论文信息 - Oxidation of ethane and propane with cobalt(II) catalyst: unexpected formation of 1,2-diol esters and C–C bond cleavage

Oxidation of ethane and propane with cobalt(II) catalyst: unexpected formation of 1,2-diol esters and C–C bond cleavage

Ethane reacts with both cobalt(III) and O2–cobalt(II) in trifluoroacetic acid solution to form ethyl trifluoroacetate and 1,2-bistrifluoroacetoxyethane in successive reactions, along with the products of C–C bond cleavage; propane undergoes similar oxidative reactions.

I. Moiseev | M. N. Vargaftik | D. A. Shishkin | I. P. Stolarov | I. I. Moiseev

[1] A. Herring,et al. Selective hydroxylation of methyl groups by platinum salts in aqueous medium. Direct conversion of ethanol to ethylene glycol , 1990 .

[2] I. Moiseev,et al. Highly selective partial oxidation of methane to methyl trifluoroacetate , 1990 .

[3] W. Mijs,et al. Organic Syntheses by Oxidation with Metal Compounds , 1986 .

[4] F. Freeman. Oxidations by Cobalt Compounds , 1986 .

[5] A. Onopchenko,et al. Electron transfer with aliphatic substrates Oxidation of Cyclohexane with cobalt(III) ions alone and in the presence of oxygen , 1973 .

[6] A. Onopchenko,et al. Oxidation of butane with cobalt salts and oxygen via electron transfer , 1973 .

[7] J. Hanotier,et al. Low-temperature oxidation of n-alkanes by cobaltic acetate activated by strong acids , 1972 .

[8] W. J. Koehl,et al. Oxidation by metal salts. V. Cobaltic acetate oxidation of alkylbenzenes , 1969 .

[9] R. L. Hunt,et al. Aromatic Oxidation by Electron Transfer. I. Oxidations of p-Methoxytoluene , 1966 .