Interference effects in the relaxation of a pair of unlike spin-1/2 nuclei

Abstract The theory of magnetic relaxation of each line of a doublet in a pair I-S of unlike spin - 1 2 nuclei with indirect coupling, in the presence of both dipolar I-S coupling and anisotropic chemical shift, in the frame of density-matrix master-equation formalism is derived. An experimental scheme for accurately measuring differential line broadening in the doublet is proposed.

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