Growth Temperature Dependence of Sol-Gel Spin Coated Indium Nitride Thin Films

The study highlights the effects of growth temperatures ranging from 500 to 650 °C on the properties of indium nitride (InN) thin films prepared by sol-gel spin coating method followed by nitridation, also, the growth mechanism was studied in depth. The findings revealed that the InN crystal growth was promoted at the growth temperature of 600 °C, by which the crystalline quality of the deposited thin films was improved and the densely packed InN grains were formed. However, thermal decomposition of InN was observed at increasing temperature to 650 °C. Apart from that, the infrared (IR) reflectance measurement shows the presence of transverse and longitudinal-optical phonon modes of wurtzite structure InN. These vibrational modes were found to be slightly shifted from the theoretical values as a result of the incorporation of oxygen contamination in the deposited thin films.

[1]  F. Yam,et al.  Growth mechanism of indium nitride via sol–gel spin coating method and nitridation process , 2017 .

[2]  S. B. Krupanidhi,et al.  High indium non-polar InGaN clusters with infrared sensitivity grown by PAMBE , 2015 .

[3]  C. Y. Fong,et al.  Effects of Nitridation Temperature on Characteristics of Gallium Nitride Thin Films Prepared Via Two-Step Method , 2015, Acta Metallurgica Sinica (English Letters).

[4]  Z. Hassan,et al.  Growth of InN thin films on different Si substrates at ambient temperature , 2013 .

[5]  I. Ferguson,et al.  Thermal Stability of InN Epilayers Grown by High Pressure Chemical Vapor Deposition , 2013 .

[6]  Z. Hassan,et al.  Growth and conversion of β-Ga2O3 nanobelts into GaN nanowires via catalyst-free chemical vapor deposition technique , 2013 .

[7]  Rong Huang,et al.  Controllable Growth of InN Nanostructures , 2012 .

[8]  Z. Mi,et al.  Large-scale cubic InN nanocrystals by a combined solution- and vapor-phase method under silica confinement. , 2012, Journal of the American Chemical Society.

[9]  G. P. Yablonskii,et al.  Dependence of InN properties on MOCVD growth parameters , 2011 .

[10]  S. Lau,et al.  Structural and optical properties of wurtzite InN grown on Si(111) , 2007 .

[11]  Shi Yi,et al.  Growth and Characterization of InN Thin Films on Sapphire by MOCVD , 2007 .

[12]  N. Mutsukura,et al.  Temperature dependence of InN film deposition by an RF plasma-assisted reactive ion beam sputtering deposition technique , 2005 .

[13]  A. Zettl,et al.  Growth and morphology of 0.80 eV photoemitting indium nitride nanowires , 2004 .

[14]  Qinghong Zhang,et al.  Preparation of ultrafine InN powder by the nitridation of In2O3 or In(OH)3 and its thermal stability , 2003 .

[15]  Yoshiki Saito,et al.  RF-Molecular Beam Epitaxy Growth and Properties of InN and Related Alloys , 2003 .

[16]  N. Teraguchi,et al.  Growth Temperature Dependence of Indium Nitride Crystalline Quality Grown by RF‐MBE , 2002 .

[17]  Takashi Mukai,et al.  High‐power InGaN/GaN double‐heterostructure violet light emitting diodes , 1993 .

[18]  P. Connell THE PHOTOCHEMISTRY OF DINITROGEN PENTOXIDE , 1979 .

[19]  P. Bridenbaugh,et al.  Thermal stability of indium nitride at elevated temperatures and nitrogen pressures , 1970 .

[20]  J. Zhang,et al.  First-Principle Studies of Phonons III-N Compound Semiconductors in Wurtzite Structure , 2013 .

[21]  M. Dinescu,et al.  STRUCTURE AND MORPHOLOGY OF INDIUM NITRIDE THIN FILMS GROWN BY PLASMA ASSISTED PLD : THE IMPACT OF NITROGEN FLOW AND SUBSTRATE TEMPERATURE , 2013 .