Unexpected formation of a “flyover-bridged” complex by reaction of a “ferrole” derivative with Ph2PCH2PPh2 (dppm) and Me3NO. Crystal structure of [Fe2(CO)5(P-dppm){C2Et2(CO)C2Et2}]

[1]  R. Heyn,et al.  Reactions of alkynes with coordinatively unsaturated (.eta.5-C5Me5)Ru derivatives. X-ray crystal structures of (.eta.5-C5Me5)Cl2Ru(.eta.2:.eta.4-.mu.2-C4H4)Ru(.eta.5-C5Me5) and (.eta.5-C5Me5)3Ru3(.mu.2-Cl)2(.mu.3-Cl)(.eta.2-.mu.2-HC.tplbond.CSiMe3) , 1990 .

[2]  M. Botta,et al.  Spectroscopic and electrochemical study of trinuclear ferracyclopentadienyl clusters [Fe3(.mu.-CO)2(CO)6(RC2R)2] , 1989 .

[3]  R. J. Angelici,et al.  Platinum(0) complexes as catalysts of metal carbonyl substitution reactions , 1988 .

[4]  M. Bruce Some reactions of ruthenium cluster carbonyls under mild conditions , 1987 .

[5]  D. Osella,et al.  Dynamic behavior of the flyover bridge complexes M2(CO)5L {.mu.-[C(R):C(R')]2CO} (M = Ru, Fe; L = CO, PPh3, AsPh3, SbPh3; R, R' = Me, Ph) , 1986 .

[6]  Y. Jeannin,et al.  Réactivité du diéthylamino-1-propyne vis-à-vis de [Fe3(CO)12] Et [Fe2(CO)9]. Synthèses et structures de [Fe2(CO)6{C5O(CH3)2(N(C2H5)2)2}], [Fe2(CO)8{C4(CH3)2(N(C2H5)2)2}], [Fe2(CO)7{C2(CH3)N(C2H5)2}] ET [Fe3(CO)8{C4(CH3)2(N(C2H5)2)2}]☆ , 1986 .

[7]  Jack Lewis,et al.  The preparation, characterization and some reactions of [Ru3(CO)11(NCMe)] and [Ru3(CO)10(NCMe)2] , 1985 .

[8]  M. Botta,et al.  Activation of the M-CO Bond in Transition-Metal Complexes. Fe2(CO)6(SMe)2 and Phosphine-Substituted Derivatives as Good Catalysts in Metal-Carbonyl Substitution Reactions , 1985 .

[9]  N. Coville The reaction between [?5-C5H5M(CO)3]2, ?5-C5H5M(CO)3I (M _ Mo, W) and isonitriles , 1981 .

[10]  G. Cash,et al.  The X-ray structure of [Me3SiC4SiMe3]2Fe2(CO)7: a σ—π-type bonding complex between a diacetylene and Iron carbonyl , 1979 .

[11]  R. Hoffmann,et al.  Hexacarbonyl(ligand)dimetal complexes , 1978 .

[12]  K. Folting,et al.  Dynamics and structure of some tricarbonylferrole-iron tricarbonyl derivatives , 1976 .

[13]  F. Cotton,et al.  Structural and carbon-13 nuclear resonance studies of compounds containing the hexacarbonyldiiron entity. I. Hexacarbonyl[.mu.-(1,2,5-.eta.:1,4,5-.eta.)-3-oxo-1,2,4,5-tetraphenyl-1,4-pentadiene-1,5-diyl]diiron(Fe-Fe) , 1976 .

[14]  E. Weiss,et al.  Über Organometall‐Komplexe, IX. Über die Reaktion von Eisencarbonylen mit Acetylen unter Druck , 1962 .