Characteristics of particulates and gaseous pollutants in a highway tunnel

Characteristics of air pollutants in a highway tunnel were studied in Osaka, Japan. The size distributions and concentrations of elemental carbon (EC) and organic carbon (OC) were measured. The results demonstrated that EC was the predominant constituent of particulates in the tunnel, which accounted for 71% by mass of the particulate matter (PM) of less than 2 μm in aerodynamic diameter. EC concentration increased linearly with increase in diesel traffic volume and the coefficient of correlation was found to be at a significant level (r=0.93, p<0.001). In contrast, OC size distribution was bimodal with peaks in the size ranges of less than 1 and 2–10 μm and not clearly dependent on diesel traffic volume. For the gaseous matter, nitrogen monoxide (NO) was found to be the major component of NOx (over 90%) and its concentration was proportional to the traffic volume of diesel vehicles (r=0.82, p<0.001). The concentrations of carbon monoxide (CO) and carbon dioxide (CO2) in the tunnel were found, by multi-regression analysis, to be dependent on both diesel and gasoline-powered vehicles.

[1]  K. W. Nicholson A review of particle resuspension , 1988 .

[2]  Thomas W. Kirchstetter,et al.  On-Road Emissions of Particulate Polycyclic Aromatic Hydrocarbons and Black Carbon from Gasoline and Diesel Vehicles , 1998 .

[3]  Roy M. Harrison,et al.  Source Apportionment of Atmospheric Polycyclic Aromatic Hydrocarbons Collected from an Urban Location in Birmingham, U.K. , 1996 .

[4]  M. F. Phillips,et al.  Determination of organic and elemental carbon in atmospheric aerosol samples by thermal evolution , 1982 .

[5]  S. Friedlander,et al.  Size distributions of polycyclic aromatic hydrocarbons and elemental carbon. 1. Sampling, measurement methods, and source characterization. , 1994, Environmental science & technology.

[6]  M. Kodama,et al.  Biological effects of diesel exhaust particles. I. In vitro production of superoxide and in vivo toxicity in mouse. , 1993, Free radical biology & medicine.

[7]  Ronald A. Hites,et al.  Identification of organic compounds on diesel engine soot , 1981 .

[8]  S. Friedlander,et al.  Size distributions of polycyclic aromatic hydrocarbons and elemental carbon. 2. Ambient measurements and effects of atmospheric processes. , 1994, Environmental science & technology.

[9]  Timo Mäkelä,et al.  Characterization of the Particulate Phase in the Exhaust from a Diesel Car , 1997 .

[10]  Roy M. Harrison,et al.  Sources and processes affecting concentrations of PM10 and PM2.5 particulate matter in Birmingham (U.K.) , 1997 .

[11]  J. C. Ball,et al.  Catalyst-free sodium borohydride reduction as a guide in the identification of direct-acting Ames assay mutagens in diesel-particle extracts. , 1987, Mutation research.

[12]  J G Kretzschmar,et al.  Air pollution measurements in traffic tunnels. , 1994 .

[13]  H. Hayashi,et al.  Analysis of Particulate Carbon and Other Elements Using Elemental Analyzer , 1985 .

[14]  Werner A. Stahel,et al.  Aerosol emission in a road tunnel , 1997 .

[15]  R. L. Dod,et al.  Tunnel measurements of the PAH, carbon thermogram and elemental source signature for vehicular exhaust , 1984 .