Build direction dependence of microstructure and high-temperature tensile property of Co–Cr–Mo alloy fabricated by electron beam melting

Abstract The microstructures and high-temperature tensile properties of a Co–28Cr–6Mo–0.23C–0.17N alloy fabricated by electron beam melting (EBM) with cylindrical axes deviating from the build direction by 0°, 45°, 55° and 90° were investigated. The preferred crystal orientations of the γ phase in the as-EBM-built samples with angles of 0°, 45°, 55° and 90° were near [0 0 1], [1 1 0], [1 1 1] and [1 0 0], respectively. M23C6 precipitates (M = Cr, Mo or Si) were observed to align along the build direction with intervals of around 3 μm. The phase was completely transformed into a single e-hexagonal close-packed (hcp) phase after aging treatment at 800 °C for 24 h, when lamellar colonies of M2N precipitates and the e-hcp phase appeared in the matrix. Among the samples, the one built with 55° deviation had the highest ultimate tensile strength of 806 MPa at 700 °C. The relationship between the microstructure and the build direction dependence of mechanical properties suggested that the conditions of heat treatment to homogenize the microstructure throughout the height of the EBM-built object should be determined by taking into account the thermal history during the post-melt period of the EBM process, especially when the solid–solid transformation is sluggish.

[1]  W. Betteridge Cobalt and its alloys , 1982 .

[2]  Naoyuki Nomura,et al.  Significant Improvement in Mechanical Properties of Biomedical Co-Cr-Mo Alloys with Combination of N Addition and Cr-Enrichment , 2008 .

[3]  Lei Zhang,et al.  Microstructure analysis of plasma nitrided cast/forged CoCrMo alloys , 2010 .

[4]  D Coutsouradis,et al.  Cobalt-based superalloys for applications in gas turbines☆ , 1987 .

[5]  J.L. Martinez,et al.  Comparison of Microstructures and Mechanical Properties for Solid and Mesh Cobalt-Base Alloy Prototypes Fabricated by Electron Beam Melting , 2010 .

[6]  Ryan B. Wicker,et al.  Next Generation Orthopaedic Implants by Additive Manufacturing Using Electron Beam Melting , 2012, International journal of biomaterials.

[7]  Ryan B. Wicker,et al.  Characterization of titanium aluminide alloy components fabricated by additive manufacturing using electron beam melting , 2010 .

[8]  Zushu Hu,et al.  Secondary carbide precipitation in a directionally solified cobalt-base superalloy , 1999 .

[9]  A. Chiba,et al.  Mechanical Properties of Biomedical Co-33Cr-5Mo-0.3N Alloy at Elevated Temperatures , 2008 .

[10]  Yunping Li,et al.  Deformation mode in biomedical Co–27% Cr–5% Mo alloy consisting of a single hexagonal close-packed structure , 2010 .

[11]  Shingo Kurosu,et al.  Grain refinement of biomedical Co-27Cr-5Mo-0.16N alloy by reverse transformation , 2010 .

[12]  Olivier Bouaziz,et al.  Correlations between the calculated stacking fault energy and the plasticity mechanisms in Fe–Mn–C alloys , 2004 .

[13]  N. Nomura,et al.  Microstructure and mechanical properties of biomedical Co–29Cr–8Mo alloy wire fabricated by a modified melt-spinning process , 2007 .

[14]  Damien Fabrègue,et al.  The damage process in a biomedical Co–29Cr–6Mo–0.14N alloy analyzed by X-ray tomography and electron backscattered diffraction , 2011 .

[15]  N. Nomura,et al.  Pin-on-disk wear behavior in a like-on-like configuration in a biological environment of high carbon cast and low carbon forged Co–29Cr–6Mo alloys , 2007 .

[16]  M. Calcagnotto,et al.  Orientation gradients and geometrically necessary dislocations in ultrafine grained dual-phase steels studied by 2D and 3D EBSD , 2010 .

[17]  A. Chiba,et al.  Origin of Significant Grain Refinement in Co-Cr-Mo Alloys Without Severe Plastic Deformation , 2012, Metallurgical and Materials Transactions A.

[18]  Ryan B. Wicker,et al.  Novel precipitate–microstructural architecture developed in the fabrication of solid copper components by additive manufacturing using electron beam melting , 2011 .

[19]  Yifu Shen,et al.  Recrystallization in a directionally solidified cobalt-base superalloy , 2008 .

[20]  A. D. J. Saldívar García,et al.  Formation of hcp martensite during the isothermal aging of an fcc Co-27Cr-5Mo-0.05C orthopedic implant alloy , 1999 .

[21]  Yunping Li,et al.  Strain-induced martensitic transformation near twin boundaries in a biomedical Co–Cr–Mo alloy with negative stacking fault energy , 2013 .

[22]  L. Murr,et al.  Microstructural Architecture, Microstructures, and Mechanical Properties for a Nickel-Base Superalloy Fabricated by Electron Beam Melting , 2011 .

[23]  C. Montero-Ocampo,et al.  Effect of fcc-hcp phase transformation produced by isothermal aging on the corrosion resistance of a Co-27Cr-5Mo-0.05C alloy , 2002 .

[24]  Ryan B. Wicker,et al.  Characterization of Ti–6Al–4V open cellular foams fabricated by additive manufacturing using electron beam melting , 2010 .

[25]  Shingo Kurosu,et al.  Isothermal Phase Transformation in Biomedical Co-29Cr-6Mo Alloy without Addition of Carbon or Nitrogen , 2010 .

[26]  G. B. Olson,et al.  A general mechanism of martensitic nucleation: Part I. General concepts and the FCC → HCP transformation , 1976 .

[27]  L. Dominey,et al.  Cobalt and Cobalt Alloys , 2010 .

[28]  A. Chiba,et al.  Mechanical properties of as-forged Ni-free Co–29Cr–6Mo alloys with ultrafine-grained microstructure , 2011 .

[29]  Xiaoxia Huang,et al.  Superalloys: Alloying and Performance , 2010 .