Multiplet exchange Auger transitions following resonant Auger decays in Ne 1s photoexcitation

Secondary electron emission with very low kinetic energy (KE) has been measured in the Ne 1s photoexcitation region. A new decay channel for Auger transitions following Ne 1s to 3p excitation has been identified using a two-dimensional mapping technique, in which slow Auger electron signals are displayed as functions of electron kinetic energy and photon energy. Electrons with about 0.68 eV KEs have been ascribed to multiplet exchange Auger electrons from the 2p−2(1S)3d state. This state is formed through the resonant Auger transition from the 1s−13p state, in which the excited 3p electron changes its azimuthal quantum number. Another cascade Auger decay of multiplet exchanging was found as electron emission of about 2.0 eV KEs; 2p−2(1S)4p → 2p−2(3P) + e−. Several cascade decays were found to occur via the photoexcitation into 1s−14p and 1s−15p states.

[1]  V. D. Mur,et al.  Current progress in developing the nonlinear ionization theory of atoms and ions , 2015 .

[2]  José N Onuchic,et al.  A semi-analytical description of protein folding that incorporates detailed geometrical information. , 2011, The Journal of chemical physics.

[3]  Y. Tamenori,et al.  Projection of Si 1s photoexcited orbitals into resonant Auger electron spectra in KLL decays of Si(CH3)4 and SiF4. , 2011, The Journal of chemical physics.

[4]  J. Viefhaus,et al.  Dynamics of electron emission in double photoionization processes near the krypton 3d threshold , 2008 .

[5]  T. Kaneyasu,et al.  Autoionization dynamics of core-valence doubly excited states in N2 , 2007 .

[6]  Y. Tamenori,et al.  Absolute Photoionization Cross Section with an Ultra‐high Energy Resolution for Ne in the Region of 1s Rydberg States , 2007 .

[7]  H. Tanaka,et al.  A study of inner-valence Auger transitions in Ne+ induced by the resonant Auger decay of photoexcited Ne 1s−1np states , 2006 .

[8]  N. Kabachnik,et al.  Population of individual Ne 1s-1np Rydberg states measured across the 1s ionization threshold and the evolution of shake-up into shake-down , 2006 .

[9]  Marcello Coreno,et al.  Study of electronic correlations in the Auger cascade decay from Ne*1s−13p , 2005 .

[10]  K. Ueda,et al.  A study of photoelectron recapture due to post-collision interaction in Ne at the 1s photoionization threshold , 2005 .

[11]  H. Tanaka,et al.  Investigation of valence inter-multiplet Auger transitions in Ne following 1s photoelectron recapture , 2005 .

[12]  Nora Berrah,et al.  An investigation of dissociative resonant photoionization in HCl and DCl using two-dimensional photoelectron spectroscopy , 2005 .

[13]  Y. Kawabe,et al.  Study of second-step Auger transitions in Auger cascades following 1s → 3p photoexcitation in Ne , 2005 .

[14]  Hiroshi Tanaka,et al.  Photoelectron recapture as a tool for the spectroscopy of ionic Rydberg states , 2004 .

[15]  T. Ishikawa,et al.  Linear Polarization Measurements of Soft X‐ray Emitted from a Figure‐8 Undulator by Using Multilayers , 2004 .

[16]  U. Heinzmann,et al.  LETTER TO THE EDITOR: Photoelectron recapture observed via second-step Auger decay , 2004 .

[17]  N. Kabachnik,et al.  Doppler-free resonant Raman auger spectroscopy of Ne+ 2s2p(5)3p excited states. , 2003, Physical review letters.

[18]  M. Coreno,et al.  High-resolution threshold photoelectron measurements of the Ne+ 2p4nℓ satellite states , 2002 .

[19]  T. Ishikawa,et al.  Performance of a grating monochromator at BL27SU beamline of SPring-8 in the higher energy region , 2002 .

[20]  T. Ishikawa,et al.  Outline of soft X-ray photochemistry beamline BL27SU of SPring-8 , 2001 .

[21]  M. Coreno,et al.  Correlation effects in Auger cascade studied by angle resolved Coincidence Electron Spectroscopy: the 1s->3p excitation in neon , 2001 .

[22]  S. Aksela,et al.  Auger decay at the 1s−1np (n=3–5) resonances of Ne , 2001 .

[23]  N. Kabachnik,et al.  Interference effects in the branching ratio for the partial decay channels of the Ne (1s-13p) resonance , 2000 .

[24]  Hiroshi Tanaka,et al.  High resolution angle-resolved measurements of Auger emission from the photo-excited 1s-13p state of Ne , 2000 .

[25]  H. Ohashi,et al.  Angle-resolved study of the Auger electron cascades following the 1s→3p photoexcitation of Ne , 2000 .

[26]  W. C. Martin,et al.  Atomic Spectra Database , 1999 .

[27]  J. Bozek,et al.  Two-dimensional imaging of atoms and molecules using angle-resolved, electron time-of-flight spectroscopy at the ALS , 1998 .

[28]  Mika Kivilompolo,et al.  Evolution of the Post-Collision-Interaction Profile from the Resonant Auger Shakeup /Shakedown Lines at the Ionization Threshold , 1997 .

[29]  V. Schmidt,et al.  Electron Spectrometry of Atoms using Synchrotron Radiation , 1997 .

[30]  Y. Hikosaka,et al.  Formation of autoionizing atomic nitrogen from superexcited states of nitric oxide , 1996 .

[31]  S. Aksela,et al.  Auger decay of resonantly excited ( n = 5, 6, 7, 8 and 9) states , 1996 .

[32]  M. Biermann,et al.  Electronic state-lifetime interference observed at Ne K inter-resonance excitation , 1996 .

[33]  G. Armen Spectator excitation accompanying core Auger decay in atoms: a hydrogenic model , 1996 .

[34]  Ito,et al.  State-to-state behavior in the neutral dissociation of O2 far beyond the ionization threshold. , 1995, Physical review letters.

[35]  Becker,et al.  Multiplet-changing Auger transitions in valence double photoionization. , 1993, Physical Review A. Atomic, Molecular, and Optical Physics.

[36]  F. Larkins,et al.  Valence-multiplet Auger decay of the doubly excited (vp2)nl states of neon and argon , 1992 .

[37]  W. Persson,et al.  The Spectrum of Singly Ionized Neon, Ne II , 1971 .

[38]  K. Siegbahn ESCA applied to free molecules , 1969 .