  A. Corma,et al.  Metal–organic frameworks as semiconductors , 2010 .

[1438]  G. Frenking,et al.  Nonclassical Metal Carbonyls: Appropriate Definitions with a Theoretical Justification. , 1998, Angewandte Chemie.

[1439]  M. Chergui,et al.  Structural determination of a photochemically active diplatinum molecule by time-resolved EXAFS spectroscopy. , 2009, Angewandte Chemie.

[1440]  Y. Tsurita,et al.  Structure of an aluminosilicophosphate , 1985 .

[1441]  M. Di Michiel,et al.  Combining time-resolved hard X-ray diffraction and diffuse reflectance infrared spectroscopy to illuminate CO dissociation and transient carbon storage by supported Pd nanoparticles during CO/NO cycling. , 2010, Journal of the American Chemical Society.

[1442]  Shuichi Kagawa,et al.  Removal of nitrogen monoxide through a novel catalytic process. 1. Decomposition on excessively copper-ion-exchanged ZSM-5 zeolites , 1991 .

[1443]  Hong-Cai Zhou,et al.  Selective gas adsorption and separation in metal-organic frameworks. , 2009, Chemical Society reviews.

[1444]  A. Corma,et al.  Nanoparticles of Pd on Hybrid Polyoxometalate−Ionic Liquid Material: Synthesis, Characterization, and Catalytic Activity for Heck Reaction , 2010 .

[1445]  T. Yokoyama,et al.  Adsorption of SO2 on Cu(100) studied by X-ray absorption fine structure spectroscopy and scanning tunneling microscopy , 1997 .

[1446]  S. Kaliaguine,et al.  Titanium sites in titanium silicalites: An XPS, XANES and EXAFS study , 1992 .

[1447]  A. Corma,et al.  Synthesis, Characterization, and Catalytic Activity of Ti-MCM-41 Structures , 1995 .

[1448]  G. Pirngruber,et al.  The surface chemistry of N2O decomposition on iron-containing zeolites (II)—The effect of high-temperature pretreatments , 2004 .

[1449]  Saeed Amirjalayer,et al.  First-Principles-Derived Force Field for Copper Paddle-Wheel-Based Metal−Organic Frameworks , 2010 .

[1450]  C. Lamberti,et al.  Local Structure of Framework Cu(II) in HKUST-1 Metallorganic Framework: Spectroscopic Characterization upon Activation and Interaction with Adsorbates , 2006 .

[1451]  Daofeng Sun,et al.  An interweaving MOF with high hydrogen uptake. , 2006, Journal of the American Chemical Society.

[1452]  K Wille,et al.  Synchrotron radiation sources , 1991 .

[1453]  P. Milani,et al.  Beta environmental fine structure characterization of defects , 1999 .

[1454]  R. A. Santen,et al.  Catalytic Activity of Titanium Silicalites—a DFT Study , 1998 .

[1455]  A. Ankudinov,et al.  Effect of hydrogen adsorption on the x-ray absorption spectra of small Pt clusters. , 2001, Physical review letters.

[1456]  John J. Rehr,et al.  Progress in the theory and interpretation of XANES , 2005 .

[1457]  E. Solomon,et al.  Electronic structures of active sites on metal oxide surfaces: definition of the copper-zinc oxide methanol synthesis catalyst by photoelectron spectroscopy , 1993 .

[1458]  Masaki Abe,et al.  Selective Reduction of NO with Propylene on Fe-silicate Catalysts , 1991 .

[1459]  G. Leofanti,et al.  Comparison of H2Adsorption, O2Adsorption, H2Titration, and O2Titration on Supported Palladium Catalysts , 1999 .

[1460]  L. Belfiore,et al.  Macromolecule–metal complexes: ligand field stabilization and thermophysical property modification , 2001 .

[1461]  M Newville,et al.  IFEFFIT: interactive XAFS analysis and FEFF fitting. , 2001, Journal of synchrotron radiation.

[1462]  R. Wagner,et al.  K X-RAY ABSORPTION SPECTRA OF GERMANIUM IN CRYSTALLINE AND IN AMORPHOUS GeO$sub 2$ , 1962 .

[1463]  Omar M Yaghi,et al.  Gas Adsorption Sites in a Large-Pore Metal-Organic Framework , 2005, Science.

[1464]  Uwe Bergmann,et al.  X-ray emission spectroscopy , 2009, Photosynthesis Research.

[1465]  L. Stievano,et al.  Real time monitoring of the evolution of Ni2+ environment in faujasite upon rehydration by in situ dispersive-EXAFS , 2005 .

[1466]  L. Valenzano,et al.  Heats of adsorption of CO and CO2 in metal-organic frameworks: Quantum mechanical study of CPO-27-M (M = Mg, Ni, Zn) , 2011 .

[1467]  P. Juhás,et al.  Local Structure of Bulk and Nanocrystalline Semiconductors Using Total Scattering Methods , 2013 .