Perovskite photonic sources

The prospects for light-emitting diodes and lasers based on perovskite materials are reviewed. The field of solution-processed semiconductors has made great strides; however, it has yet to enable electrically driven lasers. To achieve this goal, improved materials are required that combine efficient (>50% quantum yield) radiative recombination under high injection, large and balanced charge-carrier mobilities in excess of 10 cm2 V−1 s−1, free-carrier densities greater than 1017 cm−3 and gain coefficients exceeding 104 cm−1. Solid-state perovskites are — in addition to galvanizing the field of solar electricity — showing great promise in photonic sources, and may be the answer to realizing solution-cast laser diodes. Here, we discuss the properties of perovskites that benefit light emission, review recent progress in perovskite electroluminescent diodes and optically pumped lasers, and examine the remaining challenges in achieving continuous-wave and electrically driven lasing.

[1]  Donal D. C. Bradley,et al.  Fluorene-based polymer gain media for solid-state laser emission across the full visible spectrum , 2003 .

[2]  Aram Amassian,et al.  Ligand-Stabilized Reduced-Dimensionality Perovskites. , 2016, Journal of the American Chemical Society.

[3]  A. Köhler Organic semiconductors: No more breaks for electrons. , 2012, Nature materials.

[4]  Oleksandr Voznyy,et al.  Perovskite Thin Films via Atomic Layer Deposition , 2015, Advanced materials.

[5]  Yizheng Jin,et al.  Solution-processed, high-performance light-emitting diodes based on quantum dots , 2014, Nature.

[6]  D. Kabra,et al.  Near Infrared to Visible Electroluminescent Diodes Based on Organometallic Halide Perovskites: Structural and Optical Investigation , 2015 .

[7]  Qingfeng Dong,et al.  Electron-hole diffusion lengths > 175 μm in solution-grown CH3NH3PbI3 single crystals , 2015, Science.

[8]  Abhishek Swarnkar,et al.  Colloidal CsPbBr3 Perovskite Nanocrystals: Luminescence beyond Traditional Quantum Dots. , 2015, Angewandte Chemie.

[9]  H. Zeng,et al.  Nonlinear Absorption and Low-Threshold Multiphoton Pumped Stimulated Emission from All-Inorganic Perovskite Nanocrystals. , 2016, Nano letters.

[10]  Sandeep Kumar Pathak,et al.  Perovskite Crystals for Tunable White Light Emission , 2015 .

[11]  M. Grätzel,et al.  Title: Long-Range Balanced Electron and Hole Transport Lengths in Organic-Inorganic CH3NH3PbI3 , 2017 .

[12]  Robert P. H. Chang,et al.  Lead-free solid-state organic–inorganic halide perovskite solar cells , 2014, Nature Photonics.

[13]  Shaojun Guo,et al.  Room Temperature Single-Photon Emission from Individual Perovskite Quantum Dots. , 2015, ACS nano.

[14]  Felix Deschler,et al.  Bright light-emitting diodes based on organometal halide perovskite. , 2014, Nature nanotechnology.

[15]  Mohammad Khaja Nazeeruddin,et al.  Improved performance and stability of perovskite solar cells by crystal crosslinking with alkylphosphonic acid ω-ammonium chlorides. , 2015, Nature chemistry.

[16]  Tetsuo Tsutsui,et al.  Organic‐inorganic heterostructure electroluminescent device using a layered perovskite semiconductor (C6H5C2H4NH3)2PbI4 , 1994 .

[17]  R. Friend,et al.  Blue-Green Color Tunable Solution Processable Organolead Chloride–Bromide Mixed Halide Perovskites for Optoelectronic Applications , 2015, Nano letters.

[18]  Nripan Mathews,et al.  Low-temperature solution-processed wavelength-tunable perovskites for lasing. , 2014, Nature materials.

[19]  S. Xiao,et al.  Formation of single-mode laser in transverse plane of perovskite microwire via micromanipulation. , 2016, Optics letters.

[20]  Chang-Lyoul Lee,et al.  Multicolored Organic/Inorganic Hybrid Perovskite Light‐Emitting Diodes , 2015, Advanced materials.

[21]  M. Fiebig,et al.  Low-threshold amplified spontaneous emission and lasing from colloidal nanocrystals of caesium lead halide perovskites , 2015, Nature Communications.

[22]  A. McGaughey,et al.  Surface chemistry mediates thermal transport in three-dimensional nanocrystal arrays. , 2013, Nature materials.

[23]  Yang Yang,et al.  Polymer solar cells , 2012, Nature Photonics.

[24]  Henry J. Snaith,et al.  Direct measurement of the exciton binding energy and effective masses for charge carriers in organic–inorganic tri-halide perovskites , 2015, 1504.07025.

[25]  J. Kim,et al.  CZTS based thin film solar cells: a status review , 2013 .

[26]  Sudheer Gurugubelli Structural and optical investigation , 2015 .

[27]  Dmitri V Talapin,et al.  Low-threshold stimulated emission using colloidal quantum wells. , 2013, Nano letters.

[28]  Biwu Ma,et al.  Bright Light‐Emitting Diodes Based on Organometal Halide Perovskite Nanoplatelets , 2016, Advanced materials.

[29]  Illan J. Kramer,et al.  The architecture of colloidal quantum dot solar cells: materials to devices. , 2014, Chemical reviews.

[30]  Eli Yablonovitch,et al.  Strong Internal and External Luminescence as Solar Cells Approach the Shockley–Queisser Limit , 2012, IEEE Journal of Photovoltaics.

[31]  Chang-ling Zou,et al.  Output Coupling of Perovskite Lasers from Embedded Nanoscale Plasmonic Waveguides. , 2016, Journal of the American Chemical Society.

[32]  Edward H Sargent,et al.  Conformal organohalide perovskites enable lasing on spherical resonators. , 2014, ACS nano.

[33]  Young Chan Kim,et al.  Compositional engineering of perovskite materials for high-performance solar cells , 2015, Nature.

[34]  Song Jin,et al.  Nanowire Lasers of Formamidinium Lead Halide Perovskites and Their Stabilized Alloys with Improved Stability. , 2016, Nano letters.

[35]  Sandeep Kumar Pathak,et al.  High Photoluminescence Efficiency and Optically Pumped Lasing in Solution-Processed Mixed Halide Perovskite Semiconductors. , 2014, The journal of physical chemistry letters.

[36]  Thomas Walton An Environmental Perspective on Brand Design , 2010 .

[37]  R. H. Friend,et al.  Lasing from conjugated-polymer microcavities , 1996, Nature.

[38]  M. Green,et al.  The emergence of perovskite solar cells , 2014, Nature Photonics.

[39]  Rudiger Quay,et al.  Analysis and Simulation of Heterostructure Devices , 2004 .

[40]  Sorin P. Voinigescu,et al.  High-Frequency Integrated Circuits , 2013 .

[41]  Henry J Snaith,et al.  Metal-halide perovskites for photovoltaic and light-emitting devices. , 2015, Nature nanotechnology.

[42]  Arto Nurmikko,et al.  Red, green and blue lasing enabled by single-exciton gain in colloidal quantum dot films. , 2012, Nature nanotechnology.

[43]  J. Noh,et al.  Chemical management for colorful, efficient, and stable inorganic-organic hybrid nanostructured solar cells. , 2013, Nano letters.

[44]  Jay B. Patel,et al.  Enhanced Amplified Spontaneous Emission in Perovskites Using a Flexible Cholesteric Liquid Crystal Reflector. , 2015, Nano letters.

[45]  Tze Chien Sum,et al.  Room-temperature near-infrared high-Q perovskite whispering-gallery planar nanolasers. , 2014, Nano letters.

[46]  M. Saidaminov,et al.  The In‐Gap Electronic State Spectrum of Methylammonium Lead Iodide Single‐Crystal Perovskites , 2016, Advanced materials.

[47]  Hadis Morko,et al.  Handbook of Nitride Semiconductors and Devices , 2008 .

[48]  Oleksandr Voznyy,et al.  Highly efficient quantum dot near-infrared light-emitting diodes , 2016, Nature Photonics.

[49]  Junji Kido,et al.  Solution-processed multilayer small-molecule light-emitting devices with high-efficiency white-light emission , 2014, Nature Communications.

[50]  Song Jin,et al.  Lead halide perovskite nanowire lasers with low lasing thresholds and high quality factors. , 2015, Nature materials.

[51]  Roberto Cingolani,et al.  Continuous-wave biexciton lasing at room temperature using solution-processed quantum wells. , 2014, Nature nanotechnology.

[52]  Laura M. Herz,et al.  Electron-Hole Diffusion Lengths Exceeding 1 Micrometer in an Organometal Trihalide Perovskite Absorber , 2013, Science.

[53]  A. Ralph Carli,et al.  A Status Review , 1938 .

[54]  O. Voznyy,et al.  Crosslinked Remote‐Doped Hole‐Extracting Contacts Enhance Stability under Accelerated Lifetime Testing in Perovskite Solar Cells , 2016, Advanced materials.

[55]  B. Lee,et al.  High-performance perovskite light-emitting diodes via morphological control of perovskite films. , 2016, Nanoscale.

[56]  O. Voznyy,et al.  Microsecond-sustained lasing from colloidal quantum dot solids , 2015, Nature Communications.

[57]  Polymer/Perovskite Amplifying Waveguides for Active Hybrid Silicon Photonics , 2015, Advanced materials.

[58]  R. N. Marks,et al.  Light-emitting diodes based on conjugated polymers , 1990, Nature.

[59]  Markus Pollnau,et al.  Organic solid‐state integrated amplifiers and lasers , 2012 .

[60]  M. Grätzel,et al.  Sequential deposition as a route to high-performance perovskite-sensitized solar cells , 2013, Nature.

[61]  Nam-Gyu Park,et al.  Organolead Halide Perovskite: New Horizons in Solar Cell Research , 2014 .

[62]  Endre Horváth,et al.  Ultra-Low Thermal Conductivity in Organic-Inorganic Hybrid Perovskite CH3NH3PbI3. , 2014, The journal of physical chemistry letters.

[63]  M. Castro,et al.  Optical Investigation of Broadband White-Light Emission in Self-Assembled Organic–Inorganic Perovskite (C6H11NH3)2PbBr4 , 2015 .

[64]  John B. Asbury,et al.  Random lasing in organo-lead halide perovskite microcrystal networks , 2014 .

[65]  Henry J. Snaith,et al.  The renaissance of dye-sensitized solar cells , 2012, Nature Photonics.

[66]  R. F. Leheny,et al.  Direct Determination of Optical Gain in Semiconductor Crystals , 1971 .

[67]  Dawei Di,et al.  Efficient light-emitting diodes based on nanocrystalline perovskite in a dielectric polymer matrix. , 2015, Nano letters.

[68]  Frederik C. Krebs,et al.  Tin‐ and Lead‐Based Perovskite Solar Cells under Scrutiny: An Environmental Perspective , 2015 .

[69]  X. Hou,et al.  Electric field-modulated amplified spontaneous emission in organo-lead halide perovskite CH3NH3PbI3 , 2015 .

[70]  V. Wood,et al.  Hole Mobility in Nanocrystal Solids as a Function of Constituent Nanocrystal Size. , 2014, The journal of physical chemistry letters.

[71]  C. Carbonaro,et al.  Can Trihalide Lead Perovskites Support Continuous Wave Lasing? , 2015 .

[72]  J. Noh,et al.  Efficient inorganic–organic hybrid heterojunction solar cells containing perovskite compound and polymeric hole conductors , 2013, Nature Photonics.

[73]  D. Kabra,et al.  Band Gap Tuning of CH₃NH₃Pb(Br(1-x)Clx)₃ Hybrid Perovskite for Blue Electroluminescence. , 2015, ACS applied materials & interfaces.

[74]  Christophe Ballif,et al.  Organometallic Halide Perovskites: Sharp Optical Absorption Edge and Its Relation to Photovoltaic Performance. , 2014, The journal of physical chemistry letters.

[75]  Nam-Gyu Park,et al.  Organometal Perovskite Light Absorbers Toward a 20% Efficiency Low-Cost Solid-State Mesoscopic Solar Cell , 2013 .

[76]  Haibo Zeng,et al.  Quantum Dot Light‐Emitting Diodes Based on Inorganic Perovskite Cesium Lead Halides (CsPbX3). , 2016 .

[77]  Ivan Mora-Sero,et al.  Bright Visible-Infrared Light Emitting Diodes Based on Hybrid Halide Perovskite with Spiro-OMeTAD as a Hole-Injecting Layer. , 2015, The journal of physical chemistry letters.

[78]  Shuai Liu,et al.  Random lasing actions in self-assembled perovskite nanoparticles , 2015, 1512.07377.

[79]  Richard H. Friend,et al.  Overcoming the electroluminescence efficiency limitations of perovskite light-emitting diodes , 2015, Science.

[80]  E. Sargent,et al.  Low trap-state density and long carrier diffusion in organolead trihalide perovskite single crystals , 2015, Science.

[81]  M. Messing,et al.  Exciton Binding Energy and the Nature of Emissive States in Organometal Halide Perovskites. , 2015, The journal of physical chemistry letters.

[82]  Jeffrey Long,et al.  Materials to Devices , 2017 .

[83]  M. Grätzel,et al.  A hole-conductor–free, fully printable mesoscopic perovskite solar cell with high stability , 2014, Science.

[84]  O. Voznyy,et al.  Structural, optical, and electronic studies of wide-bandgap lead halide perovskites , 2015 .

[85]  Bernd Rech,et al.  A mixed-cation lead mixed-halide perovskite absorber for tandem solar cells , 2016, Science.

[86]  Libai Huang,et al.  Thermal conductivity of organic bulk heterojunction solar cells: an unusual binary mixing effect. , 2014, Physical chemistry chemical physics : PCCP.

[87]  N. Park,et al.  Lead Iodide Perovskite Sensitized All-Solid-State Submicron Thin Film Mesoscopic Solar Cell with Efficiency Exceeding 9% , 2012, Scientific Reports.

[88]  Alain Goriely,et al.  Recombination Kinetics in Organic-Inorganic Perovskites: Excitons, Free Charge, and Subgap States , 2014 .

[89]  Jay B. Patel,et al.  Structured Organic–Inorganic Perovskite toward a Distributed Feedback Laser , 2016, Advanced materials.

[90]  N. Wang,et al.  Interfacial Control Toward Efficient and Low‐Voltage Perovskite Light‐Emitting Diodes , 2015, Advanced materials.

[91]  Qing Liao,et al.  Perovskite Microdisk Microlasers Self‐Assembled from Solution , 2015, Advanced materials.

[92]  Nam-Gyu Park,et al.  6.5% efficient perovskite quantum-dot-sensitized solar cell. , 2011, Nanoscale.

[93]  Tomas Leijtens,et al.  Electronic properties of meso-superstructured and planar organometal halide perovskite films: charge trapping, photodoping, and carrier mobility. , 2014, ACS nano.

[94]  Sang Il Seok,et al.  High-performance photovoltaic perovskite layers fabricated through intramolecular exchange , 2015, Science.

[95]  Chunfeng Zhang,et al.  Superior Optical Properties of Perovskite Nanocrystals as Single Photon Emitters. , 2015, ACS nano.

[96]  Kaiyang Wang,et al.  Two-photon pumped lead halide perovskite nanowire lasers , 2015, 1510.03987.

[97]  Victor I Klimov,et al.  Effect of Auger Recombination on Lasing in Heterostructured Quantum Dots with Engineered Core/Shell Interfaces. , 2015, Nano letters.

[98]  J. Teuscher,et al.  Efficient Hybrid Solar Cells Based on Meso-Superstructured Organometal Halide Perovskites , 2012, Science.

[99]  Yu Zhang,et al.  Enhancing the Brightness of Cesium Lead Halide Perovskite Nanocrystal Based Green Light-Emitting Devices through the Interface Engineering with Perfluorinated Ionomer. , 2016, Nano letters.

[100]  A. Petrozza,et al.  Tuning the light emission properties by band gap engineering in hybrid lead halide perovskite. , 2014, Journal of the American Chemical Society.

[101]  Tze Chien Sum,et al.  Vapor Phase Synthesis of Organometal Halide Perovskite Nanowires for Tunable Room-Temperature Nanolasers. , 2015, Nano letters.

[102]  N. Kitazawa,et al.  Optical properties of CH3NH3PbX3 (X = halogen) and their mixed-halide crystals , 2002 .

[103]  Christopher H. Hendon,et al.  Nanocrystals of Cesium Lead Halide Perovskites (CsPbX3, X = Cl, Br, and I): Novel Optoelectronic Materials Showing Bright Emission with Wide Color Gamut , 2015, Nano letters.