Pressure effects on the diffusion and solubility of Zn in Pb

We have measured the activation volume of Zn in Pb to be 3.98 + 0.11 cm'/mole at 600 K and atmospheric pressure and have measured the temperature and pressure dependence of the saturation solubility of Zn in Pb. From the solubility measurements we find a volume of solution of 3.1~0,3 cm'/mole, which is not consistent with purely interstitial or purely substitutional solution. These results are compared to other impurity diffusion in Pb.

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