A computational fluid dynamics model for the flotation rate constant, Part I: Model development

A Computational Fluid Dynamics (CFD) model for the prediction of the flotation rate constant in a standard Rushton turbine flotation tank was developed. The premise for the model development was the assumption that separation by flotation is a first order rate kinetic process. An Eulerian–Eulerian framework in conjunction with the dispersed k–e turbulence model was supplemented with user defined functions to implement the local values of the turbulent flow into a kinetic model. Simulations were performed for quartz at different operational conditions. The numerical predictions were validated against experimental data and analytical computations using the fundamental flotation model of Pyke et al. (2003). The results showed that the CFD-based model not only captured the trend of experiments for a range of particle sizes but also that the CFD yielded improvements in the predictions of flotation rate constant compared with the theoretical calculations. It was found that the CFD model is able to predict the flotation rate constants of the quartz particles floating under different ranges of hydrophobicity, agitation speed and gas flow rates with lower root mean square deviation compared with the theoretical computations.

[1]  Theodore J. Heindel,et al.  Modeling flotation separation in a semi-batch process , 2003 .

[2]  Vivek V. Ranade,et al.  Gas–liquid flow in stirred reactors: Trailing vortices and gas accumulation behind impeller blades , 1999 .

[3]  G. Evans,et al.  Numerical modelling of gas-liquid flow in stirred tanks , 2005 .

[4]  P.T.L. Koh,et al.  CFD modelling of bubble–particle collision rates and efficiencies in a flotation cell , 2003 .

[5]  Emmanuel Manlapig,et al.  Studies on impeller type, impeller speed and air flow rate in an industrial scale flotation cell part 2: Effect on gas holdup , 1995 .

[6]  Geoffrey M. Evans,et al.  Predicting gas–liquid flow in a mechanically stirred tank , 2002 .

[7]  Emmanuel Manlapig,et al.  Studies on impeller type, impeller speed and air flow rate in an industrial scale flotation cell. Part 3: Effect on superficial gas velocity , 1996 .

[8]  M. P. Schwarz,et al.  CDF simulation of bubble-particle collisions in mineral flotation cells , 2000 .

[9]  H. Schubert,et al.  On the hydrodynamics of flotation machines , 1978 .

[10]  T. Heindel,et al.  An Approximate Analytical Expression for the Probability of Attachment by Sliding. , 1999, Journal of colloid and interface science.

[11]  Emmanuel Manlapig,et al.  Studies on impeller type, impeller speed and air flow rate in an industrial scale flotation cell — Part 1: Effect on bubble size distribution , 1995 .

[12]  Kari Heiskanen,et al.  Modelling bubble-particle interaction with dynamic surface tension , 2010 .

[13]  S. Grano,et al.  Hydrodynamics and scale up in Rushton turbine flotation cells: Part 1 — Cell hydrodynamics , 2007 .

[14]  P. Koh,et al.  The effect of stirring speed and induction time on flotation , 2011 .

[15]  H. Schubert,et al.  On the optimization of hydrodynamics in fine particle flotation , 2008 .

[16]  Vivek V. Ranade,et al.  CFD simulation of mixing in tall gas-liquid stirred vessel: Role of local flow patterns , 2006 .

[17]  R. Yoon,et al.  The Effect of Bubble Size on Fine Particle Flotation , 1989 .

[18]  P.T.L. Koh,et al.  CFD model of a self-aerating flotation cell , 2007 .

[19]  S. Dukhin,et al.  Dynamics of Adsorption at Liquid Interfaces: Theory, Experiment, Application , 1995 .

[20]  D. Fornasiero,et al.  Calculation of the flotation rate constant of chalcopyrite particles in an ore , 2003 .

[21]  Mohsen Karimi,et al.  Quantification of numerical and Model Uncertainties in the CFD Simulation of the Gas Holdup and flow Dynamics in a Laboratory Scale Rushton-Turbine Flotation Tank , 2012 .

[22]  Mark Cross,et al.  Modeling and Simulation of Mineral Processing Systems , 2003 .

[23]  J. Finch,et al.  Particle size dependence in flotation derived from a fundamental model of the capture process , 1987 .

[24]  D. Fornasiero,et al.  Bubble particle heterocoagulation under turbulent conditions. , 2003, Journal of colloid and interface science.

[25]  G. Wierink A computational framework for coupled modelling of three-phase systems with soluble surfactants , 2012 .

[26]  Theodore J. Heindel,et al.  On the structure of collision and detachment frequencies in flotation models , 2002 .

[27]  J. Franzidis,et al.  Studies on impeller type, impeller speed and air flow rate in an industrial scale flotation cell. Part 4: Effect of bubble surface area flux on flotation performance☆ , 1997 .

[28]  Anh V. Nguyen New method and equations for determining attachment tenacity and particle size limit in flotation , 2003 .

[29]  Chinmay V. Rane,et al.  CFD simulation of stirred tanks: Comparison of turbulence models. Part I: Radial flow impellers , 2011 .

[30]  Mohsen Karimi,et al.  Effects of different mesh schemes and turbulence models in cfd modelling of stirred tanks , 2012 .

[31]  A. Bakker,et al.  A COMPUTATIONAL MODEL FOR THE GAS-LIQUID FLOW IN STIRRED REACTORS , 1994 .

[32]  Heindel,et al.  Exact and Approximate Expressions for Bubble-Particle Collision. , 1999, Journal of colloid and interface science.

[33]  H. Schulze,et al.  New theoretical and experimental investigations on stability of bubble/particle aggregates in flotation: A theory on the upper particle size of floatability , 1977 .

[34]  B. Derjaguin,et al.  Theory of flotation of small and medium-size particles☆ , 1993 .

[35]  P. Saffman,et al.  On the collision of drops in turbulent clouds , 1956, Journal of Fluid Mechanics.

[36]  D. Fornasiero,et al.  Particle-bubble collision models--a review , 2000, Advances in colloid and interface science.

[37]  Mohsen Karimi,et al.  Comparison of different drag coefficient correlations in the CFD modelling of a Laboratory-Scale Rushton-Turbine Flotation Tank , 2012 .

[38]  K. Sutherland Physical chemistry of flotation; kinetics of the flotation process. , 1948, The Journal of physical and colloid chemistry.

[39]  Dai,et al.  Particle-Bubble Attachment in Mineral Flotation. , 1999, Journal of colloid and interface science.

[40]  P.T.L. Koh,et al.  CFD MODELLING OF BUBBLE-PARTICLE ATTACHMENTS IN FLOTATION CELLS , 2006 .

[41]  A. Bannari,et al.  CFD MODELING OF GAS DISPERSION AND BUBBLE SIZE IN A DOUBLE TURBINE STIRRED TANK , 2006 .