A statics-dynamics equivalence through the fluctuation–dissipation ratio provides a window into the spin-glass phase from nonequilibrium measurements

Significance The unifying feature of glass formers (such as polymers, supercooled liquids, colloids, granulars, spin glasses, superconductors, etc.) is a sluggish dynamics at low temperatures. Indeed, their dynamics are so slow that thermal equilibrium is never reached in macroscopic samples: in analogy with living beings, glasses are said to age. Here, we show how to relate experimentally relevant quantities with the experimentally unreachable low-temperature equilibrium phase. This relation is made quantitative via a statics-dynamics dictionary, established for spin glasses. In our dictionary, the aging response to a magnetic field is related to the spin-glass order parameter as obtained on samples small enough to equilibrate. We remark that all of the observables we consider can be measured with current experimental methods. We have performed a very accurate computation of the nonequilibrium fluctuation–dissipation ratio for the 3D Edwards–Anderson Ising spin glass, by means of large-scale simulations on the special-purpose computers Janus and Janus II. This ratio (computed for finite times on very large, effectively infinite, systems) is compared with the equilibrium probability distribution of the spin overlap for finite sizes. Our main result is a quantitative statics-dynamics dictionary, which could allow the experimental exploration of important features of the spin-glass phase without requiring uncontrollable extrapolations to infinite times or system sizes.

[1]  M. Mézard,et al.  Journal of Statistical Mechanics: Theory and Experiment , 2011 .

[2]  G. Parisi,et al.  Out-of-equilibrium finite-size method for critical behavior analyses. , 2015, Physical review. E.

[3]  A. Young,et al.  The connection between statics and dynamics of spin glasses , 2015, 1504.07709.

[4]  Udo Seifert,et al.  Single-molecule measurement of the effective temperature in non-equilibrium steady states , 2015, Nature Physics.

[5]  L. Pérez,et al.  Testing statics-dynamics equivalence at the spin-glass transition in three dimensions , 2015 .

[6]  A. Young,et al.  Nonequilibrium evolution of window overlaps in spin glasses , 2015, 1501.06760.

[7]  Denis Navarro,et al.  Janus II: A new generation application-driven computer for spin-system simulations , 2013, Comput. Phys. Commun..

[8]  G. Parisi,et al.  Critical parameters of the three-dimensional Ising spin glass , 2013, 1310.2910.

[9]  G. Parisi,et al.  Generalized fluctuation-dissipation relation and effective temperature upon heating a deeply supercooled liquid. , 2012, Physical review letters.

[10]  R. Di Leonardo,et al.  Measurement of the four-point susceptibility of an out-of-equilibrium colloidal solution of nanoparticles using time-resolved light scattering. , 2012, Physical review letters.

[11]  W. Marsden I and J , 2012 .

[12]  R. Perzynski,et al.  Experimental evidence for violation of the fluctuation-dissipation theorem in a superspin glass. , 2010, Physical review letters.

[13]  G. Parisi,et al.  Static versus dynamic heterogeneities in the D = 3 Edwards-Anderson-Ising spin glass. , 2010, Physical review letters.

[14]  S. F. Schifano,et al.  Nature of the spin-glass phase at experimental length scales , 2010, 1003.2569.

[15]  N. Israeloff,et al.  Nanoscale non-equilibrium dynamics and the fluctuation–dissipation relation in an ageing polymer glass , 2010, 1005.2515.

[16]  G. Ruocco,et al.  Generalized fluctuation-dissipation relation and effective temperature in off-equilibrium colloids , 2008, 0812.0740.

[17]  Andrea Cavagna,et al.  Supercooled liquids for pedestrians , 2009, 0903.4264.

[18]  Juan Ruben Gomez-Solano,et al.  Experimental verification of a modified fluctuation-dissipation relation for a micron-sized particle in a nonequilibrium steady state. , 2009, Physical review letters.

[19]  S. F. Schifano,et al.  An In-Depth View of the Microscopic Dynamics of Ising Spin Glasses at Fixed Temperature , 2008, 0811.2864.

[20]  Denis Navarro,et al.  Janus: An FPGA-Based System for High-Performance Scientific Computing , 2007, Computing in Science & Engineering.

[21]  Artyom Petrosyan,et al.  Experimental study of out-of-equilibrium fluctuations in a colloidal suspension of Laponite using optical traps , 2008, 0812.1391.

[22]  G. Parisi,et al.  Nonequilibrium spin-glass dynamics from picoseconds to a tenth of a second. , 2008, Physical review letters.

[23]  Denis Navarro,et al.  Simulating spin systems on IANUS, an FPGA-based computer , 2007, Comput. Phys. Commun..

[24]  S. Ciliberto,et al.  violation during the formation of a colloidal-glass , 2008 .

[25]  L. Cugliandolo,et al.  Fluctuations in glassy systems , 2007, 0704.0684.

[26]  L. Berthier Efficient measurement of linear susceptibilities in molecular simulations: application to aging supercooled liquids. , 2007, Physical review letters.

[27]  L. Cugliandolo,et al.  Growing dynamical length, scaling, and heterogeneities in the 3D Edwards–Anderson model , 2007, cond-mat/0701116.

[28]  T. Wood,et al.  Measurement of effective temperatures in an aging colloidal glass. , 2006, Physical review letters.

[29]  L. Berthier,et al.  Direct Experimental Evidence of a Growing Length Scale Accompanying the Glass Transition , 2005, Science.

[30]  F. A. Tamarit,et al.  Spin-glass behavior in the random-anisotropy Heisenberg model , 2005, cond-mat/0504483.

[31]  J. Bouchaud,et al.  Aging, rejuvenation and memory phenomena in spin glasses , 2004, cond-mat/0406721.

[32]  E. Marinari OFF-EQUILIBRIUM DYNAMICS AT VERY LOW TEMPERATURES IN 3 d SPIN GLASSES , 2005 .

[33]  M. Ocio,et al.  Off-equilibrium fluctuation-dissipation relation in a spin glass , 2004, cond-mat/0403112.

[34]  J. Bouchaud,et al.  Spin anisotropy and slow dynamics in spin glasses. , 2003, Physical review letters.

[35]  F. Ricci-Tersenghi Measuring the fluctuation-dissipation ratio in glassy systems with no perturbing field. , 2003, Physical review. E, Statistical, nonlinear, and soft matter physics.

[36]  Christophe Chatelain A far-from-equilibrium fluctuation?dissipation relation for an Ising?Glauber-like model , 2003, cond-mat/0303545.

[37]  D. Bonn,et al.  Stokes-Einstein relations and the fluctuation-dissipation theorem in a supercooled colloidal fluid , 2003 .

[38]  H. Kawamura Fluctuation-dissipation ratio of the Heisenberg spin glass. , 2002, Physical review letters.

[39]  R. Orbach,et al.  Full aging in spin glasses. , 2002, Physical review letters.

[40]  A. Tarancón,et al.  Off-equilibrium fluctuation-dissipation relations in the 3d Ising spin glass in a magnetic field , 2002, cond-mat/0209350.

[41]  M. Ocio,et al.  Fluctuation-dissipation ratio of a spin glass in the aging regime. , 2001, Physical review letters.

[42]  L. Berthier,et al.  Real-space application of the mean-field description of spin-glass dynamics. , 2001, Physical review letters.

[43]  S. Ciliberto,et al.  Violation of the fluctuation-dissipation relation during the formation of a colloidal glass , 2000, cond-mat/0008160.

[44]  C. L. Ullod,et al.  SUE: A special purpose computer for spin glass models , 2000, cond-mat/0004080.

[45]  L. Berthier,et al.  Fluctuation-dissipation relation in a sheared fluid. , 2000, Physical review. E, Statistical, nonlinear, and soft matter physics.

[46]  G. Parisi,et al.  Off-equilibrium dynamics at very low temperatures in three-dimensional spin glasses , 1999, cond-mat/9910232.

[47]  G. Parisi,et al.  Replica Symmetry Breaking in Short-Range Spin Glasses: Theoretical Foundations and Numerical Evidences , 1999, cond-mat/9906076.

[48]  T. Grigera,et al.  Observation of Fluctuation-Dissipation-Theorem Violations in a Structural Glass , 1999, cond-mat/9904351.

[49]  S. Caracciolo,et al.  UNIVERSAL FINITE-SIZE SCALING FUNCTIONS IN THE 3D ISING SPIN GLASS , 1999, cond-mat/9904246.

[50]  M. Mézard,et al.  The Response of Glassy Systems to Random Perturbations: A Bridge Between Equilibrium and Off-Equilibrium , 1999, cond-mat/9903370.

[51]  G. G. Wood,et al.  EXTRACTION OF THE SPIN GLASS CORRELATION LENGTH , 1998, cond-mat/9809246.

[52]  G. Parisi,et al.  Generalized off-equilibrium fluctuation-dissipation relations in random Ising systems , 1998, cond-mat/9811374.

[53]  W. Kob,et al.  FLUCTUATION-DISSIPATION RATIO IN AN AGING LENNARD-JONES GLASS , 1998, cond-mat/9806027.

[54]  L. Peliti,et al.  Measuring Equilibrium Properties in Aging Systems , 1998, cond-mat/9803108.

[55]  A. Young,et al.  Spin glasses and random fields , 1997 .

[56]  G. Parisi Off-equilibrium fluctuation-dissipation relation in fragile glasses , 1997 .

[57]  G. Parisi,et al.  Violation of the fluctuation-dissipation theorem in finite-dimensional spin glasses , 1997, cond-mat/9710120.

[58]  Jean-Philippe Bouchaud,et al.  Slow dynamics and aging in spin glasses , 1996, cond-mat/9607224.

[59]  Hammann,et al.  Spin Glass Dynamics under a Change in Magnetic Field. , 1996, Physical review letters.

[60]  S. Franz,et al.  Fluctuation-dissipation ratio in three-dimensional spin glasses , 1994, cond-mat/9410112.

[61]  J. Mydosh Spin glasses : an experimental introduction , 1993 .

[62]  J. Kurchan,et al.  Analytical solution of the off-equilibrium dynamics of a long-range spin-glass model. , 1993, Physical review letters.

[63]  Lundgren,et al.  Static scaling in a short-range Ising spin glass. , 1991, Physical review. B, Condensed matter.

[64]  M. Mézard,et al.  Spin Glass Theory and Beyond , 1987 .

[65]  Ogielski,et al.  Dynamics of three-dimensional Ising spin glasses in thermal equilibrium. , 1985, Physical review. B, Condensed matter.

[66]  Moore,et al.  Critical behavior of the three-dimensional Ising spin glass. , 1985, Physical review. B, Condensed matter.

[67]  Giorgio Parisi,et al.  Infinite Number of Order Parameters for Spin-Glasses , 1979 .