Dissociative electron transfer mechanism and application in the electrocatalytic activation of organic halides

[1]  Karthish Manthiram,et al.  Toward Improving the Selectivity of Organic Halide Electrocarboxylation with Mechanistically Informed Solvent Selection , 2023, Journal of the American Chemical Society.

[2]  W. Mitch,et al.  Electrochemical Reduction of Halogenated Alkanes and Alkenes Using Activated Carbon-Based Cathodes. , 2022, Environmental science & technology.

[3]  Teera Chantarojsiri,et al.  Toward green syntheses of carboxylates: Considerations of mechanisms and reactions at the electrodes for electrocarboxylation of organohalides and alkenes , 2022, Chinese Journal of Catalysis.

[4]  Shengqi Zhang,et al.  MOF-derived Single Site Catalysts with Electron-Rich Fe-N4 sites for Efficient Elimination of Trichloroacetamide DBP , 2022, Chemical Engineering Journal.

[5]  De‐Yin Wu,et al.  A DFT and SERS Study of Synergistic Roles of Thermodynamics and Kinetics During the Electrocatalytic Reduction Benzyl Chloride at Silver Cathodes , 2022, Journal of Electroanalytical Chemistry.

[6]  Feng Wu,et al.  Pyridinic nitrogen enables dechlorination of trichloroethylene to acetylene by green rust: Performance, mechanism and applications. , 2022, The Science of the total environment.

[7]  Xuxu Wang,et al.  Electrocatalytic activation of organic chlorides via direct and indirect electron transfer using atomic vacancy control of palladium-based catalyst , 2022, Cell Reports Physical Science.

[8]  Xinyong Li,et al.  Effects of Oxygen Functional Groups on Electrochemical Performance of Carbon Materials for Dechlorination of 1,2-Dichloroethane to Ethylene , 2022, Chemical Engineering Journal.

[9]  Xenia V. Medvedeva,et al.  Relative activity of metal cathodes towards electroorganic coupling of CO2 with benzylic halides , 2021 .

[10]  L. A. Baker,et al.  Electroreduction of Acetochlor at Silver Cathodes in Aqueous Media , 2021, Journal of The Electrochemical Society.

[11]  Jia‐Xing Lu,et al.  Electrocatalytic carboxylation of halogenated compounds with mesoporous silver electrode materials , 2021, RSC advances.

[12]  Ruohan Yu,et al.  Efficient carboxylation of styrene and carbon dioxide by single-atomic copper electrocatalyst. , 2021, Journal of colloid and interface science.

[13]  A. Vertova,et al.  Hydrodehalogenation of Polychloromethanes on Silver‐Based Gas Diffusion Electrodes , 2021, ChemElectroChem.

[14]  Z. Lou,et al.  Electrocatalytic dechlorination of 2,4-DCBA using CTAB functionalized Pd/GAC movable granular catalyst: Role of adsorption in catalysis , 2021, Chemical Engineering Journal.

[15]  Hanqing Yu,et al.  Integrating single-cobalt-site and electric field of boron nitride in dechlorination electrocatalysts by bioinspired design , 2021, Nature communications.

[16]  M. Siddiqui,et al.  Efficient Co-MoS2 electrocatalyst for cathodic degradation of halogenated disinfection by-products in water sample , 2020 .

[17]  Yifan Zheng,et al.  Facile and Economical Electrochemical Dehalogenative Deuteration of (Hetero)Aryl Halides , 2020, CCS Chemistry.

[18]  L. A. Baker,et al.  Direct Electrochemical Reduction of Acetochlor at Carbon and Silver Cathodes in Dimethylformamide , 2020, Journal of The Electrochemical Society.

[19]  G. Sulka,et al.  A facile approach to silver nanowire array electrode preparation and its application for chloroform reduction , 2020 .

[20]  Pravin P Ingole,et al.  Mechanistic insight into the electrocatalytic performance of reduced graphene oxide supported palladium, silver and palladium-silver nanodeposits toward electro-dehalogenation of halocarbons in room temperature ionic liquids. , 2020, Physical chemistry chemical physics : PCCP.

[21]  Xinyong Li,et al.  Active Sites in Single-Atom Fe-Nx-C Nanosheets for Selectively Electrochemical Dechlorination of 1,2-Dichloroethane to Ethylene. , 2020, ACS nano.

[22]  Wen-qian Chen,et al.  Insights into Electroreductive Dehalogenation Mechanisms of Chlorinated Environmental Pollutants , 2020 .

[23]  T. Breugelmans,et al.  Electrochemical reduction of halogenated aromatic compounds at metal cathodes in acetonitrile , 2020, Electrochimica Acta.

[24]  Xenia V. Medvedeva,et al.  Electrochemical CO2 Fixation to α-Methylbenzyl Bromide in Divided Cells with Nonsacrificial Anodes and Aqueous Anolytes , 2019, ACS Sustainable Chemistry & Engineering.

[25]  Aicheng Chen,et al.  Identification of Catalytic Active Sites in Nitrogen-Doped Carbon for Electrocatalytic Dechlorination of 1,2-Dichloroethane , 2019, ACS Catalysis.

[26]  Silvia Mena,et al.  Electrocarboxylation of halobenzonitriles: An environmentally friendly synthesis of phthalate derivatives , 2019, Electrochimica Acta.

[27]  B. Ni,et al.  Recent advances in electrocatalysts for halogenated organic pollutant degradation , 2019, Environmental Science: Nano.

[28]  Silvia Mena,et al.  Electrocarboxylation of 1-chloro-(4-isobutylphenyl)ethane with a silver cathode in ionic liquids: an environmentally benign and efficient way to synthesize Ibuprofen , 2019, RSC advances.

[29]  Silvia Mena,et al.  Electrocatalytic Processes for the Valorization of CO2: Synthesis of Cyanobenzoic Acid Using Eco-Friendly Strategies , 2019, Catalysts.

[30]  Aijie Wang,et al.  Ultrafine palladium nanoparticles supported on 3D self-supported Ni foam for cathodic dechlorination of florfenicol , 2019, Chemical Engineering Journal.

[31]  R. Weiss,et al.  Toward resolving the budget discrepancy of ozone-depleting carbon tetrachloride (CCl4): an analysis of top-down emissions from China , 2018, Atmospheric Chemistry and Physics.

[32]  Jia‐Xing Lu,et al.  Highly Efficient Electrocatalytic Carboxylation of 1-Phenylethyl Chloride at Cu Foam Cathode , 2018, Catalysts.

[33]  H. Ertan,et al.  Organohalide Respiring Bacteria and Reductive Dehalogenases: Key Tools in Organohalide Bioremediation , 2016, Front. Microbiol..

[34]  K. Fisher,et al.  Reductive dehalogenase structure suggests a mechanism for B12-dependent dehalogenation , 2014, Nature.

[35]  A. Gennaro,et al.  Electrochemical activation of carbon–halogen bonds: Electrocatalysis at silver/copper nanoparticles , 2014 .

[36]  A. Gennaro,et al.  Electrocatalytic dechlorination of polychloroethylenes at silver cathode , 2013, Journal of Applied Electrochemistry.

[37]  A. Gennaro,et al.  Electrocatalytic dechlorination of volatile organic compounds at a copper cathode. Part I: Polychloromethanes , 2012 .

[38]  A. Gennaro,et al.  Electrocatalytic properties of transition metals toward reductive dechlorination of polychloroethanes , 2012 .

[39]  Q. Guo,et al.  Electrochemical synthesis of adiponitrile from the renewable raw material glutamic acid. , 2012, ChemSusChem.

[40]  A. Gennaro,et al.  One-pot synthesis of benzoic acid by electrocatalytic reduction of bromobenzene in the presence of CO2 , 2011 .

[41]  Hans J. Schäfer,et al.  Contributions of organic electrosynthesis to green chemistry , 2011 .

[42]  Christian Amatore,et al.  In situ identification of intermediates of benzyl chloride reduction at a silver electrode by SERS coupled with DFT calculations. , 2010, Journal of the American Chemical Society.

[43]  A. Gennaro,et al.  Electrochemical hydrodehalogenation of polychloromethanes at silver and carbon electrodes , 2009 .

[44]  C. Costentin,et al.  Passage from stepwise to concerted dissociative electron transfer through modulation of electronic states coupling. , 2009, Chemistry.

[45]  A. Gennaro,et al.  Electrocatalytic carboxylation of chloroacetonitrile at a silver cathode for the synthesis of cyanoacetic acid , 2008 .

[46]  P. Poizot,et al.  The one-electron cleavage and reductive homo-coupling of alkyl bromides at silver–palladium cathodes , 2008 .

[47]  A. Gennaro,et al.  Dissociative electron transfer to organic chlorides: electrocatalysis at metal cathodes. , 2008, Physical chemistry chemical physics : PCCP.

[48]  C. Maccato,et al.  Silver nanoparticles deposited on glassy carbon. Electrocatalytic activity for reduction of benzyl chloride , 2006 .

[49]  P. Mussini,et al.  Electrochemical reduction of benzyl halides at a silver electrode , 2006 .

[50]  J. Savéant,et al.  Electron transfer and bond breaking: Recent advances , 2006 .

[51]  J. Simonet The copper-palladium cathode to achieve pure one-electron cleavages: The case of alkyl bromides , 2005 .

[52]  G. Sello,et al.  Electroreduction of volatile organic halides on activated silver cathodes , 2005 .

[53]  J. Savéant,et al.  Fragmentation of aryl halide pi anion radicals. Bending of the cleaving bond and activation vs driving force relationships. , 2004, Journal of the American Chemical Society.

[54]  A. Vertova,et al.  Electrocatalysis on silver and silver alloys for dichloromethane and trichloromethane dehalogenation , 2004 .

[55]  J. Savéant,et al.  Successive Removal of Chloride Ions from Organic Polychloride Pollutants. Mechanisms of Reductive Electrochemical Elimination in Aliphatic Gem-Polychlorides, α,β-Polychloroalkenes, and α,β-Polychloroalkanes in Mildly Protic Medium , 2003 .

[56]  A. Gennaro,et al.  Dissociative electron transfer to haloacetonitriles. An example of the dependency of in-cage ion-radical interactions upon the leaving group. , 2002, Journal of the American Chemical Society.

[57]  A. Gennaro,et al.  Electrochemical Synthesis of Cyanoacetic Acid from Chloroacetonitrile and Carbon Dioxide , 2002 .

[58]  A. Gennaro,et al.  Nickel(I)(salen)-electrocatalyzed reduction of benzyl chlorides in the presence of carbon dioxide , 2001 .

[59]  J. Savéant,et al.  Can Single-Electron Transfer Break an Aromatic Carbon−Heteroatom Bond in One Step? A Novel Example of Transition between Stepwise and Concerted Mechanisms in the Reduction of Aromatic Iodides , 1999 .

[60]  A. Gennaro,et al.  Mechanism of the electrochemical reduction of benzyl chlorides catalysed by Co(salen) , 1998 .

[61]  A. Gennaro,et al.  Electrocatalysis at palladium nanoparticles: Effect of the support nitrogen doping on the catalytic activation of carbonhalogen bond , 2014 .

[62]  A. Gennaro,et al.  Electrocatalytic Activation of Aromatic Carbon-Bromine Bonds toward Carboxylation at Silver and Copper Cathodes , 2013 .

[63]  A. Gennaro,et al.  Electrocatalytic carboxylation of benzyl chlorides at silver cathodes in acetonitrile. , 2002, Chemical communications.